









Study with the several resources on Docsity
Earn points by helping other students or get them with a premium plan
Prepare for your exams
Study with the several resources on Docsity
Earn points to download
Earn points by helping other students or get them with a premium plan
This comprehensive document provides a detailed overview of various chemical concepts, including states of matter, atomic structure, chemical thermodynamics, electrochemistry, chemical kinetics, and surface chemistry. it delves into the properties and reactions of elements from different groups of the periodic table, such as s-block, p-block, and d-block elements. the document also covers fundamental concepts in organic chemistry, including alkanes, alkenes, alkynes, benzene, phenols, alcohols, aldehydes, ketones, carboxylic acids, and amines. furthermore, it includes mathematical concepts relevant to chemistry, such as functions, equations, and differential equations. This resource is invaluable for students seeking a thorough understanding of fundamental chemistry principles.
Typology: Schemes and Mind Maps
1 / 16
This page cannot be seen from the preview
Don't miss anything!










Note: The syllabus for JEE Advanced 2025 remains the same as JEE Advanced 2024.
General topics Concept of atoms and molecules; Dalton’s atomic theory; Mole concept; Chemical formulae; Balanced chemical equations; Calculations (based on mole concept and stoichiometry) involving common oxidation-reduction, neutralisation, and displacement reactions; Concentration in terms of mole fraction, molarity, molality and normality. States of Matter: Gases and Liquids Gas laws and ideal gas equation, absolute scale of temperature; Deviation from ideality, van der Waals equation; Kinetic theory of gases, average, root mean square and most probable velocities and their relation with temperature; Law of partial pressures; Diffusion of gases. Intermolecular interactions: types, distance dependence, and their effect on properties; Liquids: vapour pressure, surface tension, viscosity. Atomic Structure Bohr model, spectrum of hydrogen atom; Wave-particle duality, de Broglie hypothesis; Uncertainty principle; Qualitative quantum mechanical picture of hydrogen atom: Energies, quantum numbers, wave function and probability density (plots only), shapes of s , p and d orbitals; Aufbau principle; Pauli’s exclusion principle and Hund’s rule. Chemical Bonding and Molecular Structure Orbital overlap and covalent bond; Hybridisation involving s , p and d orbitals only; Molecular orbital energy diagrams for homonuclear diatomic species (up to Ne 2 ); Hydrogen bond; Polarity in molecules, dipole moment; VSEPR model
and shapes of molecules (linear, angular, triangular, square planar, pyramidal, square pyramidal, trigonal bipyramidal, tetrahedral and octahedral). Chemical Thermodynamics Intensive and extensive properties, state functions, First law of thermodynamics; Internal energy, work (pressure-volume only) and heat; Enthalpy, heat capacity, standard state, Hess’s law; Enthalpy of reaction, fusion and vapourization, and lattice enthalpy; Second law of thermodynamics; Entropy; Gibbs energy; Criteria of equilibrium and spontaneity. Chemical and Ionic Equilibrium Law of mass action; Significance of ∆𝐺 and ∆𝐺⊖^ in chemical equilibrium; Equilibrium constant ( K p and K c) and reaction quotient, Le Chatelier’s principle (effect of concentration, temperature and pressure); Solubility product and its applications, common ion effect, pH and buffer solutions; Acids and bases (Brønsted and Lewis concepts); Hydrolysis of salts. Electrochemistry Electrochemical cells and cell reactions; Standard electrode potentials; Electrochemical work, Nernst equation; Electrochemical series, emf of galvanic cells; Faraday’s laws of electrolysis; Electrolytic conductance, specific, equivalent and molar conductivity, Kohlrausch’s law; Batteries: Primary and Secondary, fuel cells; Corrosion. Chemical Kinetics Rates of chemical reactions; Order and molecularity of reactions; Rate law, rate constant, half-life; Differential and integrated rate expressions for zero and first order reactions; Temperature dependence of rate constant (Arrhenius equation and activation energy); Catalysis: Homogeneous and heterogeneous, activity and selectivity of solid catalysts, enzyme catalysis and its mechanism. Solid State
