Quiz 7 Questions - Organic Chemistry, Fall 2007 | CHEM 238, Quizzes of Organic Chemistry

Material Type: Quiz; Class: ORGANIC CHEMISTRY; Subject: Chemistry; University: University of Washington - Seattle; Term: Winter 2006;

Typology: Quizzes

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Quiz 7 Name: _____________________________
CHEM 238 A Section: ________________
March 9, 2006
1. Draw two resonance structures for the enolate anion of butanal. Show all hydrogens, bonds,
unshared electrons, and charges. (2 points)
H
O
H
O
2. Show the major organic products for the following reactions. Write “No Reaction” if there
is none. When appropriate, clearly show the stereochemistry and indicate if enantiomers are
formed. (8 points)
NO
2
O
NaOH
Δ
H
3
CO H
O
H
3
CO
O
NO
2
(H
3
C)
2
HCH
2
CCCH
3
O
CF
3
COOOH
(H
3
C)
2
HCH
2
COCCH
3
O
CH
2
PPh
3
CHO NaH, DMF
CHO
OH
+
O
Δ

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Quiz 7 Name: _____________________________

CHEM 238 A Section: ________________

March 9, 2006

1. Draw two resonance structures for the enolate anion of butanal. Show all hydrogens, bonds,

unshared electrons, and charges. (2 points)

H

O

H

O

2. Show the major organic products for the following reactions. Write “No Reaction” if there

is none. When appropriate, clearly show the stereochemistry and indicate if enantiomers are

formed. (8 points)

NO 2

O

NaOH Δ

H 3 CO

H

O

H 3 CO

O

NO 2

(H 3 C) 2 HCH 2 C CCH 3

O

CF 3 COOOH

(H 3 C) 2 HCH 2 C OCCH 3

O

CH 2 PPh 3 CHO^ NaH, DMF CHO

O H+

O