Ionization Energy, Electron Affinity, and Magnetic Properties of Atoms, Quizzes of Chemistry

Definitions and trends for ionization energy, electron affinity, paramagnetic and diamagnetic properties of atoms. Ionization energy is the energy required to remove an electron from a gas-phase atom, while electron affinity is the energy released when an electron is added. The trends discussed are the increase in ionization energy and decrease in electron affinity as you move right or up on the periodic table, with exceptions for noble gases, 1/2 filled and filled subshells. Paramagnetic atoms have unfilled electron spots, while diamagnetic atoms have full electron configurations. Larger atoms exhibit more metallic character, and isoelectronic ions have the same electron configuration.

Typology: Quizzes

2010/2011

Uploaded on 03/27/2011

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TERM 1
Ionization Energy and
Trend
DEFINITION 1
Ionization energy (I.E.) is the change i n energy when one mole of
electrons is REMOVED from o ne mole of atoms in the GAS phase.
(Delta H is usually positive) The trend is that I.E. g ets larger as you
move RIGHT or UP on the periodic ta ble (smaller atoms are harder
to remove electrons from -Exception s: 1/2 filled and filled subshells
are more stable (harder to remove e lectrons from)
TERM 2
Electron Affinity and
Trend
DEFINITION 2
Electron Affinity (E.A.) is the energy c hange when 1 mole of
electrons is ADDED to 1 mole of atom s in the GAS phase. (Delta H
is usually negative) The t rend is that the 1st electron energy
decreases as you move RIGHT or UP on the periodic table -
Exceptions: Noble gases, 1/2 filled and filled subshells (smaller
atoms release more energy when a n electron is added)
TERM 3
Paramagnetic
DEFINITION 3
An atom is paramagnetic (i.e. it will respond to a magnetic
field) if there are unfilled spots on its electron configuration.
TERM 4
Diamagnetic
DEFINITION 4
An atom will be diamagnetic (doesn't respond to a magnetic
field) if all spots on its electron configuration are full.
TERM 5
Metallic Character
DEFINITION 5
Larger Atoms are more metallic
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TERM 1

Ionization Energy and

Trend

DEFINITION 1

Ionization energy (I.E.) is the change in energy when one mole of

electrons is REMOVED from one mole of atoms in the GAS phase.

(Delta H is usually positive) The trend is that I.E. gets larger as you

move RIGHT or UP on the periodic table (smaller atoms are harder

to remove electrons from -Exceptions: 1/2 filled and filled subshells

are more stable (harder to remove electrons from)

TERM 2

Electron Affinity and

Trend

DEFINITION 2

Electron Affinity (E.A.) is the energy change when 1 mole of

electrons is ADDED to 1 mole of atoms in the GAS phase. (Delta H

is usually negative) The trend is that the 1st electron energy

decreases as you move RIGHT or UP on the periodic table -

Exceptions: Noble gases, 1/2 filled and filled subshells (smaller

atoms release more energy when an electron is added)

TERM 3

Paramagnetic

DEFINITION 3

An atom is paramagnetic (i.e. it will respond to a magnetic

field) if there are unfilled spots on its electron configuration.

TERM 4

Diamagnetic

DEFINITION 4

An atom will be diamagnetic (doesn't respond to a magnetic

field) if all spots on its electron configuration are full.

TERM 5

Metallic Character

DEFINITION 5

Larger Atoms are more metallic

TERM 6

Isoelectronic

DEFINITION 6

2 or more ions with the same electron

TERM 7

Order of Electron

Configuration

DEFINITION 7

1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s,

5f, 6d, 7p

TERM 8

# of electrons in each shell

DEFINITION 8

s-shell: 2 electrons p-shell: 8 electrons d-shell: 10 electrons f-

shells: 14 electrons