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Safety Data Sheet for Phosphorus Pentachloride by FUJIFILM Wako Pure Chemical Corporation, Lecture notes of Law

Law

A Safety Data Sheet (SDS) for Phosphorus Pentachloride, a hazardous substance manufactured by FUJIFILM Wako Pure Chemical Corporation. The SDS provides information on the product identification, hazard(s) identification, composition/information on ingredients, first-aid measures, accidental release measures, handling and storage, exposure controls, physical and chemical properties, stability and reactivity, toxicological information, ecological information, transport information, regulatory information, and other relevant information.

Typology: Lecture notes

2021/2022

Uploaded on 09/12/2022

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SAFETY DATA SHEET
According to JIS Z 7253:2019
Version 5.03
Revision Date 27-Jul-2020
Section 1: PRODUCT AND COMPANY IDENTIFICATION
Product name Phosphorus Pentachloride
Product code 162-02312,166-02315
Manufacturer FUJIFILM Wako Pure Chemical Corporation
1-2 Doshomachi 3-Chome
Chuo-ku, Osaka 540-8605, Japan
Phone: +81-6-6203-3741
Fax: +81-6-6203-5964
Supplier FUJIFILM Wako Pure Chemical Corporation
1-2 Doshomachi 3-Chome, Chuo-ku, Osaka 540-8605, Japan
Phone: +81-6-6203-3741
Fax: +81-6-6203-2029
Emergency telephone number +81-6-6203-3741 / +81-3-3270-8571
Recommended uses and
restrictions on use For research purposes
Section 2: HAZARDS IDENTIFICATION
GHS classification
Classification of the substance or mixture
Acute toxicity - Oral Category 4
Skin corrosion/irritation Category 1
Serious eye damage/eye irritation Category 1
Specific target organ toxicity (single exposure) Category 1, Category 2
Category 1 respiratory system
Category 2 circulatory system
Specific target organ toxicity (repeated exposure) Category 2
Category 2 bone
Pictograms
Signal word Danger
Hazard statements
H314 - Causes severe skin burns and eye damage
H318 - Causes serious eye damage
H302 - Harmful if swallowed
H370 - Causes damage to the following organs: respiratory system
H371 - May cause damage to the following organs: circulatory system
H373 - May cause damage to the following organs through prolonged or repeated exposure: bone
Precautionary statements-(Prevention)
• Wash face, hands and any exposed skin thoroughly after handling
• Do not eat, drink or smoke when using this product
• Do not breathe dust/fume/gas/mist/vapors/spray
• Wear protective gloves/protective clothing/eye protection/face protection
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W01W0116-0231 JGHEEN Phosphorus Pentachloride
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SAFETY DATA SHEET

According to JIS Z 7253: Version 5. Revision Date 27-Jul-

Section 1: PRODUCT AND COMPANY IDENTIFICATION

Product name Phosphorus Pentachloride

Product code 162-02312,166-

Manufacturer FUJIFILM Wako Pure Chemical Corporation 1-2 Doshomachi 3-Chome Chuo-ku, Osaka 540-8605, Japan Phone: +81-6-6203- Fax: +81-6-6203- Supplier FUJIFILM Wako Pure Chemical Corporation 1-2 Doshomachi 3-Chome, Chuo-ku, Osaka 540-8605, Japan Phone: +81-6-6203- Fax: +81-6-6203- Emergency telephone number +81-6-6203-3741 / +81-3-3270- Recommended uses and restrictions on use For research purposes

Section 2: HAZARDS IDENTIFICATION

GHS classification Classification of the substance or mixture Acute toxicity - Oral Category 4 Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1 Specific target organ toxicity (single exposure) Category 1, Category 2 Category 1 respiratory system Category 2 circulatory system Specific target organ toxicity (repeated exposure) Category 2 Category 2 bone Pictograms Signal word Danger Hazard statements H314 - Causes severe skin burns and eye damage H318 - Causes serious eye damage H302 - Harmful if swallowed H370 - Causes damage to the following organs: respiratory system H371 - May cause damage to the following organs: circulatory system H373 - May cause damage to the following organs through prolonged or repeated exposure: bone Precautionary statements-(Prevention)

  • Washface,handsandanyexposedskinthoroughlyafterhandling
  • Donoteat,drinkorsmokewhenusingthisproduct
  • Donotbreathedust/fume/gas/mist/vapors/spray
  • Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection

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Precautionary statements-(Response)

  • IFIN EYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continue rinsing.
  • ImmediatelycallaPOISON CENTER ordoctor/physician
  • IFON SKIN (orhair):Remove/Takeoffimmediatelyallcontaminatedclothing.Rinseskinwithwater/shower.
  • Washcontaminatedclothingbeforereuse.
  • IFINHALED:Removevictim tofreshairandkeepatrestinapositioncomfortableforbreathing.
  • IFSWALLOWED:CallaPOISON CENTER ordoctor/physicianifyoufeelunwell
  • Rinsemouth.
  • DoNOTinducevomiting. Precautionary statements-(Storage)
  • Storelockedup. Precautionary statements-(Disposal)
  • Disposeofcontents/containertoanapprovedwastedisposalplant Others Other hazards Not available Section 3: COMPOSITION/INFORMATION ON INGREDIENTS Single Substance or Mixture Substance Formula PCl Chemical Name Weight-%^ Molecular weight^ ENCS ISHL No. CAS RN Phosphorus pentachloride

