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eo hloro phyll - Mg Haemoglekin — Fe Page No | |e ee one: (6fog/a5 Vitamin B42 = © | ________Grnplex Gompounds ars awe fel Double. Sted iT a, a Additional | + Stable in cystine fom 7 {LE ©meounds J + Dissociate completely in its Wen: Noe ne tae gguecus solubon into rks _ ______Salts_mixed eg ether conctluent ions - ina Stoichiomebric rato + Give chemical test of a\lions. Gralite 1_Mehe’s salt KCl-MgCl,-GHaO | Fesos.. Cnty), S04 1 6420 Alurn 7 J 1 KeS04.Al, Go¢)a..24H20 / General “Brms Gmplex Salts + Sablein crystalline form -4-4-- © | C-ordinghion Humber + Also chable complex ion in qq. sol. >| _No-vt ew-ordinete bonds + Do not give chemical test of all form toy CMA with ligands i Gnentuen ions. i N= F Chock \igands x ie Cenbral Mekal ahem denkicity ) “ + Nacant orbital “+ lone pair acceptor Clete aid) © | Ligand 1+ Brg ordinate hand with \igande. elechron pai doer ( | lewis base Oxidaton state of CMA Form debve bond ith cma. |. Clharge_on dhe cma when all \igands with their electron are removed connected poir f with CMA ee ee SS lee i a a a ae a. 2 Anions ry Page No. vaudt Q Neutral ~ Pa - Atesitye \ Hw — agqtor | Denbicity Ne-ot ligating atoms pesemt ina ligand forms Cn) with cmA at same sr | Werner's —heory telenias Kee Cone | A cma in io com plex compounds show dype of valencies . Primary Seo » 0-3) > Oridakion state of Cha CN of ema + [This also known os ° G-ordinate. \ond foreneh fincigle ,Tonisoble, be by cma toith ligands. “Tonic valency } € None divectional in nature : Bhetenl te afl Don't ply Any ‘ole in Quemehy ‘ Recoil foe Geamekey = >_ tmp has tendency +o both \ ies Te distinguish between Gro Valemies Werner inteduce the _____| Squore racket +. enchse cma Ligand « Ce Code | ae Cia )o J Cla = x26) =0 Ak 600) 423(-D=0 [x20 M=43 OS |= 0. O-S= +3 CR |= Gxt) <6 CN = (61) = 6 Changing C0-S}) Fixed Cen’) id ® ih Rit, eater: i ans “% 6:4 — Dal a} “ulhich ot “he Btuisiny __Witl give _tahite ppb min with BAC), | Ss Us ou, 1] S04 | ©| Pihectve At. No- [ Sidguiek Rule [EAN = if Beth: =f (0. Sb) ~Cevat § d »| EAN i¢ the number of elector of CMA after frmation of tamplex d Rice So Sidgwick . the metal Tons Conkinue Accepting elecken paie 4 Gram ligands unl Ine EAN ot metal became equa | & dy fk -no-dt next therk gas. G A__| ligands Denkicity ON_| CN | “pe EAN 4) |KeLFe Cons CN | Mone | +2 Hemeleplic| 36 ) ik Go) et | ens | thars0[/49 Htndleptic| 35 3) a Cnt3)4) Ga_| Nis Mono |B Homete pic] 35 4) Ly; (CONTE Co Mone | AO} Hemelepte | SE. s) |G Gadla cr HO | Mon | +3 Homelepice] 33 6) (Goa, Cad, Co | Cle | “GE [43 Hderlypi¢ 36 1 ENCLDEae “Ag | Nig | Mono | +4 Hombotie | 5S ®) Creat | | Oe | tone fea | 4 | Hombre! 52 AIF IN PDF Le | o [gy 4) (re Gunde! t eb [Nas | tons [42 Horwlegtic! 84 & Sa or By [ones YOUVA | | | a: ne | = _| Atomic number of next noble qas =_36 ye E@®D. Follow _sidguiek_ vale uqlye ot x" =? | 26~ OF zC2)= 36 ete _De= 0 w=5 s+ FTupac Nemenceture & CGmplex Gmpsunde ~~ B_aattion is_precen'e CC then fs name alwayc unitten firsts @-ordiwahion ampuad. after tnak _covike pame of anion. oe iad Naming of _cordinats on Squaire | sphewe | spare : © | First £ all_ name A ligand is wrtten in alphabe cal order den name of CMA is antes Fdlowing Oridakom state in_Yoman numerals in brackeks. 