Mole concept Handwriting simplified notes, Summaries of Chemistry

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some
basic
Concept
of
Chemistry
:
-
Physical
Property
:
-
The
Property
which
can
be
measured
without
changing
the
Chemical
Composition
of
the
substance
is
known
as
Physical
Property
like
mass
,
volume
,
density
etc
.
Chemical
Property
:
-
The
property
which
Can
be
evaluated
at
the
cost
of
matter
itself
is
known
as
chemical
property
.
Classification
of
Matter
:
-
Matter
V
V
Pure
Substance
Mixture
#
I
1
Element
Compound
2/
Y
Homogenous
Heteroge-
nous
pf3
pf4
pf5
pf8
pf9
pfa
pfd
pfe
pff
pf12
pf13
pf14
pf15
pf16

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some basic^ Concept

of Chemistry :

Physical Property^ : -

The

Property

which can^ be measured without

changing the Chemical^ Composition (^) of the

substance is known^ as

Physical (^) Property

like mass^ , volume^ ,

density etc. Chemical Property : -

The

property

which Can be^ evaluated at the

cost (^) of matter (^) itself is known (^) as chemical property . Classification of^ Matter^ :^

Matter

V (^) V

Pure Substance Mixture

I 1
Element Compound

2/ Y

Homogenous Heteroge-

nous

Law ofChemical^ Combination :^ -

Law of Conservation of Mass^

: - For

any chemical change

total mass

of active^ reactants^ are always equal^

to the mass of the Product

Formed.^ It^ is^ a^ derivation^ of Dalton's atomic theory. ' Atoms neither (^) created nor destroyed

  • &

Total masses of reactants= Total^ masses of

Products +^ masses^ of unreacted reactants - Example:^ -4. 90g of KCO3^ When^ heated^ Produced 1 :

92g of^ oxygen

and the^ residure^ (ke) Left

behind weights

96g

. Show (^) that (^) these results

illustrate the^ law^

of Conservation^ of mass . Soli-weight of KCI0z taken^ = (^) u. gog total weight of^ the (^) Products (^) (KC +

= 2.^96 +^1. 92 =^4. 88g Difference between the wight of^ the reactant^ and the

total

weight of^ the Product =^4.^ 90-4.^ 88-^. 02g

This small^ difference

may

be (^) due to (^) experimental error. Thus (^) , Law

of

Conservation of mass^ holds

good

within (^) experimental error.

Example :^ -Ratio^ of masses (^) of Carbon^ and (^) Sulphur which Combine^ with^ Fixed^ mass^ (32 (^) Part) (^) of

Oxygen

is 12 :^32 or 3 :^ 8. ..... ()

In CS2 ratio of masses

of Carbon (^) and (^) Sulphur is 12 :^64 or 3 :^16 ..... (2) So (^) & M The two^ ratio (^) (1) and (^) (2) are related to each other by (^) - :^ % or^2 :^1 or 3 : 2(5) First ratio (^) is integral multiple^ of^

second.

Gay

Lussac's Law^ of

Combining

Volumes :^ -

At given

temperature and^ pressure the

volume of

all

gaseous

reaction and products

bear (^) a (^) simple whole (^) number (^) ratio to each

other.

Example:^

  • H2(g) + <12(g) - > 2HC(g) ( : (^2) : 2) One (^) Volume (^) of hydrogen reacts with (^) one (^) volume of chlorine^ to^ form^ two^ volume^ of Hel^ gas

the (^) ratio by

Volume which^ gases bear^ is^1 :^ L^ :^2

which is a (^) simple whole^ number (^) ratio. Other Example are^ :

25a +^02

= 2503[ : 1 : (^) 2] (^2) Volume (^1) Volume 2 volume 2NH

= N2 + 3H2[2 :^1 :^ 3]

(^2) volume ↓ (^) Volume (^3)

Volume

NH3 +^ HCl^

NHy (l[Vapour]^ [^ : (^2) : (^) 1] I (^) volume (^) (Volume L volume Dalton's Atomic Theory :

In (^1808) , Dalton^ Published^ 'A^ new^ system of

chemical

philosophy:

in which^ he^ proposed

the following

:

=> Matter Consist^ of indivisible atoms.

  • > All the atoms (^) of a

given

element have^ identical

Properties including

identical mass. Atoms of

different elements^ differ in^ mass.

