Quiz 1 - Solution and Explanation - Principles of Chemistry II | CH 302, Quizzes of Chemistry

Material Type: Quiz; Professor: Laude; Class: PRINCIPLES OF CHEMISTRY II; Subject: Chemistry; University: University of Texas - Austin; Term: Unknown 1989;

Typology: Quizzes

Pre 2010

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Version 001 Quiz 1 David Laude (53015) 1
This print-out should have 8 questions.
Multiple-choice questions may continue on
the next column or page find all choices
before answering. V1:1, V2:1, V3:1, V4:1,
V5:2.
You will have 20 minutes for the quiz.
Please make sure you write your version num-
bers on your scantron. Good luck!
ChemPrin3e T06 35
18:05, general, multiple choice, <1 min, fixed.
001 (part 1 of 1) 5 points
How much heat is required to vaporize 50.0
g of water if the initial temperature of the
water is 25.0C and the water is heated to
its boiling point where it is converted to
steam? The specific heat capacity of water
is 4.18 J ·(C)1·g1and the standard en-
thalpy of vaporization of water at its boiling
point is 40.7 kJ ·mol1.
1. 169 kJ
2. 64.2 kJ
3. 40.7 kJ
4. 129 kJ correct
5. 23.5 kJ
Explanation:
m= 50 g Ti= 25C
Tf= 100CC= 4.18 J/g/C
Hvap = 40.7 kJ/mol
H=m C T+m
MM Hvap
= (50 g) (4.18 J/g/C)
×(100 25)C1 kJ
1000 J
+50 g
18 g/mol (40.7 kJ/mol)
= 128.731 kJ
ChemPrin3e T08 34
14:10, basic, multiple choice, <1 min, fixed.
002 (part 1 of 1) 5 points
The phase diagram for CO2is given below.
Solid
Liquid
Vapor
Temperature, K
Pressure, atm
The triple point is at 5.1 atm and 217 K.
What happens if CO2(`) at 30 atm and 450 K
is released into a room at 1 atm and 298 K?
1. The liquid vaporizes. correct
2. The liquid remains stable.
3. The liquid and vapor are in equilibrium.
4. The liquid and solid are in equilibrium.
5. The liquid freezes.
Explanation:
Sparks dissolve 001
16:04, general, multiple choice, <1 min, fixed.
003 (part 1 of 1) 5 points
For an endothermic dissolution process, as
temperature increases, solubility
1. decreases.
2. increases. correct
3. stays the same.
Explanation:
Consider an endothermic process:
solid + heat dissolved products
As heat is added, equilibrium will shift
towards a higher concentration of dissolved
products.
DAL Miscible
pf3

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This print-out should have 8 questions. Multiple-choice questions may continue on the next column or page – find all choices before answering. V1:1, V2:1, V3:1, V4:1, V5:2. You will have 20 minutes for the quiz. Please make sure you write your version num- bers on your scantron. Good luck!

ChemPrin3e T06 35 18:05, general, multiple choice, < 1 min, fixed. 001 (part 1 of 1) 5 points How much heat is required to vaporize 50. g of water if the initial temperature of the water is 25.0◦C and the water is heated to its boiling point where it is converted to steam? The specific heat capacity of water is 4.18 J · (◦C)−^1 · g−^1 and the standard en- thalpy of vaporization of water at its boiling point is 40.7 kJ · mol−^1.

  1. 169 kJ
  2. 64.2 kJ
  3. 40.7 kJ
  4. 129 kJ correct
  5. 23.5 kJ

Explanation: m = 50 g Ti = 25◦C Tf = 100◦C C = 4.18 J/g/◦C ∆Hvap = 40.7 kJ/mol

H = m C ∆T +

m MM

∆Hvap = (50 g) (4.18 J/g/◦C)

×(100 − 25)◦C

1 kJ 1000 J

50 g 18 g/mol

(40.7 kJ/mol)

= 128.731 kJ

ChemPrin3e T08 34 14:10, basic, multiple choice, < 1 min, fixed. 002 (part 1 of 1) 5 points The phase diagram for CO 2 is given below.

Solid

Liquid

Vapor

Temperature, K

Pressure, atm

The triple point is at 5.1 atm and 217 K. What happens if CO 2 (`) at 30 atm and 450 K is released into a room at 1 atm and 298 K?

  1. The liquid vaporizes. correct
  2. The liquid remains stable.
  3. The liquid and vapor are in equilibrium.
  4. The liquid and solid are in equilibrium.
  5. The liquid freezes.

Explanation:

Sparks dissolve 001 16:04, general, multiple choice, < 1 min, fixed. 003 (part 1 of 1) 5 points For an endothermic dissolution process, as temperature increases, solubility

  1. decreases.
  2. increases. correct
  3. stays the same.

Explanation: Consider an endothermic process: solid + heat → dissolved products As heat is added, equilibrium will shift towards a higher concentration of dissolved products.

DAL Miscible

16:02, general, multiple choice, < 1 min, fixed. 004 (part 1 of 1) 5 points Based simply on the molecular formula pro- vided, which of the following compounds is least likely to be miscible in cyclohexane (C 6 H 12 )?

  1. methanol (CH 3 OH) correct
  2. benzene (C 6 H 6 )
  3. phenol (C 6 H 5 OH)
  4. Each contains a hydrocarbon unit and should be equally miscible.
  5. naphthalene (C 10 H 8 )

Explanation:

ChemPrin3e T08 06 18:06, general, multiple choice, < 1 min, fixed. 005 (part 1 of 1) 5 points Estimate the enthalpy of vaporization of CCl 4 given that at 25◦C and 58◦C its vapor pressure is 107 and 405 torr, respectively. Assume that the enthalpy of vaporization is independent of the temperature.

  1. 486 J·mol−^1
  2. 48.6 kJ· mol−^1
  3. 142 kJ·mol−^1
  4. 3.98 kJ·mol−^1
  5. 33.1 kJ·mol−^1 correct

Explanation:

Msci 14 1501A 17:05, general, multiple choice, < 1 min, fixed. 006 (part 1 of 1) 5 points Consider the solutions I) 1.0 M Na 2 SO 4 , II) 1.0 M NaCl, and III) 1.0 M sugar. What answer gives the expected order of de- creasing (highest, next, lowest) osmotic pres-

sure?

  1. I, II, III correct
  2. II, I, III
  3. III, II, I
  4. III, I, II
  5. II, III, I
  6. All would have the same osmotic pres- sure. Explanation: The equation for osmotic pressure is π = M R T where π is the osmotic pressure, M is the molarity, and R and T are the same for the ideal gas law. If molarity increases then the osmotic pressure increases (they are directly proportional). Since this is a colligi- tive property, it is the number of moles of the particles that is important. Since sugar does not ionize, there is only one mole of particles present for each mole of sugar dissolved, so its effective molarity is 1.0 M. Each NaCl ionizes to give two ions so the effective molarity is 2(1.0) = 2.0 M. And lastly Na 2 SO 4 ; this also ionizes and gives three ions, so its effective molarity is 3(1.0) = 3.0 M.

ChemPrin3e T08 60 17:02, general, multiple choice, < 1 min, fixed. 007 (part 1 of 1) 5 points Calculate the vapor pressure at 25◦C of a mixture of benzene and toluene in which the mole fraction of benzene is 0.650. The vapor pressure at 25◦C of benzene is 94.6 torr and that of toluene is 29.1 torr.

  1. 84.4 torr
  2. 124 torr
  3. 51.3 torr
  4. 71.7 torr correct
  5. 61.5 torr