sodium chloride, sodium hydroxide, sodium hydrogen carbonate) and calcium (calcium oxide, calcium hydroxide, calcium carbonate, calcium sulphate). p - Block Elements Oxidation state and trends in chemical reactivity of elements of groups 13-17; anomalous properties of boron, carbon, nitrogen, oxygen, and fluorine with respect to other elements in their respective groups. Group 13 : Reactivity towards acids, alkalis, and halogens; preparation, properties, and uses of borax, orthoboric acid, diborane, boron trifluoride, aluminium chloride, and alums; uses of boron and aluminium. Group 14 : Reactivity towards water and halogen; allotropes of carbon and uses of carbon; preparation, properties, and uses of carbon monoxide, carbon dioxide, silicon dioxide, silicones, silicates, zeolites. Group 15 : Reactivity towards hydrogen, oxygen, and halogen; allotropes of phosphorous; preparation, properties, and uses of dinitrogen, ammonia, nitric acid, phosphine, phosphorus trichloride, phosphorus pentachloride; oxides of nitrogen and oxoacids of phosphorus. Group 16 : Reactivity towards hydrogen, oxygen, and halogen; simple oxides; allotropes of sulfur; preparation/manufacture, properties, and uses of dioxygen, ozone, sulfur dioxide, sulfuric acid; oxoacids of sulfur. Group 17 : Reactivity towards hydrogen, oxygen, and metals; preparation/manufacture, properties, and uses of chlorine, hydrogen chloride and interhalogen compounds; oxoacids of halogens, bleaching powder. Group 18 : Chemical properties and uses; compounds of xenon with fluorine and oxygen. d - Block Elements Oxidation states and their stability; standard electrode potentials; interstitial compounds; alloys; catalytic properties; applications; preparation, structure, and reactions of oxoanions of chromium and manganese. f - Block Elements
Lanthanoid and actinoid contractions; oxidation states; general characteristics. Coordination Compounds Werner’s theory; Nomenclature, cis-trans and ionization isomerism, hybridization and geometries (linear, tetrahedral, square planar and octahedral) of mononuclear coordination compounds; Bonding [VBT and CFT (octahedral and tetrahedral fields)]; Magnetic properties (spin-only) and colour of 3 d - series coordination compounds; Ligands and spectrochemical series; Stability; Importance and applications; Metal carbonyls. Isolation of Metals Metal ores and their concentration; extraction of crude metal from concentrated ores: thermodynamic (iron, copper, zinc) and electrochemical (aluminium) principles of metallurgy; cyanide process (silver and gold); refining. Principles of Qualitative Analysis Groups I to V (only Ag+, Hg2+, Cu2+, Pb2+, Fe3+, Cr3+, Al3+, Ca2+, Ba2+, Zn2+, Mn2+^ and Mg2+); Nitrate, halides (excluding fluoride), carbonate and bicarbonate, sulphate and sulphide. Environmental Chemistry Atmospheric pollution; water pollution; soil pollution; industrial waste; strategies to control environmental pollution; green chemistry. Basic Principles of Organic Chemistry Hybridisation of carbon; σ and π-bonds; Shapes of simple organic molecules; aromaticity; Structural and geometrical isomerism; Stereoisomers and stereochemical relationship (enantiomers, diastereomers, meso) of compounds containing only up to two asymmetric centres ( R , S and E , Z configurations excluded); Determination of empirical and molecular formulae of simple compounds by combustion method only; IUPAC nomenclature of organic molecules (hydrocarbons, including simple cyclic hydrocarbons and their mono-functional and bi-functional derivatives only); Hydrogen bonding
Rearrangement reactions of alkyl carbocation; Grignard reactions; Nucleophilic substitution reactions and their stereochemical aspects. Alcohols Physical properties; Reactions: esterification, dehydration (formation of alkenes and ethers); Reactions with: sodium, phosphorus halides, ZnCl 2 /concentrated HCl, thionyl chloride; Conversion of alcohols into aldehydes, ketones and carboxylic acids. Ethers Preparation by Williamson’s synthesis; C-O bond cleavage reactions. Aldehydes and Ketones Preparation of: aldehydes and ketones from acid chlorides and nitriles; aldehydes from esters; benzaldehyde from toluene and benzene; Reactions: oxidation, reduction, oxime and hydrazone formation; Aldol condensation, Cannizzaro reaction; Haloform reaction; Nucleophilic addition reaction with RMgX, NaHSO 3 , HCN, alcohol, amine. Carboxylic Acids Physical properties; Preparation: from nitriles, Grignard reagents, hydrolysis of esters and amides; Preparation of benzoic acid from alkylbenzenes; Reactions: reduction, halogenation, formation of esters, acid chlorides and amides. Amines Preparation from nitro compounds, nitriles and amides; Reactions: Hoffmann bromamide degradation, Gabriel phthalimide synthesis; Reaction with nitrous acid, Azo coupling reaction of diazonium salts of aromatic amines; Sandmeyer and related reactions of diazonium salts; Carbylamine reaction, Hinsberg test, Alkylation and acylation reactions. Haloarenes