96.0 208.24^ (1)-250 公表 10026-13-

Impurities and/or Additives：：：： Not applicable Section 4: FIRST AID MEASURES Inhalation Remove to fresh air. If symptoms persist, call a physician. Skin contact Wash off immediately with soap and plenty of water. If symptoms persist, call a physician. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediate medical attention is required. Ingestion Rinse mouth. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately. Do not induce vomiting without medical advice. Protection of first-aiders Use personal protective equipment as required. Section 5: FIRE FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment Unsuitable extinguishing media Do not use straight streams Specific hazards arising from the chemical product Thermal decomposition can lead to release of irritating and toxic gases and vapors. Special extinguishing method No information available Special protective actions for fire-fighters Use personal protective equipment as required. Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear.

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Color White - slightly yellow Appearance crystals - crystalline powder or mass Odor Pungent odor Melting point/freezing point 179 - 181 °C Boiling point, initial boiling point and boiling range No data available Flammability No data available Evaporation rate: No data available Flammability (solid, gas): No data available Upper/lower flammability or explosive limits Upper：：：： No data available Lower：：：： No data available Flash point No data available Auto-ignition temperature: No data available Decomposition temperature: No data available pH No data available Viscosity (coefficient of viscosity) No data available Dynamic viscosity No data available Solubilities water , Ethanol : decomposes. ether , benzene , carbon tetrachloride , carbon disulfide : soluble. n-Octanol/water partition coefficient:(log Pow) No data available Vapour pressure No data available Specific Gravity / Relative density 1. Vapour density No data available Particle characteristics No data available Section 10: STABILITY AND REACTIVITY Stability Reactivity No data available Chemical stability Stable under recommended storage conditions. Hazardous reactions None under normal processing Conditions to avoid Extremes of temperature and direct sunlight, Moisture Incompatible materials Water, Alcohols Hazardous decomposition products Phosphorus oxide, Halides Section 11: TOXICOLOGICAL INFORMATION Acute toxicity Chemical Name Oral LD50 Dermal LD50 Inhalation LC Phosphorus pentachloride 600 mg/kg ( Rat ) 660 mg/kg ( Rabbit ) N/A Chemical Name Acute toxicity -oral- source information Acute toxicity -dermal- source information Acute toxicity -inhalation gas- source information Phosphorus pentachloride Based on the NITE GHS classification results. Based on the NITE GHS classification results. Based on the NITE GHS classification results. Chemical Name Acute toxicity -inhalation vapor- source information Acute toxicity -inhalation dust- source information Acute toxicity -inhalation mist- source information Phosphorus pentachloride Based on the NITE GHS classification results. Based on the NITE GHS classification results. Based on the NITE GHS classification results. Skin irritation/corrosion Chemical Name Skin corrosion/irritation source information Phosphorus pentachloride Based on the NITE GHS classification results. Serious eye damage/ irritation Chemical Name Serious eye damage/irritation source information

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Phosphorus pentachloride Based on the NITE GHS classification results. Respiratory or skin sensitization Chemical Name Respiratory or Skin sensitization source information Phosphorus pentachloride Based on the NITE GHS classification results. Reproductive cell mutagenicity Chemical Name germ cell mutagencity source information Phosphorus pentachloride Based on the NITE GHS classification results. Carcinogenicity Chemical Name Carcinogenicity source information Phosphorus pentachloride Based on the NITE GHS classification results. Reproductive toxicity Chemical Name Reproductive toxicity source information Phosphorus pentachloride Based on the NITE GHS classification results. STOT-single exposure Chemical Name STOT -single exposure- source information Phosphorus pentachloride Based on the NITE GHS classification results. STOT-repeated exposure Chemical Name STOT -repeated exposure- source information Phosphorus pentachloride Based on the NITE GHS classification results. Aspiration hazard Chemical Name Aspiration Hazard source information Phosphorus pentachloride Based on the NITE GHS classification results. Section 12: ECOLOGICAL INFORMATION Ecotoxicity No information available Other data Chemical Name Short-term (acute) hazardous to the aquatic environment source information Long-term (chronic) hazardous to the aquatic environment source information Phosphorus pentachloride Based on the NITE GHS classification results. Based on the NITE GHS classification results. Persistence and degradability No information available Bioaccumulative potential No information available Mobility in soil No information available Hazard to the ozone layer No information available Section 13: DISPOSAL CONSIDERATIONS Waste from residues Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated container and contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Section 14: TRANSPORT INFORMATION ADR/RID UN number UN Proper shipping name: Phosphorus pentachloride UN classfication 8 Subsidiary hazard class Packing group II Marine pollutant Not applicable IMDG UN number UN

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Disclaimer This SDS is according to JIS Z 7253: 2019. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. GHS Classification is according to JIS Z7252(2019). *JIS: Japanese Industrial Standards End of Safety Data Sheet

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