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ENE 5330 Midterm Exam
Fall 2017
Name: Student number:
1. (20%) (a) How many atoms are there in the unit cell characterizing the Si lattice?
(b) What is the density of atoms per cm-3 in the Si lattice at room temperature? The lattice constant for Si is
5.43 angstrom at room temperature.
(c) Determine the center-to-center distance between the nearest neighbors in the Si lattice
(d) Calculate the density of Si at room temperature. The atomic weight of Si is 28.086 g/mol. The number of
atoms in a mole is called Avogadro's number, the value of which is approximately 6.022 ร— 1023.
(e) Calculate the (100) and (110) surface density (# of atoms per area).
Solution
(a)
Si lattice is diamond structure, hence: there are three type of atoms in the unit cell
8 corner atoms ร— 1
8= 1 atom
6 face atoms ร— 1
2= 3 atoms
4 enclosed atoms ร— 1 = 4 atoms
Total of 8 atoms per unit cell.
(b)
Number of density in Si ร— 8
๏ฟฝ5.43ร—10โˆ’8 ๐‘๐‘๏ฟฝ3= 5 ร— 1022 ๐‘๐‘โˆ’3.
(c)
From 1.(b), lattice constant for Si is 5.43ร….
Space diagonal of the unit cell = โˆš3a = 8r โ†’ r = โˆš3
8๐‘Ž.
Center to center distance between the nearest neighbors is
2r = 2 ร— โˆš3
8๐‘Ž= 2 ร— โˆš3
8ร—๏ฟฝ5.43ร…๏ฟฝ= 2.35ร….
(d)
Density of Si is
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ENE 5330 Midterm Exam

Fall 2017

Name: Student number:

  1. (20%) (a) How many atoms are there in the unit cell characterizing the Si lattice?

(b) What is the density of atoms per cm

  • in the Si lattice at room temperature? The lattice constant for Si is

5.43 angstrom at room temperature.

(c) Determine the center-to-center distance between the nearest neighbors in the Si lattice

(d) Calculate the density of Si at room temperature. The atomic weight of Si is 28.086 g/mol. The number of

atoms in a mole is called Avogadro's number, the value of which is approximately 6.022 ร— 10

23 .

(e) Calculate the (100) and (110) surface density (# of atoms per area).

Solution

(a)

Si lattice is diamond structure, hence: there are three type of atoms in the unit cell

8 corner atoms ร—

1

8

= 1 atom

6 face atoms ร—

1

2

= 3 atoms

4 enclosed atoms ร— 1 = 4 atoms

Total of 8 atoms per unit cell.

(b)

Number of density in Si ร—

8

๏ฟฝ5.43ร—

โˆ’ 8 ๐‘๐‘๏ฟฝ

3 = 5 ร— 10

22

โˆ’ 3 .

(c)

From 1.(b), lattice constant for Si is 5.43ร….

Space diagonal of the unit cell = โˆš3a = 8r โ†’ r =

โˆš

8

Center to center distance between the nearest neighbors is

2r = 2 ร—

โˆš

8

๐‘Ž = 2 ร—

โˆš

8

ร— ๏ฟฝ5.43ร…๏ฟฝ = 2.35ร….

(d)

Density of Si is

๐‘๐‘๐‘๐‘๐‘๐‘ ๐‘œ๐‘œ ๐‘‘๐‘๐‘‘๐‘‘๐‘‘๐‘‘๐‘‘ ๐‘‘๐‘‘ ๐‘†๐‘‘

๐ด๐ด๐‘œ๐ด๐ด๐‘‘๐‘๐‘œ โ€ฒ๐‘‘ ๐‘‘๐‘๐‘๐‘๐‘๐‘

ร— ๐‘ค๐‘ค๐‘ค๐‘คโ„Ž๐‘ก ๐‘œ๐‘œ ๐‘†๐‘ค

5 ร— 10

22

โˆ’

6.022 ร— 10

23

โˆ’

ร— 28.086 ๐‘ค โˆ™ ๐‘๐‘œ๐‘š

โˆ’

3

(e)

Surface density of (100) is

4 ร—

1

4

( 5. 43 ร— 10 โˆ’8^ ๐‘๐‘)^2

= 6.78 ร— 10

14

โˆ’

Surface density of (110) is

4 ร—

1

4

+2ร—

1

2

  1. 43 ร— 10 โˆ’8^ ๐‘๐‘ ร— โˆš2ร— 5. 43 ร— 10 โˆ’8^ ๐‘๐‘

= 9.59 ร— 10

14

โˆ’

  1. (20%) Consider the n=1 eigenfunction (ground state wave function) of an infinite 1D potential well of

width a. The potential energy U(x) is zero inside the well and infinity outside the well.

a) Show that the normalized wavefunction is

1

( ) x sin( x / a ) a

b) Compute < x > and provide an interpretation.

c) Compute < px > and provide an interpretation.

d) Compute

2 < p x >

e) Show that

2 2 2

2 1 0 0

p x

m m a

ฯ€ ฮต

, whereฮต 1 is the ground state energy.