Reactions: Fittig, Wurtz-Fittig; Nucleophilic aromatic substitution in haloarenes and substituted haloarenes (excluding benzyne mechanism and cine substitution). Biomolecules Carbohydrates : Classification; Mono- and di-saccharides (glucose and sucrose); Oxidation; Reduction; Glycoside formation and hydrolysis of disaccharides (sucrose, maltose, lactose); Anomers. Proteins : Amino acids; Peptide linkage; Structure of peptides (primary and secondary); Types of proteins (fibrous and globular). Nucleic acids : Chemical composition and structure of DNA and RNA. Polymers Types of polymerization (addition, condensation); Homo and copolymers; Natural rubber; Cellulose; Nylon; Teflon; Bakelite; PVC; Bio-degradable polymers; Applications of polymers. Chemistry in Everyday Life Drug-target interaction; Therapeutic action, and examples (excluding structures), of antacids, antihistamines, tranquilizers, analgesics, antimicrobials, and antifertility drugs; Artificial sweeteners (names only); Soaps, detergents, and cleansing action. Practical Organic Chemistry Detection of elements (N, S, halogens); Detection and identification of the following functional groups: hydroxyl (alcoholic and phenolic), carbonyl (aldehyde and ketone), carboxyl, amino and nitro.
Logarithms and their properties, permutations and combinations, binomial theorem for a positive integral index, properties of binomial coefficients. Matrices Matrices as a rectangular array of real numbers, equality of matrices, addition, multiplication by a scalar and product of matrices, transpose of a matrix, elementary row and column transformations, determinant of a square matrix of order up to three, adjoint of a matrix, inverse of a square matrix of order up to three, properties of these matrix operations, diagonal, symmetric and skew- symmetric matrices and their properties, solutions of simultaneous linear equations in two or three variables. Probability and Statistics Random experiment, sample space, different types of events (impossible, simple, compound), addition and multiplication rules of probability, conditional probability, independence of events, total probability, Bayes Theorem, computation of probability of events using permutations and combinations. Measure of central tendency and dispersion, mean, median, mode, mean deviation, standard deviation and variance of grouped and ungrouped data, analysis of the frequency distribution with same mean but different variance, random variable, mean and variance of the random variable. Trigonometry Trigonometric functions, their periodicity and graphs, addition and subtraction formulae, formulae involving multiple and sub-multiple angles, general solution of trigonometric equations. Inverse trigonometric functions (principal value only) and their elementary properties. Analytical Geometry
Two dimensions: Cartesian coordinates, distance between two points, section formulae, shift of origin. Equation of a straight line in various forms, angle between two lines, distance of a point from a line; Lines through the point of intersection of two given lines, equation of the bisector of the angle between two lines, concurrency of lines; Centroid, orthocentre, incentre and circumcentre of a triangle. Equation of a circle in various forms, equations of tangent, normal and chord. Parametric equations of a circle, intersection of a circle with a straight line or a circle, equation of a circle through the points of intersection of two circles and those of a circle and a straight line. Equations of a parabola, ellipse and hyperbola in standard form, their foci, directrices and eccentricity, parametric equations, equations of tangent and normal. Locus problems. Three dimensions: Distance between two points, direction cosines and direction ratios, equation of a straight line in space, skew lines, shortest distance between two lines, equation of a plane, distance of a point from a plane, angle between two lines, angle between two planes, angle between a line and the plane, coplanar lines. Differential Calculus Limit of a function at a real number, continuity of a function, limit and continuity of the sum, difference, product and quotient of two functions, L’Hospital rule of evaluation of limits of functions. Continuity of composite functions, intermediate value property of continuous functions.
