Exploring the Factors Affecting the Rate of the Iodine Clock Reaction, Slides of Electrodynamics

This article from the canadian science fair journal discusses an experiment investigating how temperature, concentration of vitamin c, stirring, and solvent volume impact the iodine clock reaction. The author hypothesizes and tests these variables to understand how they control the reaction's speed.

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ARTICLE
The Canadian Science Fair Journal
CSFJ | Vol. 1 | Issue 1
© Suuronen 2018
the seawater reacted with the calcium carbonate of the shell,
Reac-
tion A is a slow reaction in which hydrogen peroxide reacts with
iodine that produces a chemical that looks like this: I3. This is
called triiodide. As soon as each triiodide chemical is produced,
it immediately gets consumed by Reaction B.
Reaction A: Hydrogen Peroxide + Iodine → Triiodide + Water
Reaction B is a fast reaction that uses vitamin C to change the
triiodide back to iodine, which keeps the solution clear.
Reaction B: Triiodide + Vitamin C → Iodine + Sulfur Derivative
Eventually, the vitamin C that is keeping the solution from turn-
ing blue runs out, and the triiodide chemicals are not being con-
sumed by Reaction B anymore. Now triiodide reacts with the
starch, and this results in the solution turning a dark blue.
Triiodide + Starch Starch → Complex (blue)
The competing reactions (Reactions A vs. B) explain the delayed
colour change in the experiment.
INTRODUCTION
A chemical reaction is a process in which one or more mol-
ecules react with each other and are changed into other mol-
ecules. These are a part of many of the things we use or benefit
from every day. For example, batteries, car engines, and plas-
tics all require chemical reactions. Since chemical reactions
are so significant in our lives, understanding how we can con-
trol them is very important. For example, this would help with
product safety and for getting the most out of the products that
use chemistry. The iodine clock reaction is a chemical reac-
tion that can teach the basic principles of controlling chem-
istry. The iodine clock reaction is when two clear liquids are
mixed, resulting in another clear liquid. After a few moments,
the liquid instantaneously turns dark blue. The reason that the
solution remains clear momentarily is because there are two
competing reactions: Reaction A and Reaction B (Figure 1).
Iodine Clock Reaction
Ava Suuronen1
1Westboro Academy, 200 Brewer Way, Ottawa, ON K1S 5R2
PURPOSE
The purpose of this experiment is to determine how changing different
variables can affect the rate of the iodine clock reaction. The variables
to be tested are:
1) Temperature
2) Concentration of vitamin C
3) Stirring
Figure 1.
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The Canadian Science Fair Journal

CSFJ | Vol. 1 | Issue 1 © Suuronen 2018 the seawater reacted with the calcium carbonate of the shell, Reac- tion A is a slow reaction in which hydrogen peroxide reacts with iodine that produces a chemical that looks like this: I3. This is called triiodide. As soon as each triiodide chemical is produced, it immediately gets consumed by Reaction B. Reaction A: Hydrogen Peroxide + Iodine → Triiodide + Water Reaction B is a fast reaction that uses vitamin C to change the triiodide back to iodine, which keeps the solution clear. Reaction B: Triiodide + Vitamin C → Iodine + Sulfur Derivative Eventually, the vitamin C that is keeping the solution from turn- ing blue runs out, and the triiodide chemicals are not being con- sumed by Reaction B anymore. Now triiodide reacts with the starch, and this results in the solution turning a dark blue. Triiodide + Starch Starch → Complex (blue) The competing reactions (Reactions A vs. B) explain the delayed colour change in the experiment.

INTRODUCTION

A chemical reaction is a process in which one or more mol- ecules react with each other and are changed into other mol- ecules. These are a part of many of the things we use or benefit from every day. For example, batteries, car engines, and plas- tics all require chemical reactions. Since chemical reactions are so significant in our lives, understanding how we can con- trol them is very important. For example, this would help with product safety and for getting the most out of the products that use chemistry. The iodine clock reaction is a chemical reac- tion that can teach the basic principles of controlling chem- istry. The iodine clock reaction is when two clear liquids are mixed, resulting in another clear liquid. After a few moments, the liquid instantaneously turns dark blue. The reason that the solution remains clear momentarily is because there are two competing reactions: Reaction A and Reaction B (Figure 1).

