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The processes of deep water formation and upwelling in the ocean, and their role in heat redistribution between the atmosphere and ocean. It covers the physical properties of water, the effects of temperature and salinity on density, and the role of atmospheric and oceanic circulation in transferring heat from equatorial regions to high latitudes. The document also discusses the concept of latent heat and its importance in the earth's heat budget.
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This half session dealt with the construction of all conditions responsible for the observed global circulation patterns in the World Ocean. In a sense, we started the course from the very end, trying to build an ocean and understanding its physical structure (the water part in this case). The objective of the entire session is to understand the concept behind Figure 1 below:
Figure 1 : General circulation pattern of the ocean. Surface currents are indicated in red while deep currents are presented in blue.
In Figure 1, one can see that there is a link between surface circulation (red) and deep circulation (blue). Of course, to conserve mass, there must be a link between these wo circulation patterns. Areas of “deep water formation” will transfer water from the surface to the deep ocean whereas water returns to the surface via zones of upwelling. Transfer from the surface to the deep ocean will occur due to densification (increased density) of surface water (mostly through cooling but also through some increased salinity during ice formation and salt concentration in seawater). Upwelling will occur through physical transfer from current formation (Ekman circulation in eastern ocean basins) and as water is pushed up continental slope (like when the North Atlantic Deep Water is pushed up the slope of the Antarctic continent). These features are all shown in Figure 1 with areas of deep water formation as purple dots (North and South Atlantic), and areas of upwelling with blue‐to‐red arrows (eastern regions of ocean basins). Also note that surface currents are characterized by circular patterns, called gyres, in each oceanic basin for each hemisphere (Atlantic and Pacific each have 2 gyres, whereas the Indian has only 1).
The entire purpose of the first session was thus to bring all the elements necessary to comprehend the processes responsible for the ocean circulation illustrated in Figure 1. These elements are:
‐ Systems and cycles. Specifically, how mass and energy cycle through different section of a system (from the micro‐ to macro‐scales). In this section we emphasized notions of reservoir, flux, source/sink, residence time , steady state, as well as positive and negative feedback mechanisms.
‐ Physical properties of water and, in particular, how temperature and salinity affect the density of seawater. We also focused on heat capacity to explain the temperature changes different media experience (i.e. atmosphere vs. ocean, continents, vs. oceans, etc) when subjected to a gain or loss of heat.
‐ Heat budget of the earth , particularly with respect to the unbalance in incoming short wave radiations and outgoing long wave radiations that is observed in inter‐tropical vs. high latitude zones.
‐ Atmospheric circulation , as it is driven by that same unbalance in the earth heat budget and affected by the earth’s rotation ( Coriolis). The interplay of these processes then leads to global as well as seasonal wind patterns (e.g. easterlies/westerlies and monsoons, respectively).
‐ Surface ocean circulation , driven itself by the wind drag of constant winds and affected by coriolis, vorticity, and geostrophic forces. Except for the effect of local winds, the general surface ocean circulation follows the atmospheric High/Low distribution pattern with circular motion (gyres) in each ocean basin. The circulation is clockwise in the north hemisphere, and counterclockwise in the south hemisphere.
‐ Deep ocean circulation , driven by density formation in high latitude zones. Surface water can undergo large increases in density due to an interplay of salinity and temperature changes. When warm water cools, its density increases markedly. Similarly, when water increases in salinity, its density increases as well. The cooling of surface seawater in northern latitudes (e.g. sub‐Arctic seas and around Antartica) leads to an increase in its density and thus vertical transfer of water towards the deep ocean. Similarly, during sea ice formation, the expulsion of salts from the forming ice results in brine formation (increase in salinity in sea waters) and thus an increase in the water density. These processes lead to deep water‐mass formation, each with specific density conditions that help or prevent their mixing in the deep ocean.
‐ Global ocean circulation. The surface and deep ocean circulations are tied at both “ends” where surface water cools (at high latitudes) to form deep waters, and where deep waters are upwelled towards to surface (mostly on eastern boundaries of oceans) to reintegrate the surface circulation loops and eventually reach the cooling sites for another cycle. On average, a full ocean circulation cycle takes several hundred years to complete (~500 yrs) but this “mixing speed” is variable and can accelerate or decelerate depending on the rate of deep water formation (cooling, salinity changes) and upwelling (wind strength, atmospheric pressure oscillation).