2 FE mutiigte ligands ave present Dis © | Write them in alghabeli cal ordey , @ | Th case of abrevoked name of lind, tne Free alphabet 16 considered Ar alphabetral aedeae Prefixes di wei keto etc: ane used far wat tho liciby f same Vigands ® | TE ane ot Ligand — already Contain numeral profine s Cd; | Hhen ave use ig kvig ebeake) ©) |_ “TE complex fon a lis, F recent then name of CMA ~» ‘is_some as ‘he eloment . @ TH complex ion is anion, then name of metal ends with x Ye ’ For_some metalc their latin names are ged MT owitreris s§ Page No.: UPAC Examples Date: YOUVA | 4) Lo Quis) 4 Go). | Cls aera _ TTekraommine. diagua chromium +4 GW) +42) +3C4) <0 CI) chloride Xe4+Z 2) Wes Cen) 1. C504) “Wis Cothane = 4,2.- djammine) +3 G) x2-6=0 cobalt Car) A= +3. 3) Cou Cnn del . “Tetraommine. Copper CD) jon xr 4ED) = 2 4) [ fe Gho)s (nes) Fentagguaise thie Granake iron CD) ion Agia isethio cyanete 2) Cet Cn) Cen, |” Bis. Cote diamine.) Abie sul hate plokinam GE) on. Al CPt er, Cnitada J [Brg “Tekmammine dibromiie, plckinurn @ \omide 11 | CG Ow); sda fentacmmine carbonate cobalt CuL) chlovide tal Uco Gon): Cui), | “TWammine “Winibatle cbalt Cad in q\ cs @s] fents carbony| wn @) 19} CRh QWs); cn), ] “Tetra amine bithie Cyanaderhs dium Cw) 4 MT ow tf Fs Ss ws ben 2762 Ext HY Ex-2 Page No vm] Date: Ww) || CN; tial __Tetra.cyanonickelate Cen | 2 nUes Goods)” “Wioxalate cabal Car) jon (3) Ue Cone 1 Hexacy ancferrate CI) jon (4)| Nag Ceo Co} cadiumn Chexanitrite — N.) cabateate CIE) i Ka Cal Conde) | Pobassium vioxalate aluminate Cir) (6) Nag Care] Ceyolite | Heraflusro aluminate Cl) ion Galler ~cemnglex jon jon val are - [pe (NY) Grech Cons) | Ammine bromo ‘clove nitro -o = platinate @) \g] =f Ly Giro), Con pal Diaguatelralydroxe duminate GD) ien 9] [No)Cee) Ca). Cen), | Dichlorobis Celine - 4,2 diamsine) elainum CBD) nitrate ~ Ged ns_ 7 nd —>owter orbytal comple “Th ocbahedcal comglex, if Grt)d orbitals. areuced Rr hybvidis akon alsng with _ns. and ne. orbital then it i¢ Ase hybridisation - Sudy Complexes ave known as “Inner orbital / low spin paired | strong Seid | covalent Tn coset nd“ oital hybridisekon is _se%d* and Complexes are Known aS Outer orbital / High spin Sein Sree { Weak etd { Tonic com plexes } NOTE: On the basis of shyength trove are bwo typec of lig and. SFL —- Strong Bad \igand WEL 7 Weak field ligand SEL : WEL Paiving takes place «| the hybrid orbital used by metal ion pein = | >) T- “2 ar Sc <. Cy) < 8S < NOT < se7 < OH < | _C = donor > N=donor > O- donor > Helogen dense ke ee Se” Yd wet | CH, C007 <<. C2047 re Fe Hole NCS < EDTA < Nay eink < No < CHa < Cols < CN ~< Co. - - ale SFL ‘J/ NoTE . Th presence of 4d and Sd => SFL all metals - - rr Nty js Strong field ligand in presence of Fe a Mo, Cock as__ Weak field \igand . C04 * ack as 4 SFL in presence ot co. F ack os SFL in ecosence of Ni yi al a¢= - | Y.0 asa Strong Seld ligand in presence of a, a. = ea: | Cui Conal a+ 41) =-2 [ms 42 re Cada as" Wal lal] = Grd 3d® Ge" 4p CN” —> SFL ) } | 0 ee a CN = {x tah Aybridisakion = = dbo Magnetic = _Diamagnetic Geometry: = Square. planar Heture. Jeo il Unpaired dlechon = 0 a | a 4 a a, es el ee Page No YOUVA Dote | Gystal Field. “Theory Cet) eg = dx? y* dz? | aie Agenerated | es = day vay ne av ple evited bering 4 Kis Yeory, Cnt consi er ste pei conaide hegabve. poink charge and wevisal _Vigands ove consider og dipale point charge and there is { Herkractic. abtrackon ehween ligand and Cm. en_\j e 2 E - orbital \pave ine longer came energy and Srey split Premsslvec ints diferent gek of Energy levels. ec density - \olw axis [aa as dae. | Go density — ri axis ate < GS C day", d2? | ) SY ( “This Spitting ot orbrtals ys Koon oc Crystal Feld celifking. and : strength of Spitting depends upen__ sorting of ligands- ZAC ro + | Th_ockahedval complexes Z| Vigand apereaches CMAT along axis . As 4 Wesult sasy Cog) ovbikals _expierence more repulsion vs have. mare Snergy as Compared to to orbital. rsh = ) Code) ney + CAs ites + ne