Corrosion Fundamentals: Definition, Mechanisms, and Control Methods, Exams of Water and Wastewater Engineering

A summary of corrosion, including its definition, mechanisms, and control. Key concepts like passivation, galvanic series, and factors affecting corrosion rate are covered. Different corrosion types, inspection methods, and the role of inspectors in quality control are discussed. Surface preparation, coating types, and environmental factors influencing coating performance are explained. Useful for students and professionals in materials science and engineering, it offers a structured approach to managing corrosion. It is a valuable resource for enhancing knowledge of corrosion prevention in industrial applications. It presents information clearly, making it a reference for both beginners and experienced practitioners.

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NACE CIP Level 1 Study Guide
1. Define Corrosion: The deterioration of a substance, usually a metal from a reaction with its
environment
2. What is passivation?: A layer of oxides formed on the surface of a metal that provides corrosion
protection.
3. What is an example of passivation?: Stainless Steel
4. What are the elements of a corrosion cell?: Anode, Cathode, Metallic Pathway, Electrolyte
5. Describe what happens at the anode.: The metal dissolves into the electrolyte
6. What is the function of the electrolyte?: Allows the passage of ions to connect the corrosion cell
7. What is the function of the metallic pathway?: Allows the flow of electrons to connect the corrosion
cell
8. What is the galvanic series?: A listing of metals in order of reactivity (more or less noble) in
seawater at 25 C
9. The general rules of galvanic corrosion are:: The less noble (or more reactive) metal when
connected to a more noble (or less reactive metal) will corrode prefer- entially
10. Name the five most important factors that affect the rate of corrosion.: Hu- midity, oxygen,
chemical salts, pollutants, temperature
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NACE CIP Level 1 Study Guide

1. Define Corrosion: The deterioration of a substance, usually a metal from a reaction with its

environment

2. What is passivation?: A layer of oxides formed on the surface of a metal that provides corrosion

protection.

3. What is an example of passivation?: Stainless Steel

4. What are the elements of a corrosion cell?: Anode, Cathode, Metallic Pathway, Electrolyte

5. Describe what happens at the anode.: The metal dissolves into the electrolyte

6. What is the function of the electrolyte?: Allows the passage of ions to connect the corrosion cell

7. What is the function of the metallic pathway?: Allows the flow of electrons to connect the corrosion

cell

8. What is the galvanic series?: A listing of metals in order of reactivity (more or less noble) in

seawater at 25 C

9. The general rules of galvanic corrosion are:: The less noble (or more reactive) metal when

connected to a more noble (or less reactive metal) will corrode prefer- entially

10. Name the five most important factors that affect the rate of corrosion.: Hu- midity, oxygen,

chemical salts, pollutants, temperature

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11. General corrosion is:: Results in a relatively uniform loss of material over the entire surface,

Results in a general thinning of the affected surface, Relatively easy to inspect, Does not casue catastrophic failures

12. Localized corrosion is:: Typically pitting and crevice corrosion. It is typically of the most concern as

damage is concentrated and loss of integrity or structural failure can result.

13. List some of the common tools/methods used for corrosion control.: De- sign, Inhibitors, Material

Selection, Cathodic Protection, Protective Coatings, Splash Zone Systems, Alteration of the Environment

14. How does NACE define the inspector's role?: The inspector's role is that of a quality control

technician responsible for observing and reporting conformance or deviation from the project specification.

15. What is the inspector's responsibility when it comes to safety on the project?: Safety

enforcement is not the responsibility of the inspector; however, it is his/her responsibility to report any issues that may affect the project.

16. Name some tests that may need to be conducted during surface prepara- tion and coating

operations.: Temperature, Relative Humidity, Dew Point, Anchor Profile, Surface Cleanliness

17. Name some of the documentation/reports that may be required to be maintained on a coatings

project.: Daily/weekly summary, material usage reports, manpower and equipment, non conformance, and conformance

18. What are the most important characteristics of a good report?: Objective, Accurate, and Detailed.

4 / steel surface.

26. Name some of the effects wind may have on a coatings project.: blowing abrasives, causing

excessive drift or overspray, accelerating solvent evaporation, contributing to the formation of dry spray

27. What are some of the common errors when using an electronic hygrome- ter?: Failure to

acclimate the instrument to the environment with adequate time.