  • >

Compound are^ formed^ when^ atom^ of different

element Combined in a fixed Ratio.

One atom^ of^ the element^ is heavier^ in^ Comparision

to the mass of one atom of

hydrogen.

Atomic mass of an element : -

=> Mass of^ one^ atom^ of^ the^ element

Mass of^ th Part of mass of C-12^ atom

  • (^) Average Atomic^ mass^ : - Elements (^) are found in (^) different isotopic Forms (atoms (^) of same^ element^ having different atomic mass)

So the atomic mass of

any element is the average of^

all the isotopic mass within

a given

sample.

Average atomic^ mass^

= 22 % abundance) X atomic mass

Mole (^) Concept :^ -Mole is^ the number (^) equal to

Avogadro's

number just like a

doyen

is

equal

to (^12) , a Century means too, (Na = 6. 022 x (^) 1023)

6 : 02x^

  1. (^4) (of gas at^ NTP O
Particles or^ Molar^ Vol^.

In terms^ In^ terms^ of of particles ↓^ mole^ Volume In (^) terms (^) of mass

L ↓ gram gram^

formula

Igram e of

mole of mass of Substance

No. of mole (^) of Molecule =Witinemass No. of Moles (^) of atoms =lgtina No. (^) of Moles^ of Gases =oatSe volume (Standard Molar^ Volume^ at^ STP^ =^22.^4 lit)

Example: -^ Molecular^ mass^ of Calcium^ Nitrate^ :

Ca(NO3)2 =^ atomic^ mass^ of Ca^ +^ 2X^ Atomic

Mass (^) of N +^6 X^ Atomic mass of 0 =^40 +^ 2x14 + 6416 = 40 + (^28) + 96 = (^) 164u % of Calcium^ ((a) =MassOfC100 = xoO 24 · 39

% of Nitrogen (N) =^ Mass^ of N

Molecular mass^ of Ca(NO) 100 = x00 =^17 % of

Oxygen (0)^

=SS^ Ot^ of Ca(NO)X100 = x Example :^ How much^ of (^) Copper is^ obtained from

    • Loog of^

Copper Sulphate^ (Cuson)?

Sol :^ -Molecular mass

of Cusoy^

= Atomic Mass of Cu +

atomic mass (^) of Stux (^) atomic mass (^) of 0 = 63.^5 + (^32) + (^) 4X = (^159). 5 y Gram (^) Molecular mass

of Cuson^

= 159. 59

Now , 159.^5

g of^

Cuson here^ C^ =^63.

5g

: 100g of^

CuSOy have^ C^ =^63.

5 X = 39. g

Empirical Formula (^) :

It (^) is the Formula^ which (^) expresses the (^) smallest whole number ratio of

the Constituent atom

within the Molecule.

Ex :^ -^ A^ Compound Contains C^ =^71.^23 %, H^ =^12.^95 %

and 0 =^15.^81 %.^ What is^ the^ empirical Formula

of the^ Compound. Sol!^ - Element's Atomic^ Weight in^ Relative Simplest Empirical Name with mass (^) Compound No·^ of atomic (^) Formula their (^) Symbol Atom^ Ratio

Carbon (c)^12

. 93

93693- 12.^95

  1. 988

I

Hydrogen

(H) 1 12.^95

T = 12.^95 295 :^13 Cultis O -Mygen(o)

(^818090098) Chemical Equation and Stoichiometry

Symbol:

  • Liquid - > (1) Gas -^ >^ (g)

(3) - Balance the (^0) atom (^) :^ -

CazNa +^ GH^
  • >

3 (a(OH)2 +^ 2NHs

upon checking

, the^ H^ atoms^ are^ already balanced

: (^) Final (^) balanced chemical equation is^ :

CasN2+^ 6H

-- >

3 CalOH)2 +^ 2 NH

Balance the following (^) by (^) yourself. & (a^ +^ Ho -^ (a(OH)2 +^ Hz ② Aly^ +^ H^

  • AloH + Hy

* Problem^

Involving

mass-mass Relationship :

Example :^ What^ mass^ of Copper oxide^ will^ be^ obtained by Catomic maneating1235g^ of Copper Carbonata

