Atomic Theory experiments, Lecture notes of Chemistry

Brief history of the atomic structure

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ATOMIC THEORY
Brief history of the atom (Democritus and the Greek Philosophers)
Before we discuss the experiments and evidence that have, over the years, convinced scientists
that matter is made up of atoms, it’s only fair to give credit to the man who proposed “atoms” in
the first place. About 2,500 years ago, early Greek philosophers believed the entire universe was
a single, huge, entity. In other words, “everything was one.” They believed that all objects, all
matter, and all substances were connected as a single, big, unchangeable “thing.”
One of the first people to propose “atoms” was a man known as Democritus. He had an
alternative idea from the beliefs of Greek philosophers,for him he suggested that tiny,
indivisible, solid objects make up all matter in the universe. He referred to this tiny ,indivisible
objects as ‘atomos’ or ‘atomon’ .
Other Greek philosophers disliked Democritus’ “atomos” theory because they felt it was illogical.
Dalton’s Atomic Theory
A scientist by the name John Dalton, used scientific experiment to try and prove that Democritus
theory was correct . In his experiments he noted that every time he carried out a chemical
reaction, substances reacted in fixed ratios in which elements would react to combine.
Dalton suggested that subtances were composed of small, indivisible quantities which he called
“atoms” . (In reference to Democritus’ original idea)
Dalton used this idea to generate what is now known as Dalton’s Atomic Theory which stated
the following:
1. Matter is made of tiny particles called atoms.
2. Atoms are indivisible (can’t be broken into smaller particles). During a chemical reaction,
atoms are rearranged, but they do not break apart, nor are they created or destroyed.
3. All atoms of a given element are identical in mass and other properties.
4. The atoms of different elements differ in mass and other properties.
5. Atoms of one element can combine with atoms of another element to form “compounds” –
new, complex particles. In a given compound, however, the different types of atoms are always
present in the same relative numbers.
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ATOMIC THEORY

Brief history of the atom (Democritus and the Greek Philosophers)

Before we discuss the experiments and evidence that have, over the years, convinced scientists

that matter is made up of atoms, it’s only fair to give credit to the man who proposed “atoms” in

the first place. About 2,500 years ago, early Greek philosophers believed the entire universe was

a single, huge, entity. In other words, “everything was one.” They believed that all objects, all

matter, and all substances were connected as a single, big, unchangeable “thing.”

One of the first people to propose “atoms” was a man known as Democritus. He had an

alternative idea from the beliefs of Greek philosophers,for him he suggested that tiny,

indivisible, solid objects make up all matter in the universe. He referred to this tiny ,indivisible

objects as ‘atomos’ or ‘atomon’.

Other Greek philosophers disliked Democritus’ “atomos” theory because they felt it was illogical.

Dalton’s Atomic Theory

A scientist by the name John Dalton, used scientific experiment to try and prove that Democritus

theory was correct. In his experiments he noted that every time he carried out a chemical

reaction, substances reacted in fixed ratios in which elements would react to combine.

Dalton suggested that subtances were composed of small, indivisible quantities which he called

“atoms”. (In reference to Democritus’ original idea)

Dalton used this idea to generate what is now known as Dalton’s Atomic Theory which stated

the following:

1. Matter is made of tiny particles called atoms.

2. Atoms are indivisible (can’t be broken into smaller particles). During a chemical reaction,

atoms are rearranged, but they do not break apart, nor are they created or destroyed.

3. All atoms of a given element are identical in mass and other properties.

4. The atoms of different elements differ in mass and other properties.

5. Atoms of one element can combine with atoms of another element to form “compounds” –

new, complex particles. In a given compound, however, the different types of atoms are always

present in the same relative numbers.

J J Thompson & Rutherford Experiments

Dalton’s Atomic Theory was correct but not entirely. Everything was correct apart from his statement that ‘atoms are indivisible.’

According to a scientist called J.J Thompson, It turns out that atoms can be divided into smaller subatomic particles. According to Thomson’s who developed a model called “plum pudding” to prove his point.

Plum- pudding Model Experiment

This is a model that has a metaphysics appearance of how the inside of an atom looks like. J.J Thompson discovered electrons in 1897 and he came up with his theory that an atom is made up of small particles.

He proved his theory using a cathode ray tube experiment.

The figure shows a basic diagram of a cathode ray tube like the one J. J. Thomson would have used. A cathode ray tube is a small glass tube with a cathode (a negatively charged metal plate) and an anode (a positively charged metal plate) at opposite ends. By separating the cathode and anode by a short distance, the cathode ray tube can generate what are known as cathode rays – rays of electricity that flow from the cathode to the anode. J. J. Thomson wanted to know what cathode rays were, where cathode rays came from, and whether cathode rays had any mass or charge.

The technique used was, First, by cutting a small hole in the anode, J. J. Thomson found that he could get some of the cathode rays to flow through the hole in the anode and into the other end of the glass cathode ray tube. Next, J. J. Thomson figured out that if he painted a substance known as “phosphor” onto the far end of the cathode ray tube, he could see exactly where the cathode rays hit because the cathode rays made the phosphor glow.

Ernest Rutherford experiment

In trying to prove J.J Thompsons’ theory , he put up the alpha – particle scattering experiment ( Gold foil experiment)

When Rutherford fired alpha particles at a thin gold foil, most alpha particles went straight through; however, a few were scattered at different angles, and some even bounced straight back.

Rutherford reasoned that if Thompsons’ model was correct( protons and electrons mixed

uniformly inside an atom) then the atom’s mass would be spread out too, and if he shot high

velocity alpha particles there would be very little to deflect the alpha particles. But this was not

the case with the results he saw.

In order to explain the results of his Gold Foil experiment, Rutherford suggested that the positive matter in the gold atoms was concentrated at the center of the gold atom in what we now call the nucleus of the atom. He suggested that electrons surround a central nucleus. And said that mass of an atom is concentrated at the nucleus.

Rutherford also suggested the planetary Model – where he suggested that electrons orbited

around this central nucleus.

He also suggested that electrons and protons are held together by the coulombic force of

attraction.

He also argued that since each atom is electrically neutral the number of +ve charges in the

nucleus ( protons) must be equal to the number of – ve charges (electrons) in an atom.

Rutherford also proposed the existence of a neutral particle, with the approximate mass of a proton. Which was confirmed later by James Chadwick after discovering neutrons in 1911.

Bohr’s Theory