Iodine Clock Reaction

Ava Suuronen^1

(^1) Westboro Academy, 200 Brewer Way, Ottawa, ON K1S 5R

PURPOSE

The purpose of this experiment is to determine how changing different variables can affect the rate of the iodine clock reaction. The variables to be tested are:

  1. Temperature
  2. Concentration of vitamin C
  3. Stirring Figure 1.

The Canadian Science Fair Journal CSFJ | Vol. 1 | Issue 1 © Suuronen 2018

HYPOTHESES

My prediction for the effect of temperature is that the solution will turn blue faster when it is warmer because, according to the par- ticle theory, particles will move faster in higher temperatures. My prediction for the concentration of vitamin C is that more of it will cause a delayed reaction in the solution, because there will be more chemicals to try and keep the solution clear. My prediction for the effect of stirring is that the solution will turn blue more quickly, because particles are constantly in motion, so if you make them move faster (which I will be doing while stirring), they will com- plete their “battle” more quickly. My prediction for the effect of concentration is that the solution will turn blue faster because the particles are closer together. MATERIALS :

  • Clear plastic cups
  • 1000 mg Vitamin C
  • Iodine (2%)
  • Hydrogen peroxide (3%)
  • Liquid starch
  • Safety goggles
  • Measuring spoons
  • Measuring cup METHODS Note: Each experiment was repeated two times. The final result is the average of the two separate experiments. Standard Clock Reaction Procedure
  1. Put on the safety goggles and put the vitamin C (powder form) in the first cup. Add 60 ml of warm water. Stir for at least 30 seconds. This will be LIQUID A.
  2. Now put 2.5 ml of LIQUID A into a new cup and add 60 ml of warm water and 5 ml of iodine. This is LIQUID B. You will no longer need LIQUID A.
  3. In the last cup, mix 60 ml of warm water, 15 ml of the hydrogen peroxide and 15 ml of the liquid starch. This is LIQUID C.
  4. Pour all of LIQUID B into LIQUID C. Pour them back and forth five times. Place the cup down, start the timer and observe. Stop the timer when the colour changes to dark blue. Testing the Effect of Temperature Follow the standard procedure but test three different water tem- peratures: ice-cold, room temperature, and hot (boiled). Once LIQ- UIDS B and C have been mixed, time how long it takes for the solution to turn blue. Testing the Effect of Vitamin C concentration Follow the standard procedure but double the amount of vitamin C. Once LIQUIDS B and C have been mixed, time how long it takes for the solution to turn blue. Testing the Effect of Stirring Follow the standard procedure but once LIQUIDS B and C have been mixed, stir the solution until it turns blue. Time how long it takes. Testing the Effect of Solvent Volume Follow the standard procedure but LIQUIDS B and C are dis- solved into 30 ml of water instead of 60 ml. OBSERVATIONS During the original experiment (standard procedure), after I had combined LIQUID B and LIQUID C, it was approximately three minutes until the mixed solution turned a burnt-orange colour, which, in a matter of seconds, changed to the deep blue colour that was expected. The next experiment, which was to double the amount of vitamin C, had the same results as the standard proce- dure, but it took almost 7 minutes. In the experiment where I tested the effect of temperature, the colour change occurred differently. When boiled hot water was used, the colour changed to blue on the second pour before even starting the timer. For the cold water experiment, the reaction occurred from the top of the glass to the bottom. It also took approximately 4.5 minutes, which was longer than when warm water was used. The next experiment, in which I tested the effect of stirring, had the same observations as seen for the standard procedure, but took only about 1.5 minutes. In the final experiment, where I only used ½ the amount of water, the colour changed to blue on the third pour, before starting the timer. ANALYSIS Please see Appendix for all figures. DISCUSSION This project demonstrates various ways that chemical reactions can be controlled. This was done by using the classic iodine clock reaction as an example. The first experiment variation that I did was the effect of the concentration of vitamin C. The purpose of this experiment was to find out if the concentration of vitamin C affected the final result. My hypothesis was that more vitamin C would cause a delayed reaction, which was correct. My tim- ing results may not be completely accurate because the vitamin C did not completely dissolve in solution (LIQUID A). Although I stirred the vitamin C mixture before taking the 2.5 ml of LIQUID A to mix with LIQUID B, it is possible that a different amount of undissolved vitamin C was taken each time. This would affect the

The Canadian Science Fair Journal CSFJ | Vol. 1 | Issue 1 © Suuronen 2018 Figure 3. Figure 4. Figure 1. Figure 2. APPENDIX