Measuring Planck's Constant: A Historical Perspective and Experimental Approach, Lecture notes of Physics

A historical perspective on the development of Planck's constant, a fundamental concept in quantum physics. It also includes a description of an experiment designed to measure Planck's constant using light emitting diodes (LEDs). the physics theory behind the experiment, the procedure for conducting it, and the apparatus required.

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Measuring Planck’s Constant
By
Martin Hackworth
Historical Perspective and Physics Theory
Max Planck (1858-1947) was born in Kiel Germany and attended schools
in Munich and Berlin. Planck was an early pioneer in the field of quantum
physics. Around 1900 Planck developed the concept of a fundamental unit of
energy, a quantum, to explain the spectral distribution of blackbody radiation.
This idea of a basic quantum of energy is fundamental to quantum mechanics of
modern physics. Planck received a Nobel Prize for his work in the early
development of quantum mechanics in 1918. Interestingly, Planck himself
remained skeptical of practical applications for quantum theory for many years.
In order to explain blackbody radiation, Planck proposed that atoms
absorb and emit radiation in discrete quantities given by
hfEn
=
where:
n is an integer known as a quantum number
f is the frequency of vibration of the molecule, and
h is a constant, Planck's constant.
Planck named these discrete units of energy quanta. The smallest discrete amount
of energy radiated or absorbed by a system results from a change in state
whereby the quantum number, n, of the system changes by one.
In 1905 Albert Einstein (1879-1955) published a paper in which he used
Planck's quantization of energy principle to explain the photoelectric effect. The
photoelectric effect involves the emission of electrons from certain materials
when exposed to light and could not be explained by classical models. For this
work Einstein received the Nobel Prize in Physics in 1921.
Niels Bohr (1885-1962) used Planck’s ideas on quantization of energy as a
starting point in developing the modern theory for the hydrogen atom. Robert
Millikan made the first measurement of Planck’s constant in 1916. The best
current value for Planck's constant is 6.62607554 x 10-34 J · s.
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Measuring Planck’s Constant

By Martin Hackworth

Historical Perspective and Physics Theory

Max Planck (1858-1947) was born in Kiel Germany and attended schools in Munich and Berlin. Planck was an early pioneer in the field of quantum physics. Around 1900 Planck developed the concept of a fundamental unit of energy, a quantum , to explain the spectral distribution of blackbody radiation. This idea of a basic quantum of energy is fundamental to quantum mechanics of modern physics. Planck received a Nobel Prize for his work in the early development of quantum mechanics in 1918. Interestingly, Planck himself remained skeptical of practical applications for quantum theory for many years.

In order to explain blackbody radiation, Planck proposed that atoms absorb and emit radiation in discrete quantities given by

E =n hf

where:

  • n is an integer known as a quantum number
  • f is the frequency of vibration of the molecule, and
  • h is a constant, Planck's constant.

Planck named these discrete units of energy quanta. The smallest discrete amount of energy radiated or absorbed by a system results from a change in state whereby the quantum number, n, of the system changes by one.

In 1905 Albert Einstein (1879-1955) published a paper in which he used Planck's quantization of energy principle to explain the photoelectric effect. The photoelectric effect involves the emission of electrons from certain materials when exposed to light and could not be explained by classical models. For this work Einstein received the Nobel Prize in Physics in 1921.

Niels Bohr (1885-1962) used Planck’s ideas on quantization of energy as a starting point in developing the modern theory for the hydrogen atom. Robert Millikan made the first measurement of Planck’s constant in 1916. The best current value for Planck's constant is 6.62607554 x 10-34^ J · s.

In this experiment, you will use light emitting diodes (LED’s) to measure Planck's constant. You should be familiar with semiconductors and diodes from Modern Physics. To review: LED’s are semiconductors that emit electromagnetic radiation in optical and near optical frequencies when a voltage is applied to them. LED’s emit light only when the voltage is forward biased and above a minimum threshold value. This combination of conditions creates an electron hole pair in a diode. Electron hole pairs are charge carriers and move when placed in an electrical potential. Thus many electron hole pairs produce a current when placed in an electric field. Above the threshold value the current increases exponentially with voltage.

