Periodic Trends and Atomic Radius, Exams of Chemistry

This document explores the relationship between atomic radius, ionization energy, and electron affinity throughout the periodic table. It includes warm-up questions, activities, and vocabulary related to the topic. how the size of an atom affects its ability to attract electrons and how the thickness of a book affects the strength of a magnet. It also discusses the trends in atomic radius, ionization energy, and electron affinity as you move down a group or across a period in the periodic table.

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2022/2023

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Prior Knowledge Questions (Do these BEFORE using the Gizmo.)
1. On the image at right, the two magnets are the same. Which paper
clip would be harder to remove?
The paper clip would be harder to remove is B.
The thicker the book the low the ability of the magnet to hold and attract paper clips. The less
thickness of the book, the higher the ability for the magnet to attract and hold paper clips.
Name:
Student Exploration: Periodic Trends
Directions: Follow the instructions to go through the simulation. Respond to the questions and
prompts in the orange boxes.
Vocabulary: atomic radius, electron affinity, electron cloud, energy level, group, ion, ionization energy, metal,
nonmetal, nucleus, period, periodic trends, picometer, valence electron
2. Which magnet would be most likely to attract additional paper clips?
3. What is the relationship between the thickness of the book and the ability of the magnet to hold on to and
attract paper clips?
Gizmo Warm-up
Just as the thickness of a book changes how strongly a magnet attracts a paper clip, the
size of an atom determines how strongly the nucleus attracts electrons. In the Periodic
Trends Gizmo, you will explore this relationship and how it affects the properties of
different elements.
The atomic radius is a measure of the size of the electron cloud, or the region where
electrons can be found. To begin, check that H (hydrogen) is selected in Group 1 on the
left. Turn on Show ruler. To measure the radius, drag one end of the ruler to the proton in the nucleus and the
other end to the electron. Click Save radius to record the value.
1. What is the radius of hydrogen?
Notice that the radius is measured in picometers (pm). A picometer is one
trillionth of a meter.
2. On the right side of the Gizmo, select Li. Connect the right side of the ruler to
the outermost electron, or valence electron. What is the radius of lithium?
Date:
Answer
B would be most likely to attract additional paper clips.
The radius of
hydrogen is 53 pm.
The radius of lithium
is167 pm.
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Prior Knowledge Questions (Do these BEFORE using the Gizmo.)

  1. On the image at right, the two magnets are the same. Which paper clip would be harder to remove? The paper clip would be harder to remove is B. The thicker the book the low the ability of the magnet to hold and attract paper clips. The less thickness of the book, the higher the ability for the magnet to attract and hold paper clips. Name:

Student Exploration: Periodic Trends

Directions: Follow the instructions to go through the simulation. Respond to the questions and prompts in the orange boxes. Vocabulary: atomic radius, electron affinity, electron cloud, energy level, group, ion, ionization energy, metal, nonmetal, nucleus, period, periodic trends, picometer, valence electron

  1. Which magnet would be most likely to attract additional paper clips?
  2. What is the relationship between the thickness of the book and the ability of the magnet to hold on to and attract paper clips? Gizmo Warm-up Just as the thickness of a book changes how strongly a magnet attracts a paper clip, the size of an atom determines how strongly the nucleus attracts electrons. In the Periodic Trends Gizmo, you will explore this relationship and how it affects the properties of different elements. The atomic radius is a measure of the size of the electron cloud , or the region where electrons can be found. To begin, check that H (hydrogen) is selected in Group 1 on the left. Turn on Show ruler. To measure the radius, drag one end of the ruler to the proton in the nucleus and the other end to the electron. Click Save radius to record the value.
  3. What is the radius of hydrogen? Notice that the radius is measured in picometers (pm). A picometer is one trillionth of a meter.
  4. On the right side of the Gizmo, select Li. Connect the right side of the ruler to the outermost electron, or valence electron. What is the radius of lithium? Answer Date: B would be most likely to attract additional paper clips. The radius of hydrogen is 53 pm. The radius of lithium is167 pm.

The atomic radius of an atom will increase as you move down a group. The radius increase as I move down group 1. I see that the nucleus is getting bigger and the electron shell of an atom are getting smaller In general, the atomic radius increases as the group and energy levels increases. The radius of an atom will decrease as you move across a period. The radius is getting smaller as I move across a period. Activity A: Atomic radius Get the Gizmo ready: ● Check that Atomic radius is selected from the drop-down menu. Question: What factors affect the radius of an atom?

  1. Predict: How do you think the radius of an atom will change as you move down a group (vertical column) in the periodic table?
  2. Collect data: Use the ruler to measure the atomic radii of the group 1 elements. As you do so, count the energy levels (shown as rings of electrons) in each atom. Record in the table. Element H Li Na K Rb Cs Number of energy levels 1 2 3 4 5 6 Atomic radius (pm) 53 167 190 243 265 298
  3. Observe: What happens to the radius as you move down group 1?
  4. Explore: Turn off Show ruler. Select Li , and then select Be. Observe the radii of the elements in group 2. Then look at other groups. What pattern do you see?
  5. Draw a conclusion: In general, what is the effect of the number of energy levels on the radius of an atom?
  6. Predict: How do you think the radius of an atom will change as you move across a period (horizontal row) in the periodic table?
  7. Collect data: Beginning with Na , record the number of energy levels, number of protons, and atomic radius for each element in period 3. Element Na Mg Al Si P S Cl Ar Number of energy levels 3 3 3 3 3 3 3 3 Number of protons 11 12 13 14 15 16 17 18 Atomic radius (pm) 190 145 118 111 98 88 79 71
  8. Observe: What happens to the radius as you move across a period?