28. Explain the process for use of the sling psychrometer.: Make sure the wick is wet and clean,

continue to "sling" until 3 consecutive readings are achieved

29. List three desirable properties of a coating?: Chemical Resistance, water resistance, ease of

application, cohesive strength, impact resistance, dielectric strength

30. Two broad classifications of a coating are:: Organic/Inorganic, Convert- ible/non-

convertible, thermosetting/thermoplastic

31. What are the two primary components of a liquid applied coating?: Pig- ment, Vehicle (Resin or

Binder)

32. What are the three methods by which a coating provides corrosion con- trol?: barrier,

inhibitive, sacrificial

33. What are the three different ways a coating can adhere to the surface?: -

Chemical, Mechanical, Polar, or combo of all three

34. The two broad classifications for curing mechanisms are:: Convertible and Non-Convertible

35. List two Non-convertible coating types:: Chlorinated rubber, vinyl

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36. List three convertible coating curing mechanisms: oxidation, co-reaction (polmerization),

hydration, fusion

37. List two characteristics of oxidation cure coatings: Not suitable for immer- sion service, not

suitable for use over alkaline substrates, limited dry film thickness per coat

38. List three coating types that cure by polymerization: epoxies, polyurethanes, polyureas,

polyaspartics, polysiloxanies

39. Induction time is:: the time required by the product data sheet (coatings man- ufacturer) between

mixing the coating and the start of application

40. What is the main requirement for a hydrolysis coating cure?: Moisture

41. Industrial and marine coatings are commonly referred to by: generic resin type

42. Oil based coatings applied over alkaline surfaces may result in: saponifica- tion

43. List five of the formal sections usually contained in a good specification-

: scope of work, terms and definitions, pre-job conference, application, sampling coatings, inspection

44. What are two of the inspector's responsibilities as it relates to the specifi- cation?: Enforce the

specification, NOT to make changes to the specification

45. During the surface preparation, surface cleanliness should be inspected (as a minimum) the

following three times:: Before any surface preparation activ- ities, after surface preparation - before coating begins, between each application of coating in a multi-coat system

46. Factors during surface preparation that may effect service life include:: - residues of oil, grease,

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47. Common design defects include:: Hard to reach or inaccessible areas. rivets, bolts, or other

connectors. welds. gaps. overlapping surfaces. threaded areas. dis- similar metals. construction aids

48. Common fabrication defects include:: weld spatter, skip welds, sharp corners & Edges

49. Four typical SSPC SP1 pre-cleaning methods include:: Solvent wipe with cloth or rag, immersion

of the substrate in solvent, solvent spray, vapor degreasing, emulsion cleaining, chemical paint stripping, use of alkaline cleaners

50. One standare for use with Power Tool Cleaning is:: ISO St2. ISO St3. SSPC SP-3. SSPC SP-

51. Four examples of tools used for Power Tool Cleaning are:: rotary wire brushes, impact

tools, needle scaler, disc sanders, piston scalers

52. Two Abrasive Blasting methods include:: Centrifugal blasting, sand-injected water blast, slurry

blast, wet abrasive blast, dry grit blasting

53. Visual Standards for abrasive blasting include: SSPC-Vis 1, ISO 8501- 1

54. SSPC SP 10/NACE 2 limits staining to per each unit area: 5%

55. SSPC SP 5/NACE 1 limits staining to per each unit area: 0%

56. SSPC SP 6/NACE 3 limits staining to per each unit area: 33%

57. The two types of abrasive blasting nozzles include:: Straight, Venturi

58. The specified level of surface cleanliness must be achieved and main- tained: immediately

prior to coatings application

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59. Advantages of centrifugal blast equipment include:: Dust and fines are contained, abrasives

are easily recycled, blasting and priming can be an inline operation, general overall economy compared to air blasting, no compressors, piping, or air handling equipment needed for wheel blasting

60. The Inspector's checklist for surface preparation should include:: ambient conditions, conditions

of substrate, pre-blast surface cleanliness, shot/grit size se- lection, shot/grit cleanliness, abrasive blasting equipment, surface profile, surface cleanliness after abrasive blasting, operator qualifications, safety

61. Abrasive media types include:: shot & grit (metallic), crushed slag, ceramic grit, silica sand,

garnet, agricultural abrasives, specialty abrasives

62. Abrasive media typically used for recycling include:: steel shot, steel grit

63. List the pressure ranges that categorize: low pressure water cleaning: <34 MPa (5,000 psi), high-

pressure water cleaning: 34 to 70 MPa (5,000 to 10,000 psi), High-Pressure water jetting: 70 to 210 MPa (10,000 to 30,000 psi), Ultrahigh=Pres- sure water jetting: > MPa (30,000 psi)

