Binary Phase diagram for engineering materials, Study notes of Kinetics of Phase Transformations

Binary Phase Diagram engineering materials

Typology: Study notes

2019/2020

Uploaded on 04/07/2020

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Why to study phase diagram?
A phase equilibrium diagram is a graphical presentation of data that gives considerable information about
a single compound (such as SiO2, Al2O3. or MgO) or the nature of interactions between more than one
compound (1-3). The following list indicates some of the information that can be read directly from the
diagram:
1- Melting temperature of each pure compound
2- The interaction of two compounds (such as SiO2 plus Al2O3) to form a third compound (3Al2O3.2 SiO2,
mullite)
3- The presence and degree of solid solution
4- The effect of temperature on the degree of solid solution
5- The temperature at which a compound goes from one crystal structure to another (polymorphic phase
transformation)
6- The amount and composition of liquid and solid phases at a specific temperature and bulk composition
7- The presence at high temperature of immiscible liquids (liquids that are not soluble in each other).
What is the phase equilibrium diagrams ?
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Why to study phase diagram?

A phase equilibrium diagram is a graphical presentation of data that gives considerable information about a single compound (such as SiO 2 , Al 2 O 3. or MgO) or the nature of interactions between more than one compound (1-3). The following list indicates some of the information that can be read directly from the diagram:

1- Melting temperature of each pure compound 2- The interaction of two compounds (such as SiO 2 plus Al 2 O 3 ) to form a third compound (3Al 2 O 3 .2 SiO 2 , mullite) 3- The presence and degree of solid solution 4- The effect of temperature on the degree of solid solution 5- The temperature at which a compound goes from one crystal structure to another (polymorphic phase transformation) 6- The amount and composition of liquid and solid phases at a specific temperature and bulk composition 7- The presence at high temperature of immiscible liquids (liquids that are not soluble in each other).

What is the phase equilibrium diagrams?

One Components System

TiO 2 SiO 2

How to Construct the phase diagram

Cooling Curves

How to Construct phase diagram

The cooling curve for an isomorphous

alloy during solidification. We assume

that cooling rates are low so that

thermal equilibrium is maintained at

each temperature. The changes in

slope of the cooling curve indicate the

liquidus and solidus temperatures, in

this case, for a Cu-40% Ni alloy.

Composition of Each phase

Gibbs Rule for an Isomorphous phase Diagram