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chapter seven homework, Assignments of Organic Chemistry

University of Pittsburgh (Pitt) - Medical Center-Health SystemOrganic Chemistry

chapter 7 homework for professor k

Typology: Assignments

2024/2025

Uploaded on 03/02/2026

aman-rawal
aman-rawal 🇺🇸

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Chem 0310 Organic Chemistry 1 HW Problem Sets
Page 1 of 6
Chapter 7 HW Problem Set
Assigned Chapter 7 Textbook Problems (very important for problem practice):
7th edition: 25-26, 30-33, 35, 37-44, 46, 49, 53, 62-65
8th edition: 25-26, 30-33, 35, 37-39, 43-47, 49, 57, 66-69
Use all the assigned textbook problems above for practice. On this HW, show your work for five
individual problems that you consider representative from the assigned textbook problems. (e.g.
30a counts as one problem). Insert a blank page if more space is needed.
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Chapter 7 HW Problem Set Assigned Chapter 7 Textbook Problems (very important for problem practice):

7 th^ edition: 25 - 26, 30-33, 35, 37-44, 46, 49, 53, 62- 65

8th edition: 25 - 26, 30-33, 35, 37-39, 43-47, 49, 57, 66- 69

Use all the assigned textbook problems above for practice. On this HW, show your work for five individual problems that you consider representative from the assigned textbook problems. (e.g. 30 a counts as one problem). Insert a blank page if more space is needed.

Complete the following problems: Q1 : Answer the questions for the reaction below: a) Predict the product(s) of the reaction. b) Is the substrate optically active? Are the product(s) optically active as a mix? c) Draw the curved arrow mechanism for the reaction. d) What happens to the SN 1 reaction rate in each of these instances:

  1. Change the substrate to
  2. Change the substrate to
  3. Change the solvent from 100% CH 3 CH 2 OH to 10% CH 3 CH 2 OH + 90% DMF
  4. Increase the substrate concentration by 3-fold. Cl Br

Cl Br excess NaOCH 3 CH 3 OH Br KOC(CH 3 ) 3 Br acetone NaSCH 3 CH 3 OH KCl NaOC(CH 3 ) 3 HOC(CH 3 ) 3 Br D LDA (CH 3 CH 2 ) 2 O Cl LDA Cl LDA

Q6: Provide the reagents and conditions for the following reactions to make the product with a good yield. Cl NaOH Cl NaOH Br O Br Cl O Cl I