Magnetic Materials: Linear, Paramagnetic, Diamagnetic, and Ferromagnetic Properties - Prof, Study notes of Physics

The properties of magnetic materials, focusing on linear magnetic materials, paramagnets, diamagnets, and ferromagnets. Topics include the relation between magnetization and magnetic field intensity, magnetic susceptibility, paramagnetic and diamagnetic materials, and the concept of hysteresis in ferromagnetic materials. The document also includes examples of calculations involving magnetic fields and magnetic materials.

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Uploaded on 07/23/2009

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PHY481 - Lecture 30
Chapter 9 of PS, Sections 7.2.3, 7.2.4 of Griffiths
A. Linear magnetic materials
Linear magnetic materials are characterized by a linear relation between the magnetiza-
tion and the magnetic field intensity, ~
M=χm~
H, which is similar to the definition of linear
dielectrics, ~
P=0χe~
Ebut not completely analogous. We also have,
~
B=µ0~
H+µ0~
M=µ0(1 + χm)~
H=µ~
H(1)
which is analogous to ~
D=~
Ein dielectrics. µis the permeability. This should not
be confused with the magnetic moment for a current ring, which is also sometimes
called ~µ. This is horrible notation, but it is entrenched in the area. We shall have to
live with it. Most of the time I use ~m for the magnetic moment and ~
Mfor the magnetization.
B. Paramagnets, linear materials with χm>0
Paramagnets do not exhibit spontaneous magnetic order, nevertheless they can have large
magnetic susceptibilities. The magnetic moment of paramagnetic materials tries to align in
the direction of the applied magnetic field. Actually all materials will magnetically order at
sufficiently low temperatures, but when the ordering temperature is very low, materials are
called paramagnetic. The susceptibility of paramagnetic materials obeys the Curie Law,
χm=µ0C
T(2)
Paramagnetic materials are attracted to magnets.
C. Diamagnets, linear materials with 1< χm<0
If elementary particles did not have an intrinsic magnetic moment, then all materials
would be diamagnetic. That is, the magnetic moment of materials would be opposite the
direction of the applied field. This is due to Lenz’s law. Superconductors are the best
diamagnets, but many pure normal conductors are too (e.g. Cu...). At low enough values,
magnetic fields are completely excluded from the interior of a superconductors. The phase
in which this occurs is called the Meissner phase of a superconductor. From the expression,
~
B=µ0(1 + χm)~
H(3)
1
pf3
pf4
pf5

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PHY481 - Lecture 30 Chapter 9 of PS, Sections 7.2.3, 7.2.4 of Griffiths

A. Linear magnetic materials Linear magnetic materials are characterized by a linear relation between the magnetiza- tion and the magnetic field intensity, M~ = χm H~, which is similar to the definition of linear dielectrics, P~ =  0 χe E~ but not completely analogous. We also have,

B^ ~ = μ 0 H~ + μ 0 M~ = μ 0 (1 + χm) H~ = μ H~ (1)

which is analogous to D~ =  E~ in dielectrics. μ is the permeability. This should not be confused with the magnetic moment for a current ring, which is also sometimes called ~μ. This is horrible notation, but it is entrenched in the area. We shall have to live with it. Most of the time I use m~ for the magnetic moment and M~ for the magnetization.

B. Paramagnets, linear materials with χm > 0 Paramagnets do not exhibit spontaneous magnetic order, nevertheless they can have large magnetic susceptibilities. The magnetic moment of paramagnetic materials tries to align in the direction of the applied magnetic field. Actually all materials will magnetically order at sufficiently low temperatures, but when the ordering temperature is very low, materials are called paramagnetic. The susceptibility of paramagnetic materials obeys the Curie Law,

χm = μT^0 C (2)

Paramagnetic materials are attracted to magnets.

C. Diamagnets, linear materials with − 1 < χm < 0 If elementary particles did not have an intrinsic magnetic moment, then all materials would be diamagnetic. That is, the magnetic moment of materials would be opposite the direction of the applied field. This is due to Lenz’s law. Superconductors are the best diamagnets, but many pure normal conductors are too (e.g. Cu...). At low enough values, magnetic fields are completely excluded from the interior of a superconductors. The phase in which this occurs is called the Meissner phase of a superconductor. From the expression,

B^ ~ = μ 0 (1 + χm) H~ (3)

it is evident that in order for flux to be completely expelled so that B~ = 0 inside the superconductor, we must have, χm = −1. A measurement of χm is one of the first measurements that people do to determine if a material is in the superconducting state. Diamagnetic materials are repelled from magnets. This enables the possibility of magnetic levitation. Since superconductors are the best diamagnets, they are the primary candidates for possible magnetic levitation applications.