Sol :^ - The chemical equ for the reaction is!^ -

Cu(O

eat (^) >

Cu0 +^ CO
63.^5 +^12 +^48 63.^5 +^16

59 => 79. 59

5g

of Copper Carbonate^ upon

heating (^) gives C = 5 d.og of^ Copper^

Carbonate

upon (^) heating given (^) Cu : (^12). 35g of (^) Copper Carbonate^ upon heating (^) give Cy = = x12. 35 =

9

Problem Involving Mass-Volume (^) Relationship!-

  • Example :^ - KClOz On heating decompose^

to

give

KCI and Of What is^ the volume

of O at NTP (^) Liberated by 0.^2 mole of Keloz^ ? sol": · (^) The (^) chemical

equ

for the decomposition of KCOz

is

Heat

2k(

  • > 2kC +

(^2) mol 3 Mol (3x22.^ 4h^ =^67 · 2L) 2 mole of KC^

evolve O2 at NTP = 67. 21

↓ (^) mole of K2103 evolve^ O2 at^ NTP^ = Ge 0 .I mole^ of KC03 evolve (^) O2 at (^) NTP (^) =1.^2 2X

. /1= 3 .36L Problem Involving Volume-volume Relation Ship : - Example:

↓ Litre of

Oxygen at NTP is^ allowed to react with (^3) Liter (^) of Carbon monoxide at NTP·^ Calculate^ the^ volume of each

gas

found

after the^ reaction^.

Eg

. (^) 30g of He^ react^ with^29 . 09 O to^ yield t ① What (^) is limiting reactant .?. ② calculate^ the^ maximum^ amount^ of H20 that Can be (^) formed ③ Calculate^ the^ amount^ of one^ of the reactant which remains unreacted. sol. The balanced Chemical

equ

is

2H2 +^02

  • 2420 2x2 = ug 32g^ 2x18 =

36g

Step-

  • Determination of limiting reactant

4g of^ H^

react with^02 =

32g

: 3g of^ He^ react with^02 = 2x = 24g

but the amount

of oxygen

actually available = 29g As

Oxygen

is available in excess ,

therefore , hydrogen is the limiting reactant.

Step-1-Calculation of the^ amount^ of water

thatCan^ be^ formed. 4g of (^) H2 From^ H20 in^ the^ reaction^ = 369 :

3g

of He from^ to^ in^ the^ reaction^ =^ 36 ↑ X 3 = 279

Step

-> Calculation of the amount

of

oxygen

left unreacted.

4g ofHe required o^ for (^) reaction = 329 :. 3g of He required^ For reaction^ = x3 = zug but Oxygen

which

actually Present-29g : (^) Amount of (^) Oxygen Left^ unreacted^ = 29-245g

  • (^) Method of Expressing Concentration (^) of

Solution : -

Molarity (M)

: - The

Molarity of a

Solh is the no of moles

of solutePresent^ in^ one^ litre^ (1dm3)^ of the^ Som^ . M = , (^000) me M =^ No .

of moles^ ofsolute

volume of Soln^ (in^ litre) w =^ mass^ of solute (^) , M (^) , = (^) Molar (^) mass of solute v =^ volume of Solution.

It density of^ the solution^ is^ dyles , mass of

solution=

grams .

mass (^) of solute^ = MMLg[M is molar mass^ of solutel

mass of Solvent^ =

1000d-MM2g Molality (m) (^) = MM

X 1000

=o

MM

m

2/ ( or m (d- = MormM2) or M = (^2) /1 000

  • (^) Relationship between^ Molality (m) and mole (^) Fraction (^) (Xc) :^ - Molality(m) = moles^ ofSolute/mass ofSolvent Linkg)

Mole Fraction of Solute^ (X 1 ) =^ Moles^ of solute^ /(mole of solute^ +^ moles^ of

a^ Solvent)

  • n. =^ Mole

of

solute We =^ mass of (^) Solvent(g) n2 =^ mole^ of solvent S m = molality of solute M2 =^ Molar mass of Solvent(ymos)^ X1 =^ Mole (^) Fraction of solute From molality : m =

W 12 = Now ,^ mole^ Fraction^ of^ solute :

=

Final

Relationship :-

: or inversely m Relationship between^ Molavity (m) (^) and mole Fraction (*)

Mole Fraction . X

= -MMMM