Approximate Ground State and Excitation Energy for an Attractive Potential in Physics 401 , Assignments of Quantum Physics

Instructions for solving problems related to the time-independent schrödinger equation for an attractive potential in terms of dimensionless variables. How to find the approximate ground state energy and excitation energy of the first excited state in the limit of large ρ, as well as how to numerically solve for the ground state energy and plot the approximate wave function for specific potentials. The document assumes prior knowledge of quantum mechanics and calculus.

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Pre 2010

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Physics 401 Homework 9---Due November 11
The first three problems are based on the time-independent Schrödinger equation for an attractive
potential in terms of dimensionless variables:
)()()(
2
2
2ξψεξψξρ
ξ=
+
f
where
)()( 0
0x
x
fVxV =
,
0
x
x
ξ
,
2
2
00
22
xVm
ρ
,
2
2
0
2
xEm
ε
.
1. As
ρ
becomes large the well becomes deep and supports many bound states. The
lowest lying states are well-localized at the bottom of the well where the well looks
harmonic.
a. From this you should be able to show that in the limit of large
ρ
the ground
state dimensionless energy,
0
ε
is given approximately by
where
max
ξ
is the value of
ξ
which
maximizes f (i.e. miminimizes the potential which is attractive).
b. Show that the excitation energy of the first excited state in dimensionless
units is given approximately by
)(2 max01 ξρεε f
.
The approximations in a. and b. should become more an accurate as ρ increases
and become exact in the
ρ
limit.
c. Consider the case where
)cosh(
1
)( ξ
ξ =f
. Show that the approximate
ground state energy and excitation energy of the first excited state in
dimensionless units is given by
ρρε 2
1
2
0+
ρεε 2
01
2. Numerically solve for the ground state for the for the potential with
)cosh(
1
)( ξ
ξ =f
. Determine the bound state energies by adjusting the energy until
the wave function has a very small exponentially growing part. Plot the approximate
wave function. You may find the mathematica notebook on the course website
useful.
a. Do this analysis for the case where
.10=ρ
b. Do this analysis for the case where
.100=ρ
3. Verify that the energies obtained in 2a. and 2b. are close to those given by the
approximations in 1c. Which case works better in terms of number of accurately
predicted digits? Why?
Griffths: 2.30, 2.52

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Physics 401 Homework 9---Due November 11

The first three problems are based on the time-independent Schrödinger equation for an attractive

potential in terms of dimensionless variables:

2

2

2

ρ ξ ψ ξ εψ ξ

ξ

f where

0

0 x

x

V x = − V f ,

0

x

x

ξ ≡ ,

2

2

0 0

2

mV x

ρ ≡

,

2

2

0

mE x

ε ≡

.

  1. As

ρ

becomes large the well becomes deep and supports many bound states. The

lowest lying states are well-localized at the bottom of the well where the well looks

harmonic.

a. From this you should be able to show that in the limit of large

ρ

the ground

state dimensionless energy,

0

ε is given approximately by

max

max

2

0

ξ

ε ρ ξ ρ

f

f

≈ − + where

max

ξ is the value of

ξ which

maximizes f ( i.e. miminimizes the potential which is attractive).

b. Show that the excitation energy of the first excited state in dimensionless

units is given approximately by 2 ( )

1 0 max

ε − ε ≈ρ − f ′′ξ.

The approximations in a. and b. should become more an accurate as ρ increases

and become exact in the

ρ →∞

limit.

c. Consider the case where

cosh( )

ξ

f ξ =

. Show that the approximate

ground state energy and excitation energy of the first excited state in

dimensionless units is given by ε ρ ρ

2

1

2

0

≈ − + ε ε 2 ρ

1 0

  1. Numerically solve for the ground state for the for the potential with

cosh( )

ξ

f ξ =

. Determine the bound state energies by adjusting the energy until

the wave function has a very small exponentially growing part. Plot the approximate

wave function. You may find the mathematica notebook on the course website

useful.

a. Do this analysis for the case where

ρ= 10.

b. Do this analysis for the case where

ρ= 100.

  1. Verify that the energies obtained in 2a. and 2b. are close to those given by the

approximations in 1c. Which case works better in terms of number of accurately

predicted digits? Why?

Griffths: 2.30, 2.