Properties & Behavior of Representative Elements: Hydrogen, Alkali & Alkaline Earth Metals, Exams of Construction

An in-depth analysis of the representative elements in the periodic table, including hydrogen, alkali metals, alkaline earth metals, boron group, carbon group, nitrogen group, oxygen group, and halogens. It covers their electron configurations, properties, reactions, and important compounds.

Typology: Exams

2021/2022

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Chapter 18:
The
Representative
Elements
oHydrogen
oGroup 1A
oGroup 2A
oGroup 3A
oGroup 4A
oGroup 5A
oGroup 6A
oGroup 7A
oGroup 8A
1
Big Idea: The structure of atoms
determines their
properties;
consequently, the
behavior of elements is
related to their
location in the
periodic table. In
general nonmetallic
character becomes
more pronounced
toward the right of the
periodic table.
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Chapter 18:

The

Representative

Elements

o Hydrogen o Group 1A o Group 2A o Group 3A o Group 4A o Group 5A o Group 6A o Group 7A o Group 8A 1 Big Idea: The structure of atoms determines their properties; consequently, the behavior of elements is related to their location in the periodic table. In general nonmetallic character becomes more pronounced toward the right of the periodic table.

The Representative Elements

2

Hydrogen

๏‚› Electron configuration is

1s

1

(similar to the electron

configurations of group

1A elements)

๏‚› Classified as a non metal

๏‚› Therefore it doesnโ€™t fit

into any group

4

Hydrogen

๏‚› Most H is made up of only two particles (an

electron and a proton)

๏‚› H is the most abundant element in the universe

and accounts for 89% of all atoms

๏‚› Little free H on earth

๏‚› H

2

gas is so light that it moves very fast and can

escape the Earthโ€™s gravitational pull

๏‚› Need heavier planets to confine H

2 5

๏‚› Strong polarizing power ๏‚› Forms bonds with highly covalent character ๏‚› Used in ceramics, Lubricants, Medicine (lithium carbonate (treatment for bipolar disorder)) ๏‚› Mined as rock salt which is a deposit of sodium chloride left as ancient oceans evaporated ๏‚› Extracted using electrolysis of molten NaCl (Downs process) 7 Lithium Sodium

Important Group ๏‚› NaCl ๏‚› NaOH ๏‚› NaHCO 3 (Baking Soda) ๏‚› HCO 3

  • (aq) + HA(aq) ๏ƒ  A - (g) + H 2 O(l) +CO 2 (g) ๏‚› The weak acid (HA) must be present in the dough; Some weak acids are sour milk, buttermilk, lemon jucie, or vinegar. ๏‚› KNO 3 ๏‚› 2KNO 3 (s) โˆ† 2KNO 2 (s) + O 2 (g) Note: Baking powder contains a solid weak acid as well as the hydrogen carbonate therefore CO 2 (g) is released when water is added 8

๏‚› Electron configuration is ns 2 (n is the period number). ๏‚› All group 2 element are too reactive to occur in the uncombined state in nature. ๏‚› Usually found as doubly charged cations. ๏‚› All group 2 elements except for beryllium react with water and the vigor of the reaction increases going down the group. 10 The Alkaline Earth Metals

๏‚› Has some non metal tendencies ๏‚› The gemstone emerald contains Be but its green color is caused by Cr 3+ ions ๏‚› Obtained by the electrolytic reduction of molten beryllium chloride ๏‚› Found in sea water ๏‚› The element of rigidity and construction (bones, shells, concrete, mortar, limestone (buildings)โ€ฆ) 11 Beryllium Magnesium Calcium ๏‚› Found in sea water ๏‚› Mg is present in the chlorophyll molecule ๏‚› Forms protective oxide ๏‚› Obtained by either chemical or electrolytic reduction of its compounds

Common Reactions ๏‚› Reaction with Halogens ๏‚› M + X 2 ๏ƒ  MX 2 X 2 is any halogen ๏‚› Reaction with Oxygen ๏‚› 2M + O 2 ๏ƒ  2MO ๏‚› Reaction with H ๏‚› M + H 2 ๏ƒ  MH 2 ๏‚› Reaction with N ๏‚› 3M + N 2 ๏ƒ  M 3 N 2 High temperatures ๏‚› Reaction with Water ๏‚› M +2H 2 O ๏ƒ  M(OH) 2 + H 2 ๏‚› Reaction with Ions ๏‚› M + 2H

๏ƒ  M 2+

  • H 2 13

๏‚› Electron configuration is ns 2 np 1 (n is the period number). ๏‚› Boron and aluminum almost always have an oxidation number of +3. ๏‚› The heavier elements of the group are more likely to keep their s electrons and can have oxidation numbers of + or +3. 14

Important Compounds ๏‚› B(OH) 3 (Boric Acid) ๏‚› Na 2 B 4 O 7 ยท10H 2 O(borax) ๏‚› Al 2 O 3 (Aluminum oxide or alumina) 16

Common Reactions ๏‚› Reaction with Halogens ๏‚› 2M +3X 2 ๏ƒ  2MX 3 X 2 any halogen, TI gives as TIX well, but no TII 3 ๏‚› Reactions with O ๏‚› 4M + 3O 2 ๏ƒ  2M 2 O 3 ๏‚› Reactions with N ๏‚› 2M +N 2 ๏ƒ  2MN ๏‚› Reactions with ions ๏‚› 2M + 6H

๏ƒ  2M 3+

  • 3H 2 ๏‚› 2M + 2OH
    • 6H 2 O ๏ƒ  2M(OH) 4
  • 3H 2

๏‚› Central element to life

๏‚› Nonmetallic properties

๏‚› Forms Covalent bonds

with nonmetals and ionic

bonds with metals

๏‚› Small radius allows for the

wide occurrence of C=C

and C=O bonds in

compounds

๏‚› Central element to

electronic technology

and artificial intelligences.

๏‚› Larger atomic size than C

which results in relatively

few compounds that

have Si=Si and Si=O

bonds.

19 Carbon (^) Silicon

๏‚› Germanium is

recovered from

the flue dust of

industrial plants

processing zinc

ores.

๏‚› Germanium is

mainly used in

the

semiconductor

industry.

๏‚› Tin is easily

obtained from it

ore (cassiterite

(SnO

2

)) by

reduction with

carbon.

๏‚› Tin is expensive

and not very

strong but it is

resistant to

corrosion.

20

๏‚› Lead is durable

and malleable

which makes it

useful in the

construction

industry

๏‚› It is very dense

which makes it

ideal as

radiation shields

from x rays

Germanium Tin Lead