Ch. 9 Worksheet, Exercises of Geometry

The molecular geometry of phosphorus trichloride PCl3 is . a) trigonal planar b) trigonal pyramidal c) tetrahedral d) bent e) T–shape.

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Ch. 9 Worksheet
Supplemental Instruction
Iowa State University
Leader:
Tina
Course:
Chem 177
Instructor:
Dr. Appy
Date: 4/8/15
1. How many sigma and pi bonds does are in a molecule of ethyne (acetylyene), HCCH?
a) 1 sigma, 1 pi
b) 2 sigma, 1 pi
c) 2 sigma, 3 pi
d) 3 sigma, 2 pi
2. Which bonds are formed by a Carbon atom with sp2 hybridization?
a) 4 pi bonds
b) 2 pi bonds and 2 sigma bonds
c) 1 pi bonds and 3 sigma bonds
d) 4 sigma bonds
3. How many sigma bonds does propyne have? (What’s the formula of propyne?)
a) 2 b) 4 c) 6 d) 8
4. In the Lewis structure for SCl2O, the formal charges are: on S, on the Cl atoms, and on O.
a) 0, 0, 0 b) +1, 0, –2 c) +1, 0, –1 d) +4, –1, –2 e) –1, 0, +1
5. Based on VSEPR theory, which should have the smallest XAX bond angle?
6. The molecular geometry of phosphorus trichloride PCl3 is .
a) trigonal planar b) trigonal pyramidal c) tetrahedral
d) bent e) T–shape
7. What is the approximate ClPCl bond angle in phosphorus trichloride PCl3?
a) 90˚ b) 109.5˚ c) 120˚ d) 180o
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Ch. 9 Worksheet

Supplemental Instruction Iowa State University

Leader: Tina Course: Chem 177 Instructor: Dr. Appy Date: 4/8/

  1. How many sigma and pi bonds does are in a molecule of ethyne (acetylyene), HCCH?

a) 1 sigma, 1 pi b) 2 sigma, 1 pi c) 2 sigma, 3 pi d) 3 sigma, 2 pi

  1. Which bonds are formed by a Carbon atom with sp2 hybridization? a) 4 pi bonds b) 2 pi bonds and 2 sigma bonds c) 1 pi bonds and 3 sigma bonds d) 4 sigma bonds
  2. How many sigma bonds does propyne have? (What’s the formula of propyne?)

a) 2 b) 4 c) 6 d) 8

  1. In the Lewis structure for SCl 2 O, the formal charges are: on S, on the Cl atoms, and on O.

a) 0, 0, 0 b) +1, 0, –2 c) +1, 0, –1 d) +4, –1, –2 e) –1, 0, +

  1. Based on VSEPR theory, which should have the smallest XAX bond angle?
  2. The molecular geometry of phosphorus trichloride PCl 3 is.

a) trigonal planar b) trigonal pyramidal c) tetrahedral d) bent e) T–shape

  1. What is the approximate Cl P Cl bond angle in phosphorus trichloride PCl 3?

a) 90˚ b) 109.5˚ c) 120˚ d) 180 o

  1. The bond angles marked a, b, and c in the molecule below are approximately , , and , respectively.

a) 109.5˚, 109.5˚, 109.5˚

c) 109.5˚, 109.5˚, 90˚ d) 90˚, 90˚,90˚

e) 109.5˚, 109.5˚, 120˚

  1. A. (2 pts) Draw the Lewis structure for PCl 3 F 2. Include lone pairs.

B. (2 pts) The more electronegative are the atoms bonded to the central atom, the less are the repulsions between the electron pairs in the bonds. On the basis of this statement, draw the most probable structure of the molecule PCl 3 F 2. If you did not arrive at a Lewis structure in part A, use this:

F S

F

C. (2 pts) What is the name of the shape or geometry of the molecule?

D. (3 pts) indicate the bond angles in the molecule. “A” refers to the central atom.

Bond angle F – A – Cl

Cl – A – Cl

F – A – F

E. (1 pts) Is this molecule polar or nonpolar?

Cl

b) 120˚, 109.5˚, 120˚

F

F Cl