‐ Earth climate balance. The relationship between atmospheric and ocean circulation, help redistribute heat from zones of surplus radiation (inter‐tropical zones) to zones of deficit (high latitudes). In low latitudes, the majority of the heat transfer occurs through ocean circulation, whereas atmospheric circulation is responsible for most of the heat transfer in mid‐ to high latitudes. Event such as hurricanes are rapid and natural “pressure valve” processes that transfer large amounts of heat from the inter‐tropical zones to mid‐latitude regions.
Figure 2 : Time exchange for exchange of air and water between the atmosphere and ocean.
Advantages of Cycle Approach
Disadvantages of Cycle Approach
Water molecule: Dipole Uneven charge Hydrogen bonds! (DNA anyone?) Higher energy requirement for change of state (solid to liquid, liquid to gaseous) than similar molecules. Make sure you can explain the figure below:
Figure 3 : Melting and boiling temperatures for water and a series of molecules with similar chemical composition.
The structure of the water molecule thus leads to very high energy requirements for changes of state ( Latent Heat ), in particular for changes between liquid to gaseous state. In the figure below, the heat required to for changes in phase (state) are illustrated as horizontal lines. This demonstrates that heat has to constantly be supplied to water for his change of phase without, however, resulting in any change of temperature. Latent heat is just that, and change in heat without a change in temperature. Note the much more important heat requirement for vaporization (580 cal/gram) than for fusion (80 cal/gram). Also note that this heat transfer is reversible, meaning that 540 cal of heat is released to the atmosphere when 1 gram of water vapor condensed (rain) and 620 cal of heat is released when 1 gram of vapor solidifies (snow). Latent heat is thus an important component of the earth heat redistribution process (e.g. evaporation in inter‐tropical zones and condensation in mid‐ to high latitudes).
Figure 4 : Heat and temperature changes in water across its phase change continuum.
We also spent some time on the concept of Heat Capacity. Heat capacity is defined as the quantity of heat required to raise the temperature of 1 gram of a substance by 1°C.
We used the concept of heat capacity to explain major differences in temperature observed between continents and oceans. This was then applied to explain the three following figures.
Figure 5 : Seasonal temperature curves at San Francisco (green) and Norfolk (blue). Both cities are located on the same latitude. Hence, differences are not due to solar radiation difference.
needs to be corrected for the effect of pressure. The resulting temperature is called Potential Temperature.
Change of Phase Density
During the transition from liquid to solid state, at the freezing point, the bond angle between oxygen and hydrogen atoms expands from about 105° to about 109°. This change allows ice to form a hexagonal crystal lattice. The space taken by 24 molecules in solid state could be occupied by 27 in the liquid state Water expands about 9%!
Ice has a density of 0.917 vs. ~1.000 g/cm3. Fresh water maximum density at ~4°C
Density
Density of seawater is affected by a combination of parameters: temperature (density when temperature), salinity (density when salinity), pressure (density when pressure). We can, however, remove the effect of pressure by using potential temperature (which itself is corrected for pressure).
Hence, seawater density can be calculated as a function of both temperature and salinity:
It is the density of a parcel of water of specific T and S that is brought up to the surface (no pressure effect!)
σT = ((1.02594/1.0000) – 1) x 1000 = 25.94 (No units!)
Figure 8 : Sigma‐T values for water of different salinity (S) and temperature (T). To obtain the density of seawater you need to use σT and integrate it in the following equation: Density = [(σT ×
10 ‐3) + 1] g/cm 3. Note also that you can obtain seawater of similar densities by varying S and T. The examples circled in red, blue, and green show seawater of similar densities (within each color code) despite changes in parameters (e.g. as temperature increases, salinity has to increase for the water to maintain the same density).