A quanta of energy is required to create an electron hole pair and this energy is released when an electron and a hole recombine. In most diodes this energy is absorbed by the semiconductor as heat, but in LED’s this quanta of energy produces a photon of discreet energy E = hf. Because multiple states may be excited by increasing the voltage across a diode, photons of increasing energies will be emitted with increasing voltage. Thus the light emitted by an LED may span a range of discrete wavelengths that decrease with increasing voltage above the threshold voltage (shorter wavelength = higher energy). We are interested in the maximum wavelength that is determined by the minimum energy needed to just to create an electron hole pair. It is numerically equal to the turn on voltage of the LED. The relation between the maximum wavelength, λ , and the turn on voltage, V 0 , is

eV 0 E = hf = hc = λ where:

  • f is the frequency of the emitted photons,
  • c is the velocity of light,
  • e is the electronic charge, and
  • h is Planck's constant.

The maximum wavelength of the LED can be measured to a resolution of a few nanometers with a good spectrometer. If the turn on voltage, V 0 , is measured for several diodes of different color (and different maximum wavelength, λ ), a graph of V 0 vs. 1/ λ should be linear with a slope of hc / e. An experimental value of Planck's constant may then be determined by using the known values of the speed of light, c , and the charge of an electron, e , and computing h.

Diode V 0 (volts) λmax

 - 0.0006 0.0008 0.0010 0.0012 0.0014 0.0016 0.0018 0. 
      • IR 0.866 ____________________________
      • Red 1.367
      • Yellow 1.464
      • Green 1.560
  • V Slope=hc/λ

Apparatus

PC Pasco 750 interface Voltage probes Breadboard 1000 Ω ½W resistor 5V DC regulated power supply 10kW potentiometer large LEDs (blue, green, red, yellow) infrared LED of known wavelength (if available) connecting wires Gratner spectrometer with grating.

  1. Connect the 5V power supply to the breadboard. Use the convention black (-) and red (+).
  2. Connect the red probe of the test lead in A to its place on the breadboard and the black probe to the ground. Connect the red probe of the test lead in B to its place on the breadboard and the black probe to the ground.
  3. Switch on the power supply and the 750 INTERFACE box.
  4. Click on the Data Studio icon on the computer screen and choose the appropriate port for the 750 INTERFACE box (COM1 or COM2).
  5. Start the Data Studio program.
  6. Move the pointer to the y-axis label and hold the left mouse button and choose Port 1 on the menu that appears. Execute a similar procedure for the x-axis label, only choose Port 2 for the x-axis.
  7. Press and hold the right mouse button; a new menu should appear. While holding the mouse button, move the pointer to the arrow beside "Display" and then choose "Set All Max, Min" from the Display submenu. In the box that appears, type 5.0 in the area for max, 0 for min, and then click "ok".
  8. Repeat procedure 7 except choose "Collect" and "Data Rate". Move the pointer to the circle in front of the number 500 and click once; click "ok".
  9. Check the 10 kW potentiometer to see that it is turned fully counterclockwise. To take data, click the "Start" button. Immediately after

Data

Slope of turn on voltage versus 1/ λ graph __________ V· m Experimentally determined value for h _______× 10 -34^ J· s

Calculations

  1. After exiting Data Studio, start the Graphical Analysis program by clicking on its icon.
  2. Enter your data points by choosing the "Input New Data" option and input the information for which the program will prompt you. Plot 1/λ on the horizontal axis with units of 1/m and the turn on voltage on the vertical axis with units of V. (Remember your wavelengths are in nm, so if the wavelength is 500nm, then 1/ l is 2.00 x 10^6 m-1, and should be entered as 2.00e6). Enter the graph title when prompted for it, and choose Automatic Scaling, Start at 0 for both axes. Print a copy of the graph for each person in the group.
  3. The value for the slope will be given along the top of the graph. The slope is the value for m. The value for Planck's constant is the slope of your graph multiplied by e / c where e is the electronic charge (1.6022 x 10-19^ C) and c is the velocity of light (2.998 x 10^8 m/s).