D. Ferromagnets, non-linear magnetic materials, hysteresis In ferromagnetic materials, the magnetic moments of the atoms in the material seek to align in the same direction. Examples are Fe and Permalloy (55% Fe, 45% Ni). It is actually quite difficult to find good ferromagnetic materials. There is a continuing search for ferromagnetic materials which have large local magnetic moments. A group at GM research in Detroit made a major breakthrough in this area about a decade ago. They helped develop the Niodymium, Iron, Boron magnets. The production of these magnets is now a multibillion dollar industry. Calculation of the fields around magnetics is carried out in a similar manner to the fixed magnetization case discussed above, e.g. for a uniformly magnetized sphere. A more general calculation uses a non-linear consitutive law. Sometimes ferromagnets are treated as a linear dielectric with a large positive value of χm - this is not completely correct, but it gives an indication of the expected behavior. Ferromagnetic materials are very important in technology. For example the hard drives in most computers are made using small domains on ferromagnetic materials. A small sensor (or read head) scans the surface of the hard drive. On the hard drive surface are small domains of ferromagnetic material. These domains are oriented in the plane of the surface and they have a prefered direction. The read head measures a resistivity which is sensitive to the local magnetic field. The technology of magnetic storage (e.g. hard drives) relies on a particular property of ferromagnetic materials. This property is called hysteresis. Hysteresis is a property which occurs when a magnetic field is applied to a ferromagnet which is below its Curie temperature. In order to describe hysteresis we must describe the way in which we vary the temperature and the magnetic field. Let us start at high temperatures and quench to a temperature well below the Curie temperature. The magnetic material is frozen in a domain structure by this process. Now we apply a positive external field. The domains now begin to align with

For a solenoid with n turns per unit length and carrying current I, we found, B 0 = μ 0 nI (4)

This is the result for a solenoid in air. Now if we place a material inside the solenoid, we use Ampere’s law for the field intensity, and B~ = μ H~, to find,

H = ni; and B = μH = μ 0 (1 + χm)ni (5)

From this expression it is evident that the magnetic field inside the solenoid is greatly enhanced if the center (the core) of the solenoid is composed of a magnetic material which has large magnetic susceptibility χm, for example permalloy. Note that this seems different to dielectrics where the electric field is reduced when a dielectric is placed between the plates of an isolated capacitor. However, if a capacitor is connected to a battery, the electric field is unaltered by the addition of the dielectric, however the charge stored increases by a large amount. If we associate the charge stored on the capacitor with the flux in the solenoid, then the two devices appear more similar. This is the analogy that is usually used. The energy stored in the solenoid is still Li^2 /2, but we need to calculated L again. L is defined through Li = N φ so that L = N 2 μA/l (6)

This is just the formula that we have for vacuum, but with μ 0 → μ. The energy stored in the inductor thus increases dramatically when a large permeability material is used for the core of the inductor. As an example, consider an inductor containing permalloy with μ = 10000 and with N = 10, 000, A = 0. 1 m^2 , l = 1m, carrying a current of 20A, then U = N 2 μAi^2 /l = 4 × 1013 J. This is a very large number and looks attractive for energy storage applications. However there are a number of critical limitations, ranging from hysteresis to resistive losses and the effects of large magnetic fields on materials and people. Materials with positive χm are drawn toward regions of high field (i.e. the solenoid), while those with negative χm are repelled from regions of high field.

A co-axial cable Consider a co-axial cable with an inner conductor of radius a and a material with permeability μ in the region a < r < b. A conducting cylinder completes the cable and has inner radius, b and outer radius c. Find the magnetic field in each of the four regions

of the material. We did this problem before for the case of vacuum for the insulating material. The extension to this case is straightforward. Simply carry out the calculation using Ampere’s law for H~ and then use B~ = μ H~ to find the field. Notice that we could do a problem where there are different values of μ in each regime in the same way, but just using the appropriate value of μ in each part of the co-axial.