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The six vertex model is a statistical mechanics model of ice crystals. Oxygen atoms sit at vertices of a square lattice; Hydrogen atoms.
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Gus Schrader
Michael Zhao Memorial Colloquium October 30, 2019
An n × n alternating sign matrix is a matrix such that each entry of the matrix is either 0, 1 or −1. the sum of entries in each row and column is 1, and the non-zero entries in each row and column alternate in sign.
Conjecture (Mills, Robbins, Rumsey, early 80s) The number of n × n alternating sign matrices is given by
|ASMn| =
n∏− 1
k=
(3k + 1)! (n + k)!
A proof of the ASM conjecture was announced by Doron Zeilberger in December 1992 – by mid 1994 all gaps in the 84 page paper had been filled and cases checked:
The six vertex model is a statistical mechanics model of ice crystals.
Oxygen atoms sit at vertices of a square lattice; Hydrogen atoms live on the edges, and can be in one of two energy minima (closer to one of the two oxygen atoms)
But each Oxygen atom must have exactly two Hydrogens close to it to form a H 2 O molecule!
If we assign a weight wi to each of the 6 possible vertex types, define the weight of an arrow configuration σ on a finite domain D to be the product of all weights of vertices in σ.
The partition function of the model on the domain D is then the weighted enumeration
Z (D) =
all states σ
weight(σ).
Six vertex model can also be thought of as a model of interacting paths:
It’s the interaction between the paths in the 6-vertex model that makes it tricky to analyze.
After all, the number of non-intersecting ensembles of n paths in any acyclic directed graph Γ starting at vertices A = {a 1 ,... , an} and ending at vertices B = {b 1 ,... , bn} is computed by the Lindst¨om-Gessel-Viennot Lemma:
#paths (A → B) = det [E (ai , bj )]ni,j=1 ,
where E (ai , bj ) = #paths from ai → bj. (cf Wick’s theorem for free fermions, Kasteleyn determinant for dimers, etc...)
The 6-vertex is more subtle than a model of free fermions, and for general boundary conditions its partition function does not have a determinant representation.
Nonetheless, for a special type of boundary condition on the square grid called the domain wall, one can use the integrability of the model to exactly calculate the partition function.
Observation: (Elkies-Kuperberg-Larsen-Propp ’92) The assignment
defines a bijection
{n × n ASM’s} ↔ {6-vertex states on n × n grid with DWBC. }
Baxter’s discovery: suppose q, x are nonzero complex numbers, and we choose vertex weights of the form
Consider V = C^2 ' V ∗^ with orthonormal basis {e 1 , e 2 }.
We can think of a vertex as representing a 4-legged tensor in V ⊗ V ⊗ V ∗^ ⊗ V ∗, whose matrix elements with respect to the basis {e 1 ⊗ e 1 , e 1 ⊗ e 2 , e 2 ⊗ e 1 , e 2 ⊗ e 2 } are given by the vertex weights: