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Binary Phase Diagram engineering materials
Typology: Study notes
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A phase equilibrium diagram is a graphical presentation of data that gives considerable information about a single compound (such as SiO 2 , Al 2 O 3. or MgO) or the nature of interactions between more than one compound (1-3). The following list indicates some of the information that can be read directly from the diagram:
1- Melting temperature of each pure compound 2- The interaction of two compounds (such as SiO 2 plus Al 2 O 3 ) to form a third compound (3Al 2 O 3 .2 SiO 2 , mullite) 3- The presence and degree of solid solution 4- The effect of temperature on the degree of solid solution 5- The temperature at which a compound goes from one crystal structure to another (polymorphic phase transformation) 6- The amount and composition of liquid and solid phases at a specific temperature and bulk composition 7- The presence at high temperature of immiscible liquids (liquids that are not soluble in each other).
Composition of Each phase
Gibbs Rule for an Isomorphous phase Diagram