Bachelor of Engineering (Honours) in Mechanical Engineering Exam - Autumn 2005 - Chemistry, Exams of Chemistry

A past exam paper from the bachelor of engineering (honours) in mechanical engineering program at cork institute of technology, ireland. The exam covers various topics in chemistry, including nuclear equations, fuel cells, bond energy, and environmental pollution. Students are required to answer questions on completing nuclear equations, calculating energy changes, writing notes on specific topics, and discussing environmental pollution. The exam is from the autumn 2005 semester and is worth 3 hours.

Typology: Exams

2012/2013

Uploaded on 04/12/2013

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Cork Institute of Technology
Bachelor of Engineering (Honours) in Mechanical Engineering – Stage 1
(Bachelor of Engineering in Mechanical Engineering – Stage 1)
(NFQ – Level 8)
Autumn 2005
Chemistry
(Time: 3 Hours)
Instructions
Answer any FIVE questions.
All questions carry equal marks.
Examiners: Mr. S. P. McCarthy
Prof. J. Monaghan
Mr. J. E. Hegarty
Q1. (a) Complete the following nuclear equations:
(i) Al
27
13 + n
1
0 Na
24
11 + ……………
(ii) N
14
7 + He
4
2 O
17
8 +..…………...
(iii) Al
27
13 + n
1
0 Mg
27
12 + …………….
(6 marks)
(b) Calculate the energy change per gram of reactant for the following nuclear fusion
reaction:
H
2
1 + H
2
1 = He
4
2
Useful data:
Velocity of light = 3 x 108 ms-1
Avagadros Number = 6.02 x 1023
Atomic mass of 4
2He = 4.0026 a.m.u.
Atomic mass of 2
1H = 2.0141 a.m.u. (14 marks)
Q2. Write notes on the following:
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Cork Institute of Technology

Bachelor of Engineering (Honours) in Mechanical Engineering – Stage 1

(Bachelor of Engineering in Mechanical Engineering – Stage 1)

(NFQ – Level 8)

Autumn 2005

Chemistry

(Time: 3 Hours)

Instructions Answer any FIVE questions. All questions carry equal marks.

Examiners: Mr. S. P. McCarthy Prof. J. Monaghan Mr. J. E. Hegarty

Q1. (a) Complete the following nuclear equations:

(i) 2713 Al + 01 n → 1124 Na + ……………

(ii) (^147) N + (^24) He → 178 O +..…………...

(iii) 2713 Al + 01 n → 1227 Mg + ……………. (6 marks) (b) Calculate the energy change per gram of reactant for the following nuclear fusion reaction:

(^21) H + 21 H = 24 He

Useful data: Velocity of light = 3 x 10 8 ms- Avagadros Number = 6.02 x 10 23 Atomic mass of 42 He = 4.0026 a.m.u. Atomic mass of 21 H = 2.0141 a.m.u. (14 marks)

Q2. Write notes on the following:

(a) Fuel cells (7 marks) (b) Cracking of hydrocarbons (6 marks) (c) Semi conductors. (7 marks)

Q3. (a) Calculate the enthalpy hange ( ∆ H )for the following reaction:

CH 4 (g) + 4Cl 2 (g) = CCl 4 (g) + 4HCL (g)

Useful data: Bond Energies C-H 413 kJ Cl-Cl 243kJ C-Cl 327kJ H-Cl 432kJ

Comment on the significance of your result. (b) Write concise notes on: (i) Hess’s Law of heat summation (ii) Bond Energy. (8 marks)

Q4. Write notes on two of the following: (a) Liquid – liquid extraction (10 marks) (b) Hardness of water (10 marks) (c) Determination of the enthalpy of neutralisation of a strong acid and strong base.(10 marks)

Q5. Discuss environmental pollution under the headings: (a) Incineration (6 marks) (b) Atmospheric pollution (7 marks) (c) Water pollution (7 marks)