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Instructions for solving problems related to the time-independent schrödinger equation for an attractive potential in terms of dimensionless variables. How to find the approximate ground state energy and excitation energy of the first excited state in the limit of large ρ, as well as how to numerically solve for the ground state energy and plot the approximate wave function for specific potentials. The document assumes prior knowledge of quantum mechanics and calculus.
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The first three problems are based on the time-independent Schrödinger equation for an attractive
potential in terms of dimensionless variables:
2
2
2
ρ ξ ψ ξ εψ ξ
ξ
f where
0
0 x
x
V x = − V f ,
0
x
x
ξ ≡ ,
2
2
0 0
2
mV x
ρ ≡
,
2
2
0
mE x
ε ≡
.
ρ
becomes large the well becomes deep and supports many bound states. The
lowest lying states are well-localized at the bottom of the well where the well looks
harmonic.
a. From this you should be able to show that in the limit of large
ρ
the ground
state dimensionless energy,
0
ε is given approximately by
max
max
2
0
ξ
ε ρ ξ ρ
f
f
≈ − + where
max
ξ is the value of
ξ which
maximizes f ( i.e. miminimizes the potential which is attractive).
b. Show that the excitation energy of the first excited state in dimensionless
units is given approximately by 2 ( )
1 0 max
ε − ε ≈ρ − f ′′ξ.
The approximations in a. and b. should become more an accurate as ρ increases
and become exact in the
ρ →∞
limit.
c. Consider the case where
cosh( )
ξ
f ξ =
. Show that the approximate
ground state energy and excitation energy of the first excited state in
dimensionless units is given by ε ρ ρ
2
1
2
0
≈ − + ε ε 2 ρ
1 0
cosh( )
ξ
f ξ =
. Determine the bound state energies by adjusting the energy until
the wave function has a very small exponentially growing part. Plot the approximate
wave function. You may find the mathematica notebook on the course website
useful.
a. Do this analysis for the case where
ρ= 10.
b. Do this analysis for the case where
ρ= 100.
approximations in 1c. Which case works better in terms of number of accurately
predicted digits? Why?
Griffths: 2.30, 2.