Solution:

a) ฯˆ (^) ( x (^) ) = A sin (^) ( kx (^) ) + B cos( kx )

ฯˆ (^) ( 0 )= 0 โ†’ B = 0

( ) 0

n a k a

( ) sin^

n x A x a

ฯ€ ฯˆ

( )

2

0

a x dx A a

โˆซ

( )

sin

n x x a a

1 (^ )

x sin x a a

b) (^) ( ) ( )

  • 2 1 1 0 0

sin 2

a a (^) a x x x x dx x x dx a a

ฯ€ ฯˆ ฯˆ

โˆซ โˆซ

The expectation value of position is

2

a , which is the middle of the infinite potential well

  1. (20%) Consider a two dimensional semiconductor with width W and length L. Assuming the dimensions

are much larger than atomic dimension, derive an expression for the density of states (g (^) 2D) in energy.

Assume a valley degeneracy of gV.

a) Assume a parabolic dispersion near k = 0

2 2

2

C

k E E m

b) Assume a linear dispersion near k = 0

E = E C + > ฯ… Fk

Show details of your work.

Solution:

a)

1 1

2 2

States between &

E E E

k dk k A spin kdk

L W

= ร— =

States per unit energy per area @ (^1 )

V D

g dk E g k

ฯ€ dE

2 2

  • 2 2

C C C

k m E E dk m E E k m dE E E

โˆ’ = + โ‡’ = โ‡’ = โˆ’

(^2 )

V V D

g dk g m g k

ฯ€ dE ฯ€

b)

C^1

C F F F

E E dk E E k k dE

(^2 2 )

2 for positive and negative

V V C D F

g dk g E E g k ฯ€ dE ฯ€ ฯ…

k

  1. (10%) Consider germanium with an acceptor concentration of Na=

15 cm

  • . Consider temperature of 200,

400, and 600K. Calculate the hole concentration and the position of the Fermi level with respect to the

intrinsic Fermi level at these temperatures. Assume that for germanium, NC =1.03x

19 cm

  • ,

NV=5.35x

18 cm

  • , and Eg =0.663 eV are constants.

Solution:

2 = ๐‘๐‘ ๐‘๐ด๐‘ค๐‘’๐‘’ ๏ฟฝ

and ๐‘ƒ 0 =

๐‘๐‘Ž โˆ’๐‘๐‘‘

2

๐‘๐‘Ž โˆ’๐‘๐‘‘

2

2

  • ๐‘›๐‘‘

2 , ๐‘๐ด โ‰ซ ๐‘๐‘‘ โ†’ ๐‘ƒ 0 =

๐‘๐‘Ž

2

๐‘๐‘Ž

2

2

  • ๐‘›๐‘‘

2

๐‘˜ = 200 ๐พ, ๐‘˜๐‘˜ = 0.0259 ๐‘ค๐‘’ ร—

๐‘›๐‘‘ = 3.538 ร— 10

10 ๐‘๐‘

โˆ’ , ๐‘ƒ 0 = 1 ร— 10

15 ๐‘๐‘

โˆ’ , ๐ธ๐น๐‘‘ โˆ’ ๐ธ๐น = 0.177 ๐‘ค๐‘’

๐‘˜ = 400 ๐พ, ๐‘˜๐‘˜ = 0.0259 ๐‘ค๐‘’ ร—

๐‘›๐‘‘ = 4.984 ร— 10

14 ๐‘๐‘

โˆ’ , ๐‘ƒ 0 = 1.206 ร— 10

15 ๐‘๐‘

โˆ’ , ๐ธ๐น๐‘‘ โˆ’ ๐ธ๐น = 0.0305 ๐‘ค๐‘’

๐‘˜ = 600 ๐พ, ๐‘˜๐‘˜ = 0.0259 ๐‘ค๐‘’ ร—

๐‘›๐‘‘ = 1.234 ร— 10

16 ๐‘๐‘

โˆ’ , ๐‘ƒ 0 = 1.285 ร— 10

16 ๐‘๐‘

โˆ’ , ๐ธ๐น๐‘‘ โˆ’ ๐ธ๐น = 0.00210 ๐‘ค๐‘’

7 (10%) The Fermi level in n-type germanium at T=300K is 245 meV below the conduction band and 200

meV below the donor level with a donor concentration of 10

18 cm

  • . Determine the probability of finding an

electron (a) in the donor level and (b) in the conduction band minimum. Also calculate electron density n 0.

Solution:

(a)

For the donor level

= 8.852 ร— 10

โˆ’

(b)

We have

= 7.794 ร— 10

โˆ’

๏ฟฝ = 1.03 ร— 10

19 ๐‘๐‘

โˆ’ ร— 7.794 ร— 10

โˆ’ = 8.028 ร— 10

14 ๐‘๐‘

โˆ’