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=> AROMATIC HYDROCARBONS; 4 ‘) ¢ I) Regules Hexogonal H-C 7 ~\ _CHH r 2) Plumay Structure iC) 3) $p? (Carbon) 4-C ~~ ¢-H 4) 120° C 4 s) 6 Bond in prewt b/w i COCH > Delocabization =f xe Sp?- sp? S Sp*-S > Catron Covbon bond Length 6) blw tus C akong, x in abo present. wa Sane. 4) Subsitution ; Benzene gia MéctROPHINIC; , FRIEDEL CRAFT REACTION; (Alluylation) H cH AY + CQ -cng _Alcls > AY ened We A OXIDATION (Alokine KMnOy + Rect \ a) 0H LW) (BeNzo1¢ Acid) Acylation ; (Aduyl + Grbonye. ) oO —~" rf aN C-ti3 CJ + a-c-ers ats [OT N= NITRATION IN BENZENE; N02 J 4+ Nos “ne _ (Or (NITRO (OD J Ey LO) GEN2ENE ) Benzene Sn+(on HCL ow Heat HNO + ReSOy —> NO2* + WiDy 4 HO 6CHI (Repuctton) v | we (JJ HALOHENSTION ; I \_ + aq Mee Oe WY) WY ADDITION: (@\rr ae) SF (HEAT) - YW Single Bonded Gyoupn => Lectin Donating ; OW ONat I / ()] + Na , {(_)) tate SP Zt (Sedum Phenoxide ) On ONa ~ [()]__ + Naor , 1(_)]_ + 0 3 S (Gelium Phenoxide ) * No veockion with NazCo3. —> Alleoholiy owly veact vith Soodiam Metal, Co not cast wth Nal W of Naz C3. “GLECTRON WSTHDRALIIN Grkoue, (DOUBLE BONDED) if thee alkciched bo Beneew then elocbrophil wilh attach at Meta _parition . coon Coon | A Ww \ cls CABOXYLIC, ACID AND DERIVATIVES ; 19) @ y-c-on _féblinn a + 2 Todles Auidified kittndy HA ® Ho-c-c-oN _Aeidifiedd » 202 + 1120 kindy £0] CABOXYLIC ACID > AlYLE HALIDE; o >) R- C -oW Pils, Pls, SDCke g-t ~xX Q (9) | ° 1 tw ' ee n @ CWa-c-On + Pp? p (Hac —@ + HCD + Poca a’ ‘eo 9 o \t 1 2) 2 Wy-C-Od + PCy p 3 CHa-cC-R + Raho ny o s Q cHg-C-on £cL-S-cl ———> (‘H3-c-0 + 90. + HL Reactiviry; 4 i CO HYDROLYSIS 5 Oo. i »\ H ny v) rt ra i ' i cuz —C Jor : (Ag-¢ ~CL# Ol » (z-C-ON 4 HCL tLe RP XO ANS Oo” Abo L—Q ce. ETN | Cus) Renvction oF NITRILE; ( C=N) H I (W2-C=N 44th] LALKY » CH3 -C —NH . 1 ( Style vibe) Dry Sher HoH | KeouctioN OF Amp, {c-n ae) iv) W CH3-C Nao 4 Uf 4] p _CH3-Cla -NH2 + H20 PREPERATIon OF Amine; Reagent ; Acyh Halide, Ammonia. ; : iy i C3 -C- @ + H-N-H > CW3-C—NHo +¢ HQ. i] H r . CHa-e-(L_f H-N = is » (Hz-c-N-Cts + WA- 3 chs (N.N y ditnethul Ahanaruele ). O1-A20Tization, {N=N NO + HCL Lino + Nad ni- + Aa NT Py NENQ (aa 4 nnor ane SC (RY lO inwe OJ if Temp ‘The temp Above 00°C, Nenclan : on CO 4 H-on Abre l0C 4No4 hd —_ oH ) » | 7 YO Gone __\ (ssc) f pio, Hee AIO Nh rich Os, CJ—O DYE FORMATION; + ane ———S N= NC f[-————-“\ OOOO Azo Dye +nel AMINO Adio; f kh - N -¢*- COOH Hoy @2uiner JON; @ R i} I - HIN - cC— coon ed HsN* -— c- coo h ! Dwitten Ton }) TI 