Neg—» No-fe7 in & ovbital Ao — Splitting energy of h iy —> No-of o7 in hog erbibal ockahedral Gra plex. h—> No: of paivs of e.7 P —» Painna enerey a ty A> : fairing takes: place _ Ligand—> SFL <{ + No pairs ey Lig ond —> WEL Mot ow tf Ff SS Page No. YOUVA eg Date A | \ a rn es song OE sil | [See Contre: | te Code] Fe Crd 94°” CN —> SFL—» fairing CN= 6 LI6 Ww ik----— -~--— 41% 4 \fokell€) i dsp" oekahedval Onpaived e =24 ( dimagne be [u=s | : Oni con asNie Gar] 34? G6" Ge? Gee = UCo.4a) 4 Cn= 4x1=4 ; (0.6A) 4 3p } C\ —> WEL —> No saivin = 24-64-34) 8 AU no Csé= 3p _ 0.844 a aula) 44 ee SS Av | AY eg —_M 1 WoT iF S$ os (46) Page No 4 YOUVA ” bate a allt i ca Ai wil bt \ 4’ Wl 4 lvl : ‘eg! aybitals paints directiy ak ligands , $0 ansymmebic Siling of cleckrons “eg” orbitals causes distortion 19 shah abeal qeemery obitele Kes blu Kigond. aperoching direction so ‘ ry kag Uneyeamels.cal Alling of elechron iy “is mbita| causes (xs dictertion which is negligible. | Fackors atfecting CFSE ® Qhage on OMT [cfse X charge on Cm kKalrecendel < ky Ure Conde] @ Geomeloy of_Comalex a4 A 4 >| Asp. ple plan re 4h 3 “LA sq.-planie > (\s > At r = Rouge Some Colourtyl sweets from _otfice ar ow 1 + =. 5 containing ualer | gc © 2 ome Veena YOuvA | Noncy eat nine jn Conteon Coyridoay i ee a a = —_ @ | Transikion — Series of. ot (mI _ etal 2 [3 BIA 2 aq< 4d < 5d : Gyddt < Gaad* < Gad 3d 4d qo ®) Seegly of Ligand K_CFSE Ce Gnd s Creamy s GeGodke l* > Ce Gud Shength : CN > No2 > Hoo > of” At= 4 4 ae ax He Glours in CC Due 4» unpaired 7 presentin CMT. CT Gc 13 HB | a" = [Ar] 3d G* 23) on a T= (rad? hs° ct 1] In a one d’ elechven 1S present in 42g (evel - TE Night corves ponding 4p categy of yellow ~ green region js absorbed by the Comm lx & it ect excite eC Ween he) Lease! 4 “eg! level As a veculk complex show \ed- violet cslour, Which is Com plementry colour of absarbe light. Copnp lex Compound show d-d trane'sti on (Th obsonce of ligand crystal fetd Se litting doec ast accur| and Com pound 1S. cileusess . LAT N Structure ne ke different bon ding " jsorm ers i ; = | youws | —— fn Metal and Ligand ') | Tonisation Amers Se These isomer give different ion im their selubien » This dye isomers occas when counter jon behave as_a “P tguids ~n Xhis isomers ligand & counter ion interchange usin each cher. eg: | UO (Ha) Br] Soy tho Leo (nita)s Br J “ S0y give udlyite colour pet of BaSSy with Bat? jon *) Linkage Asners * [Ty Ahese type of isomers atleack one embidented Vgand js present hese compounds have same melecular formula and_cunters ion bub but the meade of finkage of embidented lig and is Afferent - ’ oe 2) | Wydvaked comers” + {Th Wece compcunds Na-of Selvent molecules gre present as ligands Gas molecule of solvation Chydration ) are. “different » 9:| CrCls CHeo —> [Cr Gs) 10, —> Tor Giese Je] + G-ordinalion “Tsomens Anese isomers beth cattens and anions are comglen entitie “Tn these icomes Mutual exch ange “of lig ands takes place Leroeen these complex enti es Co Crtae J Cty Con) 6) Cou Cutts) ad [et OH | Cee Cnide) Lode) | CuGrs ] Teas] Stereo isomers : ate occur: e to different Spatial Ovrangement: ef Nigands arround Nye Cma - 1)| Geomelical Isomers Bigs = Similar ligand at adjacent pesitien mae a Trans —> Similar ligand at oppesite pasition | Gry taahebal t \ No GT pessible in tetrahedra! M @mplex bemuse relative positions “at 1 ey: of ligands ave same, ws0et each cher +| Gr in Square planay 4) | Cag }->[Neo ] | 4) (Nabe )—» 2 GT 2) [Mash _|—> No Gx 3)| LE Mab2}—> 2 G& =) Cab cd \-—> 352 €]| Cm Can) ak] —> No Gr eee ) tm Cag) ba_| —>_ No GT 8)) Um Ge) C2] —s No GT WL Ce) ob — 2Gz [im (a8)2_] — By Gr 
