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Material Safety Data Sheet for Methyl Benzoate, Schemes and Mind Maps of Engineering

Rice UniversityEngineering

Section 1 - Chemical Product and Company Identification. MSDS Name: Methyl benzoate, 99%. Catalog Numbers: AC126340000, AC126340025, AC126340250, ...

Typology: Schemes and Mind Maps

2022/2023

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Material Safety Data Sheet
Methyl benzoate, 99%
ACC # 00 963
Section 1 - Chemical Product and Company Identification
MSDS Name: Methyl benzoate, 99%
Catalog Numbers: AC126340000, AC126340025, AC126340250, AC126345000
Synonyms: Benzoic ac id, methyl ester; Oil of niobe.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
CAS # Chemical Name Perce nt EINECS /ELINC S
93-5 8-3 Met hyl b en zo ate 99 202 -259 -7
Section 3 - Hazards Identification
EM ER G ENC Y O VE RV IEW
Appearance: c olorless liquid. Flash Point: 82 deg C.
Ca ution ! May c ause e ye, skin, and respiratory trac t irritation. Combustible liquid and vapor. May be harmful if swallowed.
Target Organs: None known.
Potential Health Effects
Eye: May cause eye irritation. Causes redness and pain.
Skin: May c ause skin irritation. Causes redness and pain. May be harmful if absorbed through the skin.
Ingestion: May c ause irritation of t he digestive t ract . May be harmful if swallowed.
Inhalation: May ca use respiratory trac t irritation. May be harmful if inhaled.
Chronic: No information found.
Section 4 - First Aid Measures
Eyes: F lush eyes with plenty of wa ter for at least 15 minutes, oc ca sionally lifting the upper and lower eye lids. Get medical aid.
Skin: Flush skin with plenty of w ater for at least 15 minutes while removing cont aminated c lothing and shoes. Get medical aid if irritat ion
develops or persists.
Ingestion: Do not induce vomiting. If vict im is consc ious and alert, give 2- 4 c upfuls of milk or water. Never give anyt hing by mouth to an
unconsc ious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use
mouth-t o-mouth resusc itation. If breat hing has cease d apply artificial respiration using oxygen and a suitable mechanical device suc h as
a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-c ontained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or
equivalent), and full protec tive gear. During a fire, irritating and highly toxic gases may be generat ed by t hermal decomposition or
combustion. Vapors may be heavier than air. They can s pread along the ground and collect in low or c onfined areas. Runoff from fire
cont rol or dilution water may ca use pollution. Combustible liquid and vapor.
Extinguishing Media: Use water spray, dry c hemical, c arbon dioxide, or appropriate foam.
Flash Point: 82 deg C ( 179.60 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 2; Insta bility: 0
Section 6 - Accidental Release Measures
General Information: Use proper personal protec tive e quipment as indicate d in Sect ion 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, s and or earth), t hen place in suitable c onta iner. Avoid runoff into storm
sewers and ditc hes whic h lead to w aterways. Remove all sources of ignition. Provide ventilation.
Section 7 - Handling and Storage
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Material Safety Data Sheet

Methyl benzoate, 99%

ACC# 00963

Section 1 - Chemical Product and Company Identification

MSDS Name: Methyl benzoate, 99% Catalog Numbers: AC126340000, AC126340025, AC126340250, AC Synonyms: Benzoic acid, methyl ester; Oil of niobe. Company Identification: Acros Organics N.V. One Reagent Lane Fair Lawn, NJ 07410 For information in North America, call: 800-ACROS- For emergencies in the US, call CHEMTREC: 800-424-

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS 93-58-3 Methyl benzoate 99 202-259-

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: colorless liquid. Flash Point: 82 deg C.

Caution! May cause eye, skin, and respiratory tract irritation. Combustible liquid and vapor. May be harmful if swallowed.

Target Organs: None known. Potential Health Effects Eye: May cause eye irritation. Causes redness and pain. Skin: May cause skin irritation. Causes redness and pain. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: No information found.

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Runoff from fire control or dilution water may cause pollution. Combustible liquid and vapor. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. Flash Point: 82 deg C ( 179.60 deg F) Autoignition Temperature: Not available. Explosion Limits, Lower: Not available. Upper: Not available. NFPA Rating: (estimated) Health: 1; Flammability: 2; Instability: 0

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Remove all sources of ignition. Provide ventilation.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Keep away from heat and flame. Storage: Keep away from heat and flame. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits Chemical Name ACGIH NIOSH OSHA - Final PELs Methyl benzoate none listed none listed none listed OSHA Vacated PELs: Methyl benzoate: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - Physical and Chemical Properties Physical State: Liquid Appearance: colorless Odor: Pleasant odor. pH: Not available. Vapor Pressure: 0.38 mm Hg @ 25 deg C Vapor Density: 4.7 (air=1) Evaporation Rate: Not available. Viscosity: Not available. Boiling Point: 198 - 199 deg C @ 760 mm Hg Freezing/Melting Point: -12 deg C Decomposition Temperature: Not available. Solubility: Insoluble. Specific Gravity/Density: 1.0940 g/cm Molecular Formula: C8H8O Molecular Weight: 136. Section 10 - Stability and Reactivity Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Ignition sources, excess heat. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - Toxicological Information RTECS#: CAS# 93-58-3: DH LD50/LC50: CAS# 93-58-3: Oral, mouse: LD50 = 3330 mg/kg; Oral, rabbit: LD50 = 2170 mg/kg; Oral, rat: LD50 = 1177 mg/kg; . Carcinogenicity: CAS# 93-58-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Epidemiology: No information available. Teratogenicity: No information available. Reproductive Effects: No information available. Mutagenicity: No information available. Neurotoxicity: No information available. Other Studies: Section 12 - Ecological Information No information available.

Revision #3 Date: 10/03/ The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.