General General Units and dimensions, dimensional analysis; least count, significant figures; Methods of measurement and error analysis for physical quantities pertaining to the following experiments: Experiments based on using Vernier calipers and screw gauge (micrometer), Determination of g using simple pendulum, Young’s modulus - elasticity of the material, Surface tension of water by capillary rise and effect of detergents. Specific heat of a liquid using calorimeter, focal length of a concave mirror and a convex lens using u-v method, Speed of sound using resonance column, Verification of Ohm’s law using voltmeter and ammeter, and specific resistance of the material of a wire using meter bridge and post office box. Mechanics Kinematics in one and two dimensions (Cartesian coordinates only), projectiles; Uniform circular motion; Relative velocity. Newton’s laws of motion; Inertial and uniformly accelerated frames of reference; Static and dynamic friction; Kinetic and potential energy; Work and power; Conservation of linear momentum and mechanical energy. Systems of particles; Centre of mass and its motion; Impulse; Elastic and inelastic collisions. Rigid body, moment of inertia, parallel and perpendicular axes theorems, moment of inertia of uniform bodies with simple geometrical shapes; Angular momentum; Torque; Conservation of angular momentum; Dynamics of rigid bodies with fixed axis of rotation; Rolling without slipping of rings, cylinders and spheres; Equilibrium of rigid bodies; Collision of point masses with rigid bodies. Forced and damped oscillation (in one dimension), resonance.
Linear and angular simple harmonic motions. Hooke’s law, Young’s modulus. Law of gravitation; Gravitational potential and field; Acceleration due to gravity; Kepler’s law, Geostationary orbits, Motion of planets and satellites in circular orbits; Escape velocity. Pressure in a fluid; Pascal’s law; Buoyancy; Surface energy and surface tension, angle of contact, drops, bubbles and capillary rise. Viscosity (Poiseuille’s equation excluded), Modulus of rigidity and bulk modulus in mechanics. Stoke’s law; Terminal velocity, Streamline flow, equation of continuity, Bernoulli’s theorem and its applications. Wave motion (plane waves only), longitudinal and transverse waves, superposition of waves; Progressive and stationary waves; Vibration of strings and air columns; Resonance; Beats; Speed of sound in gases; Doppler effect (in sound). Thermal Physics Thermal expansion of solids, liquids and gases; Calorimetry, latent heat; Heat conduction in one dimension; Elementary concepts of convection and radiation; Newton’s law of cooling; Ideal gas laws; Specific heats ( Cv and Cp for monoatomic and diatomic gases); Isothermal and adiabatic processes, bulk modulus of gases; Equivalence of heat and work; First law of thermodynamics and its applications (only for ideal gases); Second law of thermodynamics, reversible and irreversible processes, Carnot engine and its efficiency; Blackbody radiation: absorptive and emissive powers; Kirchhoff’s law; Wien’s displacement law, Stefan’s law. Electricity and Magnetism Coulomb’s law; Electric field and potential; Electrical potential energy of a system of point charges and of electrical dipoles in a uniform electrostatic field; Electric field lines; Flux of electric field; Gauss’s law and its application in
Diffraction due to a single slit. Polarization of light, plane polarized light; Brewster's law, Polaroids. Modern Physics Atomic nucleus; α, β and γ radiations; Law of radioactive decay; Decay constant; Half-life and mean life; Binding energy and its calculation; Fission and fusion processes; Energy calculation in these processes. Photoelectric effect; Bohr’s theory of hydrogen-like atoms; Characteristic and continuous X-rays, Moseley’s law; de Broglie wavelength of matter waves.