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helpful notes for chemistry for advance learners
Typology: Exercises
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1) Chemical reaction — Chemical changes or chemical reactions are the changes in which one or more new substances are formed. 2 ) Chemical Equations – Representation of a chemical reaction in terms of symbols and formulae of the reactants and products is known as chemical equation. 3) Balanced Chemical equations – The chemical equation in which the no. of atoms of different elements is same on both sides of the arrow is called balanced chemical equation. 4) The chemical reactions can be classified into different types such as— a) Combination reaction – The reactions in which two or more substances combine to form a new substance are called combination reaction. For example,
2Mg(s) + O 2 (g) 2 MgO (s) b) Decomposition reaction - The reaction in which a single compound breaks up into two or more simpler substances are called decomposition reactions. For example,
2Pb (NO 3 ) 2 (s) 2PbO (s) + 4NO 2 (g) +O 2 (g) The decomposition of a substance by passing electric current through it is known as electrolysis. The decomposition of a substance on heating is known as thermal decomposition. The decomposition of a substance by absorbing light energy is called photochemical decomposition. c) Displacement reactions -The chemical reactions in which a more reactive element displaces a less reactive element from a compound are known as displacement reactions. For example,
i) Zn (s) + CuSO 4 (aq) ZnSO 4 (aq) + Cu (s).
ii) Cu (s) + 2AgNO 3 (aq) Cu (NO 3 ) 2 (aq) +2Ag (s).
d) Double Displacement Reactions - The chemical reactions in which compounds react to form two different compounds by mutual exchange of ions are called double displacement reactions.
These reactions take place in solution two common types of this reaction are precipitation reactions and neutralization reactions i) Precipitation reaction : In this reactions, aqueous solution of two salts are mixed whereby
Some salts precipitate due to mutual exchange of ions between the two salts. For example AgNO 3 (aq) + NaCI (aq) -----> AgCl(s) + NaNO 3. ii) Neutralization reaction: In this type of reaction an acid reacts with a base to form salt and water by exchange of ions.
NaOH (aq) + HCl (aq) NaCl (aq) + H 2 O.
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e) Redox reaction: Chemical reaction which shows both oxidation and reduction reaction.
Oxidation: Reaction that involves the gain of oxygen or loss of hydrogen.
Reduction: Reaction that shows the loss of oxygen or gain of hydrogen.
Both oxidation and reduction take place simultaneously and hence called redox reaction. ZnO + C Zn + CO ZnO reduce to Zn ---- reduction C oxidize to CO ------oxidation f) Exothermic reaction and endothermic reaction: On the basis of energy changes during chemical reaction, they can be classified as i) Exothermic reaction: A chemical reaction in which heat energy is produced.
C + O 2 CO 2 (g) + heat ii) Endothermic reaction: A chemical reaction in which heat energy is absorbed.
CaCO 3 + Heat CaO + CO 2
5 Corrosion – The process of slow conversion of metals into their undesirable compounds due to their reaction with oxygen, water, acids, gases etc. present in the atmosphere is called corrosion. Rusting – Iron when reacts with oxygen and moisture forms red substance called rust.
6 Rancidity – The taste and odour of food materials containing fat and oil changes when they are left exposed to air for long time. This is called rancidity. It is caused due to oxidation of fat and oil present in food material. It can be prevented by using various methods such as by adding antioxidants to the food materials, Storing food in air tight container and by flushing out air with nitrogen.
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Instructions: Questions : 1 to 5 – 1 Mark each Questions : 6 to 9 – 2 Marks each Questions : 10 to 13 – 3 Marks each Question 14 – 5 Marks
H 2 S (^) (g) + Cl 2 S (^) (s) + HCl (^) (g)
Na 2 SO 4 + BaCl 2 _________ + ________
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a. Why can not a chemical change be normally reversed? b. Why is it always essential to balance a chemical equation? c. What happens when CO 2 gas is passed through lime water and why does it disappear on passing excess CO 2? d. Can rusting of iron take place in distilled water?
Q.1. A water insoluble substance ‗X‘ on reacting with dilute H 2 SO 4 released a colourless and odourless gas accompanied by brisk effervescence. When the gas was passed through water, the solution obtained turned blue litmus red. On bubbling the gas through lime water, it initially became milky and milkyness disappeared when the gas was passed in excess. Identify the substance ‗X‘. Write its chemical equations of the reactions involved. Ans. The water insoluble substance ‗X‘ is metal carbonate CaCO 3. CaCO3 (S) + H 2 SO4 (Aq) CaSO4(Aq) + H 2 O (^) (Aq) + O2 (G) Ca(OH) 2 + CO2 (G)CaCO3 (S) + H 2 O (^) (L) (milky) CaCO3 (S) + CO2 (G)+ H 2 O (^) (Aq)Ca(OH) 2 (milkiness)
Q.2. Ahmad took a magnesium ribbon (cleaned) and burned it on a flame. The white powder formed was taken in a test tube and water was added to it. He then tested the solution formed with red and blue litmus paper. What change was seen? Why? Ans. Red litmus paper turned blue. Blue litmus paper remained blue. This is because the magnesium ribbon on burning in air forms the white magnesium oxide. Which dissolved in water, it forms magnesium hydroxide, which is Basic in nature.
Q.3. Give one example of a combination reaction in which an element combines with a compound to give you a new compound. Ans. (^) O 2 + 2SO 2 2SO 3 8NH 3 + 3Cl 2 6NH 4 Cl
Q.4. Marble statues often slowly get corroded when kept in open for a long time. Assign a suitable explanation.
Q.5. Mohan tool pure water for the electrolytic decomposition of water but did not see any bubbles near the electrodes. Explain why? Q. 6 Rancidity is a process used for spoiling of cooked food materials like vegetables, etc. When kept for long time in open. How can you prevent such process to proceed? Give an example. Q. 7 A substance ‗X‘ displaces ‗Y‘ from its solution in water. It is called displacement reaction. What other chemical name can be given to such type of reactions? Explain, giving an example? Q. 8 A grey coloured metal ‗Z‘ (Atomic weight=65) is used in making dry cell. It reacts with dil. HCl to liberate a gas. What is the gas evolved? Calculate the minimum amount of ‗Z‘ required to produce 100 l 0f gas?
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