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Explore the world of polymers, their role in our lives, and the two major methods of polymerization: addition and condensation. Learn about thermoplastic and thermosetting polymers, and the synthesis of specific polymers such as polyethylene, PVC, styrene, proteins, and copolymers like PET, Kevlar, nylon 66, and ceramics.
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Polymers are extremely large molecules that are essential to our very existence. They are a main constituent of our food (starch, protein, etc.), our clothes (polyester, nylons, cotton, etc.), our houses (wood cellulose, paints, etc.), and our bodies (poly (nucleic acids), proteins, etc.). The word polymer derived from a Greek words (poly) meaning many and (meros) meaning part.
Polymers can be separated into plastics, fibers and rubbers. As engineering materials, it is appropriate to divide them into the following three categories:
There are two major types of' polymerization methods used to convert small molecules (monomers) into polymers. These methods were originally referred to as addition and condensation polymerization. Addition polymerization known as chain-growth, or chain- reaction polymerization. Condensation polymerization is now referred to as step-growth or step-reaction polymerization.
*Addition polymerization: 1 - The monomers employed in this type of polymerization contain carbon- carbon double bond (C=C) that can participate in a chain reaction. Chain-reactions normally afford polymers with high molecular weights. 2 - The mechanism of the polymerization consists of three distinct steps. a) In the Initiation Step an initiator molecule(s) is thermally decomposed or allowed to undergo a chemical reaction to generate an “active species.” This “active species,” which can be a free radical, a cation, or an anion, which then initiates the polymerization by adding to the monomer’s carbon-carbon double bond to open it. b) The Propagation Step, the newly generated “active species” adds to another monomer in the same manner as in the Initiation Step. This procedure is repeated over and over again until the final step of the process. c) Termination Step: the chain terminates through reaction with another growing chain, by reaction with another species in the polymerization mixture. Example: tetra-chloroethylene Initiation by using peroxides (RO-OR) as initiator which thermally decomposed to generate active species (free radical RO.^ to attack the Π bond). Propagation: the newly generated “active species” adds to another monomer in the same manner as in the initiation step. Termination: end of the reaction and formation of polychloroethylene.
Each amino acid contains two functional groups: an amine group (-NH 2 ) and a carboxylic group (-COOH). Where R could be carbon and hydrogen atoms in some amino acids; in others it may include additional atoms such as oxygen, nitrogen or sulfur. Another example for condensation reaction: Synthesis of polyester
Poyethylene terephthalate (PET) is a copolymer is a combination of two or more different monomers. Other examples will be find in the handout Synthesis of Kevlar Synthesis of nylon 66 Synthesis of Ceramics