The ability of an atom to hold its valence electrons will lessen as the atom’s size get bigger. This is because as the atom gets bigger, the outer shell gets further away from the nucleus. The longer the distance between the original and the final position of the electron, the lesser the ionization energy. The distance decreases as the ionization energy increases. Question: How does the radius of an atom affect the ability of the protons in the nucleus to hold on to and attract electrons?

  1. Predict: Ionization energy (IE) is the energy required to remove an electron from an atom. As atomic radius increases, the valence electrons get farther from the nucleus. How do you think an atom’s size will affect its ability to hold on to its valence electrons? Why?
  2. Investigate: Select H. In the Gizmo, the hydrogen atom is shown next to a positive charge. As you move the atom to the right, the force of attraction between the positive charge and the valence electron will increase until the electron is removed. Slowly drag the atom towards the charge. After the electron is removed, use the ruler to measure the distance between the original and the final position of the electron. Record the distance and ionization energy in the table, then repeat for the other group 1 elements. Element H Li Na K Rb Cs Fr Distance (no units) 227 397 402 418 422 427 427 Ionization energy (kJ/mol) 1312 520 496 419 403 376 380
  3. Analyze: What trend do you notice?
  4. Investigate: Gather data for ionization energy across a period. Record in the table below. Element Na Mg Al Si P S Cl Ar Distance (no units) 402 350 384 339 291 294 240 182 Ionization energy (kJ/mol) 496 738 578 787 1012 1000 1251 1521
  5. Analyze: What trend do you notice?
  6. Explore: Examine other groups and periods in the periodic table to see if the same trends exist. What trends do you see in ionization energy down a group and across a period? Get the Gizmo ready: ● Choose Ionization energy from the drop-down menu. Activity B: Removing and adding electrons

An increase in atomic radius would result in a lower ionization energy because there is a less attraction, therefore lower ionization energy. Decrease in atomic radius would result in a greater ionization energy because there is a stronger attraction making it harder to remove an electron. The bigger the atom the lesser the ability of the atom to attract additional electrons.

  1. Think and discuss: As you move down a group, you will recall that the radius increases. Why do you think an increase in atomic radius would result in a lower ionization energy?
  2. Think and discuss: As you move across a period, you will recall that the radius decreases. Why do you think a decrease in atomic radius would result in a greater ionization energy?
  3. Predict: Electron affinity (EA) refers to the energy released when an electron is added to an atom. This release of energy is always expressed as a negative value. The greater the magnitude of the negative value, the greater the attraction for electrons. (An EA of – 100 kJ/mol would indicate a stronger attraction for electrons than an EA of – 50 kJ/mol.) How do you think the size of an atom will affect its ability to attract additional electrons?
  4. Investigate: Choose Electron affinity and select fluorine ( F ). In the Gizmo, the fluorine atom is shown next to an electron. To measure the electron affinity, slowly drag the fluorine atom toward the electron. When the electron hops over, use the ruler to measure the distance. What is the ruler distance?
  5. Explore: Find the electron affinity for each of the other Group 17 elements and each of the other Period 2 elements. Record these below. (Note: If an atom has a positive EA it will have no attraction for an electron.) All values in the tables below will be in kJ/mol. Grp. 17 EA F: - 328 Cl: - 349 Br: - 325 I: - 295 At: - 222 Ts: - 166 Per. 2 EA Li: - 60 Be: 50 B: - 27 C: - 122 N: - 7 O: - 141 F: - 328 Ne: 120 What is the trend in EA down a group? What is the trend in EA across a period? When you go down a group and across a period, the ionization energy increases and the distance decreases. It increases It decreases 463 What is the electron affinity? - 328 kJ/mol

Nonmetals tend to have high electron affinities because they have high ionization energy. It is easier for them to gain electrons than to remove electrons Metals tend to have low ionization energy because the electrons are far from the nucleus, so the force of attraction is low. The group 18 have filled valence electron and are stable, therefore they have high ionization energies but weak electron affinities. Group 18 has high ionization energies but very weak electron affinities.

  1. Infer: Which group has high ionization energies but very weak electron affinities? Which group has high ionization energies but very weak electron affinities? Why do you think this is so?
  2. Investigate: Select Groups. The periodic table is divided into metals and nonmetals. Metals are to the left of the metalloids and nonmetals to the right. To the left of the table you will see a list of group names. Click on each group name to reveal its properties. A. Metals tend to have low ionization energies. What properties of elements in the metal groups do you think are the result of this tendency? B. Except for the noble gases, nonmetals tend to have high electron affinities. What properties of nonmetals do you think are the result of this tendency?
  3. Analyze: The metallic character of an element is determined by how readily it loses electrons. Elements that lose electrons most easily have the greatest metallic character. A. Which group has the greatest metallic character? B. Which group has the lowest metallic character? C. What is the relationship between metallic character and ionization energy?
  4. Summarize: ✏ Hand draw in this space or click here to select EDIT to use the drawing tool. Group 1 Group 18 The ionization energy decreases as metallic character increases.

ase eat Metals don’t hold electrons well, instead they lose electrons due to weak attraction. Nonmetals gains electrons due to strong attraction.

AR

increases

IE and

EA

decreases

A. Label the metals and the nonmetals. B. For the vertical arrow, indicate the trend for atomic radius (AR), ionization energy (IE) and electron affinity (EA) by adding a text box and labeling next to the arrow whether each property increases or decre s. C. Rep the instructions in B for the horizontal arrow. D. For the diagonal arrow, indicate whether metallic character increases or decreases. What conclusion can you draw about the ability of metals to hold on to and attract electrons, as compared to nonmetals?

Metallic character decreases

Nonmetals

Metals

AR decreases

IE and EA

increases