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This problem set covers various aspects of angular momentum and quantum states. Topics include showing that the angular momentum operator in a certain basis depends on the phase, normalization and expectation values calculation for a specific state, constructing matrices for angular momentum operators and verifying their commutation relations, and understanding the relationship between different basis sets. This problem set emphasizes the physical significance of relative phases and the importance of complete basis sets.
Typology: Assignments
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2
1 γ ψ
i
x
L (^). The fact
that the expectation value depends on the phase γ is a demonstration of the general
principle that while the overall phase of a states is unphysical, the relative phase
between different components has physical significance.
are of the form n^ lm where n is the radial quantum number and l and m describe the
angular degrees of freedom. Suppose the system is in the state
10
3
10
1
2
1
2
1
2
1 ψ = − − + i + − − .Verify that the
state is normalized and calculate the following expectation values:
ψ ψ z
ψ ψ
2 ˆ L
ψ ψ
2 ˆ
z
ψ ψ y
ψ ψ x
y
z
and
2 ˆ L and that the matrices were block diagonal.
a) Working in the block with l =1 explicitly construct the 3 by 3 matrices associated
with these four operators.
b) Denote the matrices associated with x
y
z
as x
y
z
show that they
satisfy the same commutation relations as the operators:
x y z
L L i L
y z x
L L i L
z x y
L L i L
c) Show that as matrices
(^2 )
L L L L x x x
2 L
is the matrix associated with
2 ˆ L
and
2 ˆ L we
equally well could have picked x
and
2 ˆ L
. Let us denote the new basis as the primed
basis. The primed basis states are normalized and have the following properties
L lm mlm x
= (i)
2 2 L lm = l l + lm (ii)
by direct analogy with the usual basis states. Since each basis set is complete any of the
primed basis states can be written as a superposition of unprimed states with the same l:
1 2 1 2
l m ' c lm
n
where lm 2 m 1
c (^) are coefficients.
a) Using the properties (i) and (ii) above the matrix elements we computed in class plus
normalization to show that
2
1
2
1
2
1 = + + −
2
1
2
1 = + −
2
1
2
1
2
1 − = − + −
b) Explain how the linear combinations given in part a) can be understood in terms of
the eigenvectors and eigenvalues of the matrix x
constructed in problem 3.