CHM 255 Final Study Guide, Study notes of Organic Chemistry

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Ether Synthesis

too

Brv

To

or

Onlyfor (^10) 1k

0h

Electrophilic Addition Epoxides 4 1 04 I RE 1 1 af 111 et Mk 1 oh 1kg

Electrophilic Addition

É

you ma (^) I i Elec Nu you iT cut

Substitution Tmi re yothe Yi get o 3 EliminationJF 0H X (^) H O H xp n y If^ feb 4 EIim yiim.IT 4m L isime

CHM255 Final Exam

27 R R R R HBr Br^ Br 2 eq.

*also hydroboration/oxidation (1) BH 3 , 2) H 2 O 2 , NaOH)

Alkyne Reduction IN (^) my E^ W IE 64Eur

FL

minstII I m

wer

t Mechanism BjBr Br

Br Initiation

VF Br T H Br^ chainpropagation V _By Br (^) KVBr Br

voor (^) It Br EII.IE I Mechanism

SHE_ a

Base

Acid

F go Br 420 Mechanism NIH Br No Br N Fabr.tn^

BrtHz

Alcoholdehydrationt You notifying

a

El

Mechanism of Yoire Heo

Base

Acid

H2O

I

H

H3o

Alkyl

and Hydride^ Shifts^ possible A loxidations Oxidation Loss^ of (^) H2 or^ Gain^ of 0

Jones

10 Alcohol Carboxylic^ Acid

Alcohol Ketone 0H r OH 1 2 4 E PCC 1 Alcohol^ Aldehyde 2 Alcohol Ketone 0H E

I III 8

Mechanism

1 H2O 0 I 1 48 Stereoselectivity

1h RTngopeningofEpoxidesSN an in

an n.co an

Mechanism

450 kt as

Sn

Teast substituted and HS 8 M Base

t

I

mechanism

I H2o

81 hote Stereoselectivity ggo

tyn

afly