64. Three types of Water-Blasting include:: Comparator and coupons, replica tape, digital surface

profile gauge

65. Types of soluble salt contamination include:: chlorides, sulfates, nitrates

66. If inspection is to be effective with regards to soluble salts, the specifica- tion should very clearly

state:: limits to be accepted, specific salts to be limited, test method to be used, frequency of testing,

10 / engineer, specifying engineer, operations personnel, spec- ifier, purchasing agents, coatings manufacturer, coatings inspector, project safety personnel, coatings applicator

75. Before the start of the Pre Job Conference the inspector should obtain a copy of, read, and

understand the:: specification, any standard / procedure referenced in the project specifications, manufacturer's product data sheets, safety requirements of the MSDS

76. Documentation may include:: Detailed written daily reports, inspection logs, routine reports,

reports for weekly progress meetings, daily entries in a project log book, a daily inspection report using standardized forms, routine reports, monthly or quarterly reports

77. Inspection records show:: environmental conditions, pretreatment details, cleaning details,

materials details, coating applications details, results of work and all tests

78. Good records allow management to:: detect and tag design defects for future work, evaluate

coating performance, determine annual cost data on each coating system, develop ongoing maintenance program

79. Project inspection documentation provides:: inspection (QC) records, man- agement information,

verification of work by the contractor, details of non-conform- ing work

80. One guide for enclosures for coatings projects is:: SSPC Technology Guide No. 12, SSPC

Technology Update No. 6 Guide for Containing Surface Preparation Debris Generated During Paint Removal Operations

81. Low Temperature concerns during coatings application include:: Slow the curing of chemically

11 / curing coatings, will increase the viscosity of material, some coatings may use special cure

82. High temperatures concerns during coatings application include:: Can cause the solvent to

evaporate too fast, will reduce the pot life, decrease the viscosity of many two-component materials

83. High humidity during coating application:: Slows the evaporation of the solvent, can leave

moisture on the surface of the coating, may effect the gloss or color, may cause amine blush (must be removed prior to top coating)

84. Coatings may be applied by the following methods:: Roller, brush, airless spray (including plural

component), conventional spray, high volume low pressure (HVLP), air assisted airless

85. Coatings Product Data Sheets (Paint Specs) provide users with the follow- ing:: surface

preparation, storage, mixing and thinning, application procedure, DFT requirements

86. SDS contains the following:: Provides workers and emergency personnel with critical information

on composition, handling or working with the substance. Includes information such as melting point, boiling point, flash point, toxicity, health effects, first aid, reactivity, storage, disposal, protective equipment, and spill handling procedures. Provides info regarding the safety issues associated with any hazardous (or potentially hazardous) material. Provides instructions for the correct action to take in the event of a spill, explosion, fire or hazardous exposure.

87. Failure of coatings to cure may be caused by:: not adding curing agent, wrong curing agent or

incorrect amount of it. problem with material from the man- ufacturer. environmental issues (too cold, hot, or humid). wrong or contaminated thinner (solvent)

88. Some of the problems that can be caused by amine blush are:: surface tackiness or greasiness,

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99. Low-voltage (wet sponge) holiday detectors are powered by batteries with output voltages

ranging from .: 5 to 120 V DC

100. Describe Low-voltage (wet-sponge) holiday dectectors:: ground cable is attached directly to

substrate, sponge saturate with a solution of tap water/wetting agent, maximum rate of 30 cm/s ( linear ft/s) double stroke, used on coatings up to 500 uM (20 mils), may be used on concrete

101. High Voltage DC Holiday detector types include:: DC - Pulsed, DC - Con- stant Current

102. Describe High Voltage DC Holiday Detectors:: Ground connection must be made direct to metal

substrate (preferred) or indirectly when necessary (e.g., to soil for pipeline measurement). Rule of thumb: 100V/mil (4V/um). Electrode rate of 0.3 m/s (1 ft/s) in a single pass (according to NACE Standard SPO 188). Voltage output range from 800 to 60,000 V

103. The type of High Voltage Holiday dectector used for concrete is a:: High Voltage DC Constant

Current

104. What is a Standard?: An established norm or requirement that is written by industry

professionals. A formal document that establishes uniform engineering or technical criteria, methods, processes and practices

105. What percentage of NACE Standards relate to coatings?: 50%