Understanding Polymers: Types, Synthesis, and Important Processes, Papers of Architecture

Explore the world of polymers, their role in our lives, and the two major methods of polymerization: addition and condensation. Learn about thermoplastic and thermosetting polymers, and the synthesis of specific polymers such as polyethylene, PVC, styrene, proteins, and copolymers like PET, Kevlar, nylon 66, and ceramics.

Typology: Papers

2020/2021

Uploaded on 02/19/2021

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Polymers
Polymers are extremely large molecules that are essential to our very existence.
They are a main constituent of our food (starch, protein, etc.), our clothes
(polyester, nylons, cotton, etc.), our houses (wood cellulose, paints, etc.), and our
bodies (poly (nucleic acids), proteins, etc.).
The word polymer derived from a Greek words (poly) meaning many and (meros)
meaning part.
Types of Polymers
Polymers can be separated into plastics, fibers and rubbers. As engineering
materials, it is appropriate to divide them into the following three categories:
1. Thermo-plastic polymers
2. Thermo-setting polymers
3. Elastomers
Thermoplastic polymer can be heated from a solid state to a viscous liquid state
and then cooled back down to solid, this heating and cooling cycle can be repeated
multiple times without degrading the polymer.
By contrast, thermosets change chemically when heated, which cross-links their
molecules and permanently sets these polymers.
Polymer Synthesis
There are two major types of' polymerization methods used to convert small
molecules (monomers) into polymers. These methods were originally referred to as
addition and condensation polymerization. Addition polymerization known as
chain-growth, or chain- reaction polymerization. Condensation polymerization is
now referred to as step-growth or step-reaction polymerization.
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Polymers

Polymers are extremely large molecules that are essential to our very existence. They are a main constituent of our food (starch, protein, etc.), our clothes (polyester, nylons, cotton, etc.), our houses (wood cellulose, paints, etc.), and our bodies (poly (nucleic acids), proteins, etc.). The word polymer derived from a Greek words (poly) meaning many and (meros) meaning part.

Types of Polymers

Polymers can be separated into plastics, fibers and rubbers. As engineering materials, it is appropriate to divide them into the following three categories:

  1. Thermo-plastic polymers
    1. Thermo-setting polymers
    2. Elastomers Thermoplastic polymer can be heated from a solid state to a viscous liquid state and then cooled back down to solid, this heating and cooling cycle can be repeated multiple times without degrading the polymer. By contrast, thermosets change chemically when heated, which cross-links their molecules and permanently sets these polymers.

Polymer Synthesis

There are two major types of' polymerization methods used to convert small molecules (monomers) into polymers. These methods were originally referred to as addition and condensation polymerization. Addition polymerization known as chain-growth, or chain- reaction polymerization. Condensation polymerization is now referred to as step-growth or step-reaction polymerization.

*Addition polymerization: 1 - The monomers employed in this type of polymerization contain carbon- carbon double bond (C=C) that can participate in a chain reaction. Chain-reactions normally afford polymers with high molecular weights. 2 - The mechanism of the polymerization consists of three distinct steps. a) In the Initiation Step an initiator molecule(s) is thermally decomposed or allowed to undergo a chemical reaction to generate an “active species.” This “active species,” which can be a free radical, a cation, or an anion, which then initiates the polymerization by adding to the monomer’s carbon-carbon double bond to open it. b) The Propagation Step, the newly generated “active species” adds to another monomer in the same manner as in the Initiation Step. This procedure is repeated over and over again until the final step of the process. c) Termination Step: the chain terminates through reaction with another growing chain, by reaction with another species in the polymerization mixture. Example: tetra-chloroethylene  Initiation by using peroxides (RO-OR) as initiator which thermally decomposed to generate active species (free radical RO.^ to attack the Π bond).  Propagation: the newly generated “active species” adds to another monomer in the same manner as in the initiation step.  Termination: end of the reaction and formation of polychloroethylene.

Each amino acid contains two functional groups: an amine group (-NH 2 ) and a carboxylic group (-COOH). Where R could be carbon and hydrogen atoms in some amino acids; in others it may include additional atoms such as oxygen, nitrogen or sulfur. Another example for condensation reaction: Synthesis of polyester

Poyethylene terephthalate (PET) is a copolymer is a combination of two or more different monomers. Other examples will be find in the handout  Synthesis of Kevlar  Synthesis of nylon 66  Synthesis of Ceramics