Test Paper - Advanced Chemistry - Mumbai University - Chemical engineering - 3rd Semester -2009, Study notes of Chemistry

Download Test Paper - Advanced Chemistry - Mumbai University - Chemical engineering - 3rd Semester -2009 and more Study notes Chemistry in PDF only on Docsity!

08 crt. Advance. Chemisby -T 2631-09. (REVISED COURSE) rsfs]or VR-3979936) (3 Hours) [Total Marks : 100 : (1) Question No. 1 is compulsory. (2) Attempt any four questions from the remaining six questions. Attempt any four of the following -— 20 (a) Write the chemical formula of the co-ordination compounds. {i) Potassium hexacyano ferrate (IIN) (ii) Trichlorotriammine cobalt (itl) (b) Write the mechanism of Breckmann reaction. (c) Give synthesis of Vitamin C. : (d) Give the preparation and properties of Feg(CO);o. (e) Give the Drawbacks of VBT. (a) Give the limitation of CFT. (b) What is CFSE ? Calculate CFSE for d4 and d?. (ec) What is EAN ? Calculate EAN of complex Ky [ Fe (CN)g] (d) Explain oxygen atom transfer bimolecular reactions containing iron. won (a) Explain Debye Huckel theory of electrolyte. , (b) Explain structure of Ni(CO),- (c) Applications of Cytochromes. (d) Effect of temp. on conductivity. aaa (a) Derive an expression for concentration cell without transference. (b) Application of Cytochromes. {c) On the basis of MOT, explain molecular orbital energy pattern of No. (d) Explain Magnetic behaviour of [Fe (CN)g} +. qawda (a) Explain structure of BrF3 on the basis of VSEPR theory. (b) Write the structure of (i) Congored (ii) Malachite green. (c) Difference between bonding and antibonding orbital. (d) Write the synthesis of :— : . (i) Aspirin (ii) Alizarin. anon (a) Give the synthesis of Alizarin. 20 (b) What are drawbacks of CFT. (c) Give the mechanism of Fischer Indole Synthesis. (d) Give the nomenclature of dyes. Write reaction with mechanism :— 20 (a) Benzyl-Benzyllic acid (b) Darzen reaction (c) Michel reaction (d) Pincol-pinacolone rearrangement.