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PhD Comprehensive sum_{i} n_i
int_{T_0}^{T_c} c_{p,i}(T) dT = - m_dot_fuel *
Delta_H_comb,ref – Advanced Rocket
Propulsion
Duration: 60 minutes  Total Marks: 25
This examination assesses advanced understanding of thermodynamics, gas
dynamics, propulsion chemistry, and nozzle design in high-performance
liquid rocket systems. Answer all questions clearly, showing full derivations
and reasoning.
1.
Section A — (6 points)
1. A single-stage liquid rocket engine burns RP-1 (C₁₂H₂₆) with liquid oxygen
(LOX) as oxidizer. Given the chamber pressure Pc = 10 MPa, mixture ratio
O/F = 2.6 (by mass), and desired thrust F = 800 kN. Expansion ratio ε = 25,
propellant inlet temperature T₀ = 298 K. Assume ideal gas behavior and
products CO₂, H₂O, CO, H₂, O₂, N₂.
(a) Derive the general symbolic relation for the mass flow rate of fuel and
oxidizer required to achieve the specified thrust (based on later nozzle
analysis).
(b) Using the stoichiometric reaction of C₁₂H₂₆ with O₂, estimate the molar
composition of combustion products. Explain briefly (2–3 sentences) why
incomplete combustion (CO, H₂) may occur.
2.
Section B — (8 points)
2. Assuming all chemical energy converts into thermal energy of the
products (adiabatic, constant-pressure combustion), use the given reaction
enthalpy ΔH_comb,ref = –44,000 kJ/kg_fuel and polynomial Cp(T) relations
(provided in the data table) to numerically determine the adiabatic flame
temperature Tc from:
Type equation here .
Compute Tc, the mean γ = Cp/Cv, and molecular weight M
M of the product
mixture. Report all results clearly with assumptions and iteration method
used.
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PhD Comprehensive sum_{i} n_i

int_{T_0}^{T_c} c_{p,i}(T) dT = - m_dot_fuel *

Delta_H_comb,ref – Advanced Rocket

Propulsion

Duration: 60 minutes Total Marks: 25

This examination assesses advanced understanding of thermodynamics, gas

dynamics, propulsion chemistry, and nozzle design in high-performance

liquid rocket systems. Answer all questions clearly, showing full derivations

and reasoning.

Section A — (6 points)

  1. A single-stage liquid rocket engine burns RP-1 (C₁₂H₂₆) with liquid oxygen

(LOX) as oxidizer. Given the chamber pressure Pc = 10 MPa, mixture ratio

O/F = 2.6 (by mass), and desired thrust F = 800 kN. Expansion ratio ε = 25,

propellant inlet temperature T₀ = 298 K. Assume ideal gas behavior and

products CO₂, H₂O, CO, H₂, O₂, N₂.

(a) Derive the general symbolic relation for the mass flow rate of fuel and

oxidizer required to achieve the specified thrust (based on later nozzle

analysis).

(b) Using the stoichiometric reaction of C₁₂H₂₆ with O₂, estimate the molar

composition of combustion products. Explain briefly (2–3 sentences) why

incomplete combustion (CO, H₂) may occur.

Section B — (8 points)

  1. Assuming all chemical energy converts into thermal energy of the

products (adiabatic, constant-pressure combustion), use the given reaction

enthalpy ΔH_comb,ref = –44,000 kJ/kg_fuel and polynomial Cp(T) relations

(provided in the data table) to numerically determine the adiabatic flame

temperature Tc from:

Type equation here.

Compute Tc, the mean γ = Cp/Cv, and molecular weight M

M

of the product

mixture. Report all results clearly with assumptions and iteration method

used.

Section C — (6 points)

  1. Nozzle Design: Assuming choked flow at the throat (Mach = 1) and

isentropic expansion to exit, determine:

(a) The sonic velocity at the throat (using Tc and γ from Section B).

(b) The total mass flow rate ṁ required for F = 800 kN using the isentropic

thrust relation:

F = ṁV_e + (P_e – P_a)A_e, where P_a = 101.325 kPa.

(c) Compute throat area A_t and exit area A_e using the isentropic flow

relations with expansion ratio ε = 25.

Section D — (3 points)

  1. Accounting for viscous boundary-layer displacement at the throat

(reducing effective area by 2.5%), recalculate the effective mass flow rate

and thrust. Determine the percentage thrust loss compared to the ideal

case.

Section E — (2 points)

  1. Film Cooling Estimate: To limit the nozzle wall temperature to Tw = 900

K, estimate the minimum fraction of total mass flow that must be injected as

film coolant at T₀ = 298 K to maintain this wall temperature. Provide a brief

energy-based justification.

Data Summary (for reference):

Species a (kJ/kmol·K) b (×10⁻³

kJ/kmol·K²)

c (×10⁻⁶

kJ/kmol·K³)

CO₂ 22.26 5.981 –3.

H₂O 30.09 0.931 –0.

CO 28.01 0.167 0.

H₂ 29.0 –0.84 1.

O₂ 25.48 1.52 –0.

N₂ 29.0 0.0 0.