TemperatureSalinity (TS) Diagr ams In TS Diagrams (Figure 9), salinity (S) is represented on the x ‐axis while temperature (T) is represented on the y ‐axis. The sigma‐T (σT) lines indicate conditions of similar densities. The movement from the upper left to the lower right is a direction of increased density (the largest shift in density occurs when the movement is perpendicular to the σT lines).
Figure 9 : TS Diagram. Note: A drop of 5°C in warm water (25°C) generates a greater increase in density than a similar cooling in cold water (5°C). In short, the more perpendicular to the σT lines the change is, the more intense the change in density.
Plotting actual values of T and S on such a TS Diagram will give you the number of water masses in the water column and their specific T and S characteristics.
Figure 10 : Depth profiles of temperature and salinity for a station in the North Atlantic.
Light
Autotrophs – with a few exceptions – depend on energy from sunlight. As do land plants, marine plants use chlorophyll and other pigment to capture the visible light from the sun to perform photosynthesis. As solar radiation strikes the surface of the Ocean, a large fraction of it is reflected back to the atmosphere (dependent on the angle of the sun’s rays and the smoothness of the water surface).
The amount that enters is ultimately absorbed by water molecules (~65% of visible light is absorbed within 1 m depth!): Absorbed energy manifests itself as heat (elevating the temperature of the surface water)
Figure 13 : Spectrum of light absorption with respect to water depth. Absorption is greatest at longer wavelength. In clear water, only ~1% of surface energy remains at 100 m (in coastal waters with lots of particles, light doesn’t penetrate more than a few meters).
Based on the temperature of the sun and the earth, and on physical laws of radiation ( Stefan Boltzmann’s and Wien’s laws), the sun emits radiation mostly in the visible to ultra violet (UV), whereas the earth emits mostly in the infrared (IR) spectrum. These differences in radiation wavelengths are crucial to explain the earth actual vs. theoretical average temperature. Based on the solar radiation that earth receives per unit area, the theoretical temperature of the earth should be ‐18°C. But the actual temperature of earth is much higher than that (+15°C). The +33° difference can be explained by what is called the greenhouse effect. In short, gases in the atmosphere (e.g. water, CO 2 , CH 4 , CFCs, N 2 O) are relatively transparent to short wave radiation (meaning they let these pass through), whereas they absorb longer wavelength radiation. Figure 14 illustrates this process. The substantial absorption of IR back radiation by the earth atmosphere thus permits the earth to retain heat within in fluid envelope and thus warm beyond the theoretical value determined by solar radiation alone (Figure 15).
Figure 14 : Proportion of light absorption in the earth atmosphere with respect to radiation wavelength. There are two “window” of transparency. The atmosphere is nearly transparent to visible and near UV radiation (majority of solar radiation), whereas it absorbs strongly in the UV (from O 3 ) and near IR (water, CO 2 , CH 4 , CFCs, N 2 O). The second window is in the IR and permits some long wavelength radiation to escape the earth’s atmosphere.
Figure 15 : Warming of the earth by solar radiation alone (left) and through the combination of solar radiation and greenhouse effect (right).
Figure 16. Although average temperatures vary seasonally and spatially, the earth’s overall T changes only slightly over the years “must” return to space the same amount of energy it absorbed. Total energy input = 100 units (per unit time). Note: Albedo is the fraction of the sun radiation that is reflected back to space without being incorporated in the heat budget of earth.
Because of these geographical and temporal variations in short wave incoming radiation, long wave radiation also show similar variations (IR). The figure below illustrates these geographical and temporal differences.
Figure 17. Long wave radiation for the earth. Left hand panel: January. Right hand panel: June.
These figures show graphically that the there is an equator to pole change in incoming radiation ΔHeating as well as a seasonal change in incoming radiation ΔHeating.
The earth heat budget is thus apparently unbalanced with the inter‐tropical region apparently continuously gaining heat and the high latitude regions apparently continuously losing heat (Figure 18). However, because the inter‐tropical zones do not heat continuously or the high latitude regions do not freeze continuously, then heat transfer from zones of heat surplus to the zones of heat deficit must occur. This is the founding condition that leads to circulation patterns in the fluid envelopes of earth (atmosphere and ocean).
Figure 18 Short wave (Qs) minus long wave (Q (^) b ) radiation for the earth.