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Solutions to problems related to thermal velocities and the maxwell-boltzmann distribution. Topics include defining variables, calculating the number of particles with certain speeds, and determining the average density, mean free path, and collision frequency.
Typology: Assignments
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Problems Chapter 11
The Maxwell speed distribution (number of particles with speed in the range
dv) is
N (v)dv = 4πN
m
2 πkT
v
2 e
− mv
2 2 kT (^) dv
a) Define
x =
v
vm
, dx =
dv
vm
, vm =
2 kT
m
Then
∗ (x)dx = N (xvm)d (xvm) =
π
x
2 e
−x^2 dx
b) The total number of particles with v < v 0 is
P(v 0 ) =
∫ (^) v 0
0
dvN (v) =
∫ (^) x 0
0
dxN
∗ (x)
π
∫ (^) x 0
0
x
2 e
−x^2 dx
π
∫ (^) x 0
0
x
de
−x^2
dx
dx
π
∫ (^) x 0
0
d
xe−x
2
dx
d (x)
dx
e
−x^2
(^) dx
π
x 0 e
−x^20 −
∫ (^) x 0
0
e
−x^2 dx
c) For v 0 = vm, x 0 = 1 and
P(vm)
N
π
e
− 1 −
0
e
−x^2 dx
11-8 The definitions are
vm =
2 kT
m
, v =
8 kT
πm
, vrms =
3 kT
m
For the Oxygen molecule
m = 32 ∗ 1. 67 ∗ 10
− 27
a) For T = 300K
vm = 393. 8 , v = 444. 3 , vrms = 482. 3
b) For T = 1000K
vm = 2273, v = 2565, vrms = 2784
11-11 The average density is
n =
The mean free path is
π
σ =
π
πd
2 = 3. 85 ∗ 10
− 8
and the ratio of the mean free path to the particle diameter is
d
Finally, the collision frequency is
νc =
v
`
π
kT
m
πd
2 = 9. 9 ∗ 10
9