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Material Name: BORON TRICHLORIDE SDS ID: MAT
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*** * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * ***
Material Name: BORON TRICHLORIDE
Manufacturer Information
MATHESON TRI-GAS, INC. General Information: 1- 800 - 416 - 2505
150 Allen Road, Suite 302 Emergency #: 1- 800 - 424 - 9300 (CHEMTREC)
Basking Ridge, NJ 07920 Outside the US: 703- 527 - 3887 (Call collect)
Chemical Family
non-metallic, halides
Synonyms
MTG MSDS 8; BORON CHLORIDE; CHLORURE DE BORE; TRICHLOROBORANE; TRICHLOROBORON; BORANE, TRICHLORO-; BORON CHLORIDE (BCL3); UN 1741; BCL3; RTECS: ED
Product Use
industrial
Usage Restrictions
None known.
*** * * Section 2 - HAZARDS IDENTIFICATION * * ***
EMERGENCY OVERVIEW
Color: colorless
Physical Form: fuming liquid gas
Odor: pungent odor
Health Hazards: respiratory tract burns, skin burns, eye burns, mucous membrane burns
Physical Hazards: Containers may rupture or explode if exposed to heat. May react on contact with water. Releases toxic, corrosive, flammable or explosive gases.
Material Name: BORON TRICHLORIDE SDS ID: MAT
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POTENTIAL HEALTH EFFECTS
Inhalation
Short Term: burns
Long Term: same as effects reported in short term exposure
Skin
Short Term: burns
Long Term: same as effects reported in short term exposure
Eye
Short Term: burns
Long Term: same as effects reported in short term exposure
Ingestion
Short Term: burns
Long Term: same as effects reported in short term exposure
*** * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * ***
CAS Component Percent
10294 - 34 - 5 BORON TRICHLORIDE 100.
*** * * Section 4 - FIRST AID MEASURES * * ***
Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention.
Skin
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing before reuse. Destroy contaminated shoes.
Material Name: BORON TRICHLORIDE SDS ID: MAT
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Combustion: chlorine
Thermal Decomposition Products
Water or Moisture: boron compounds, hydrochloric acid
*** * * Section 6 - ACCIDENTAL RELEASE MEASURES * * ***
Occupational spill/release
Stop leak if possible without personal risk. Reduce vapors with water spray. Do not get water directly on material. Do not get water inside container. Keep unnecessary people away, isolate hazard area and deny entry. Small spills: Flood with water. Large spills: Dike for later disposal. Stay upwind and keep out of low areas. Ventilate closed spaces before entering. Evacuation radius: 150 feet. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).
*** * * Section 7 - HANDLING AND STORAGE * * ***
Handling Procedures
Do not breathe gas, fumes, vapor, or spray. When using, do not eat, drink or smoke. Wash thoroughly after handling.
Storage Procedures
Store and handle in accordance with all current regulations and standards. Notify State Emergency Response Commission for storage or use at amounts greater than or equal to the TPQ (U.S. EPA SARA Section 302). SARA Section 303 requires facilities storing a material with a TPQ to participate in local emergency response planning (U.S. EPA 40 CFR 355 Part B). Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Keep separated from incompatible substances. Store in a well-ventilated area. Store below 52 C. Store in a cool, dry place. Protect from sunlight.
*** * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * ***
Component Analysis
ACGIH, OSHA and NIOSH have not developed exposure limits for any of this product's components.
Component Biological Limit Values
There are no biological limit values for any of this product's components.
Ventilation
Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits.
Material Name: BORON TRICHLORIDE SDS ID: MAT
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PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face
Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Protective Clothing
Wear appropriate chemical resistant clothing.
Glove Recommendations
Wear appropriate chemical resistant gloves.
Protective Materials
butyl rubber, neoprene, polyvinyl chloride (PVC), polyethylene
Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may be needed.
Respiratory protection is ranked in order from minimum to maximum.
Consider warning properties before use.
Any chemical cartridge respirator with acid gas cartridge(s).
Any chemical cartridge respirator with a full facepiece and acid gas cartridge(s).
Any air-purifying respirator with a full facepiece and an acid gas canister.
For Unknown Concentrations or Immediately Dangerous to Life or Health -
Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.
Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
*** * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * ***
Material Name: BORON TRICHLORIDE SDS ID: MAT
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Possibility of Hazardous Reactions
Will not polymerize.
*** * * Section 11 - TOXICOLOGICAL INFORMATION * * ***
Component Analysis - LD50/LC
The components of this material have been reviewed in various sources and the following selected endpoints are published:
BORON TRICHLORIDE (10294-34-5)
Inhalation LC50 Rat 2541 ppm 1 h
Acute Toxicity Level
BORON TRICHLORIDE (10294-34-5)
Moderately Toxic: (^) inhalation.
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, OSHA or DFG.
Irritation
No animal testing data available for skin or eyes.
Local Effects
BORON TRICHLORIDE (10294-34-5)
Corrosive: inhalation, skin, eye, ingestion.
Medical Conditions Aggravated by Exposure
respiratory disorders
Tumorigenic
No data available.
Mutagenic
No data available.
Reproductive Effects
No data available.
Material Name: BORON TRICHLORIDE SDS ID: MAT
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*** * * Section 12 - ECOLOGICAL INFORMATION * * ***
Component Analysis - Aquatic Toxicity
No LOLI ecotoxicity data are available for this product's components.
*** * * Section 13 - DISPOSAL CONSIDERATIONS * * ***
Disposal Methods
Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D003.
Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components.
*** * * Section 14 - TRANSPORT INFORMATION * * ***
US DOT Information
Shipping Name: Boron trichloride
UN/NA #: UN1741 Hazard Class: 2.
Required Label(s): 2.3, 8
Additional Info.: Toxic-Inhalation Hazard Zone C
TDG Information
Shipping Name: Boron trichloride
UN #: UN1741 Hazard Class: 2.
Required Label(s): 2.3, (8)
Material Name: BORON TRICHLORIDE SDS ID: MAT
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*** * * Section 16 - OTHER INFORMATION * * ***
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR's Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States
Other Information
Matheson Tri-Gas, Inc. makes no express or implied warranties, guarantees or representations regarding the product or the information herein, including but not limited to any implied warranty or merchantability or fitness for use. Matheson Tri-Gas, Inc. shall not be liable for any personal injury, property or other damages of any nature, whether compensatory, consequential, exemplary, or otherwise, resulting from any publication, use or reliance upon the information herein.
End of Sheet MAT
