Cartesian Coordinates - Introduction to Quantum Mechanics - Exam, Exams of Quantum Mechanics

This is the Exam of Introduction to Quantum Mechanics which includes Wavefunctions Valid, Bound State Solutions, One Bound State, Lowering Operators, State Vector, Arbitrary Complex Number, Energy of Electron, Approximate Energy etc. Key important points are: Cartesian Coordinates, Infinitesimally Small Rotation, Axis of Wavefunction, Angular Momentum Component, Spherical Coordinates, Eigenfunctions, Harmonic Oscillator Hamiltonian, Step Operators

Typology: Exams

2012/2013

Uploaded on 03/07/2013

noshe
noshe 🇮🇳

4.1

(12)

57 documents

1 / 2

Toggle sidebar

This page cannot be seen from the preview

Don't miss anything!

bg1
NIU Physics PhD Candidacy Exam Spring 2010 Quantum Mechanics
DO ONLY THREE OUT OF FOUR QUESTIONS
Problem 1. In many systems, the Hamiltonian is invariant under rotations. An example is the
hydrogen atom where the potential V(r) in the Hamiltonian
H=p2
2m+V(r),
depends only on the distance to the origin.
An infinitesimally small rotation along the z-axis of the wavefunction is given by
Rz,dϕψ(x, y , z) = ψ(xydϕ, y +xdϕ, z),
(a) Show that this rotation can be expressed in terms of the angular momentum component
Lz. [10 points]
(b) Starting from the expression of Lzin Cartesian coordinates, show that Lzcan be related to
the derivative with respect to ϕin spherical coordinates. Derive the ϕ-dependent part of the
wavefunction corresponding to an eigenstate of Lz. [10 points]
(c) Show that if Rz,dϕ commutes with the Hamiltonian, then there exist eigenfunctions of Hthat
are also eigenfunctions of Rz,dϕ . [10 points]
(d) Using the fact that Liwith i=x, y, z commute with the Hamiltonian, show that L2commutes
with the Hamiltonian. [10 points]
Problem 2. To an harmonic oscillator Hamiltonian
H= ¯hωaa,
we add a term
H=λ(a+a).
This problem is known as the displaced harmonic oscillator. It can be diagonalized exactly by
adding a constant (let us call it ∆) to the step operators.
(a) Express the constant in terms of ¯ and λ. [8 points]
(b) The energies are shifted by a constant energy. Express that energy in terms of ¯ and λ. [8
points]
(c) Express the new eigenstates |˜niin terms of the displaced oscillator operator ˜a. [8 points]
(d) Calculate the matrix elements h˜n|0i.[8 points]
(e) An harmonic oscillator is in the ground state of H. At a certain time, the Hamiltonian
suddenly changes to H+H. Plot the probability and change in energy for the final states |˜ni
for ˜n= 0,···,5 for = 2. [8 points]
pf2

Partial preview of the text

Download Cartesian Coordinates - Introduction to Quantum Mechanics - Exam and more Exams Quantum Mechanics in PDF only on Docsity!

NIU Physics PhD Candidacy Exam – Spring 2010 – Quantum Mechanics DO ONLY THREE OUT OF FOUR QUESTIONS

Problem 1. In many systems, the Hamiltonian is invariant under rotations. An example is the hydrogen atom where the potential V (r) in the Hamiltonian

H =

p^2 2 m

  • V (r),

depends only on the distance to the origin. An infinitesimally small rotation along the z-axis of the wavefunction is given by

Rz,dϕψ(x, y, z) = ψ(x − ydϕ, y + xdϕ, z),

(a) Show that this rotation can be expressed in terms of the angular momentum component Lz. [10 points] (b) Starting from the expression of Lz in Cartesian coordinates, show that Lz can be related to the derivative with respect to ϕ in spherical coordinates. Derive the ϕ-dependent part of the wavefunction corresponding to an eigenstate of Lz. [10 points] (c) Show that if Rz,dϕ commutes with the Hamiltonian, then there exist eigenfunctions of H that are also eigenfunctions of Rz,dϕ. [10 points] (d) Using the fact that Li with i = x, y, z commute with the Hamiltonian, show that L^2 commutes with the Hamiltonian. [10 points]

Problem 2. To an harmonic oscillator Hamiltonian

H = ¯hωa†a,

we add a term

H′^ = λ(a†^ + a).

This problem is known as the displaced harmonic oscillator. It can be diagonalized exactly by adding a constant (let us call it ∆) to the step operators. (a) Express the constant ∆ in terms of ¯hω and λ. [8 points] (b) The energies are shifted by a constant energy. Express that energy in terms of ¯hω and λ. [ points] (c) Express the new eigenstates |n˜〉 in terms of the displaced oscillator operator ˜a†. [8 points] (d) Calculate the matrix elements 〈˜n| 0 〉.[8 points] (e) An harmonic oscillator is in the ground state of H. At a certain time, the Hamiltonian suddenly changes to H + H′. Plot the probability and change in energy for the final states |n˜〉 for ˜n = 0, · · · , 5 for ∆ = 2. [8 points]

Problem 3. We consider scattering off a spherical potential well given by

V (r) =

{ −V 0 r ≤ a 0 r > a

V 0 , a > 0

The particles’ mass is m. We restrict ourselves to low energies, where it is sufficient to consider s wave scattering (angular momentum l = 0). (a) Starting from the Schr¨odinger equation for this problem, derive the phase shift δ 0 .[14 points] (b) Calculate the total scattering cross section σ assuming a shallow potential well

(a

√ 2 mV 0 /h¯^2 ≪ 1). [10 points] (c)Show that the same total scattering cross section σ as in b) is also obtained when using the Born approximation. Note: part c) is really independent of parts a) and b). [16 points]

Problem 4. The normalized wavefunctions for the 2s and 2p states of the hydrogen atom are:

ψ 2 s =

32 πa^3

(N − r/a) e−r/^2 a

ψ 2 p, 0 =

32 πa^3

(r/a) e−r/^2 a^ cos θ

ψ 2 p,± 1 =

64 πa^3

(r/a) e−r/^2 a^ sin θ e±iφ.

where a is the Bohr radius and N is a certain rational number. (a) Calculate N. (Show your work; no credit for just writing down the answer.) [10 points] (b) Find an expression for the probability of finding the electron at a distance greater than a from the nucleus, if the atom is in the 2p, +1 state. (You may leave this answer in the form of a single integral over one variable.) [10 points] (c) Now suppose the atom is perturbed by a constant uniform electric field E~ = E 0 ˆz. Find the energies of the 2s and 2p states to first order in E 0. [20 points]