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A comprehensive overview of basic chemistry concepts, including the definition and properties of compounds, types of chemical reactions, and the characteristics of acids and bases. It includes examples, chemical formulas, and balancing equations, making it a valuable resource for high school chemistry students.
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A compound is a substance in which the atoms of two or more elements are joined together by chemical bonds. Because of these bonds, it can be very difficult to split a compound into its individual elements. The properties of a compound can be very different from those of the elements it contains. For example, the salt we use in our food is a harmless compound, yet it is made up of two dangerous elements -- sodium, which reacts violently with air; and chlorine, which is a poisonous gas. Another important characteristic of a compound is that the weight of each element in the compound always has a fixed, definite ratio to the weight of the other elements in the compound. For example, water always breaks down into 2.016 parts of hydrogen by weight to 16.000 parts of oxygen by weight, which is a ratio of about 1 to 8, regardless of whether the water came from the Mississippi River or the ice of Antarctica. In other words, a compound has a definite, invariable composition, always containing the same elements in the same proportions by weight; this is the law of definite proportions. Water is an example of a compound. A water molecule consists of an oxygen atom and two hydrogen atoms. Many elements combine in more than one ratio, giving different compounds. In addition to forming water, hydrogen and oxygen also form hydrogen peroxide. Hydrogen peroxide has 2.016 parts of hydrogen to 32 parts of oxygen; that is, 1.008 parts of hydrogen to 16 parts of oxygen. Water, as stated above, has 2.016 parts of hydrogen to 16 parts of oxygen. The figure 2.016 is twice 1.008. This example illustrates the law of multiple proportions. When two elements combine to form more than one compound, the element whose mass varies combines with a fixed mass of the second element weights in a simple whole- number ratio such as 2:1, 3:1, or 3:2. BINARY COMPOUNDS A binary compound is one that is formed from two types of elements. Three possibilities exist. metal + metal → metallic compound metal + non-metal →ionic compound non-metal + non-metal → covalent compound Metallic compounds The metallic elements are found on the left-hand side of the Periodic Table. The proposed structure for samples of metals is that of the "band theory" of metallic bonding. Metal samples are considered to be composed of metal atoms that are held together by delocalized bonds formed by all of the atoms in the sample. It is proposed that electrons can move easily within the sample. Ionic Compounds Ionic compounds are crystalline compounds in which the forces providing the structure of the material are ionic bonds. The crystals are made up of positive and negative ions, but the compounds themselves possess no net charge since the oppositely charged ions exist in a perfect balance with each other. The common table salt, is a representative of an important class of compounds called salts. A salt consists of positive and negative ions, Na and Cl in NaCl. Covalent Compounds Covalent compounds are compounds in which the atoms are held together by covalent bonds. It has lower melting and boiling points than ionic compounds. Covalent compounds are usually gases or liquids, although some are solids with giant molecular structures. The gases have no significant forces of attraction between molecules.Covalent compounds are formed as a result of the reaction of nonmetallic elements. They cannot dissociate into ions, so they cannot function as electrolytes. Many covalent compounds are insoluble in water, but may dissolve in a number of organic solvents.
Chemical Groups Atoms often tend to combine in certain fixed proportions to form relatively stable units. These units may remain unchanged throughout a number of chemical processes, and some may exist independently in certain chemical environments. These units were formerly called radicals, but are now known as groups.
Compounds containing a metal will be based on the name of the elemental metal plus the name of the anion. The name of simple non-metal anions convert the ending of the element name with -ide. Polyatomic anions usually end with -ite or -ate. (Note that Hydroxide OH-, is an exemption.) Common anions containing non-metals symbol name symbol name symbol name symbol name
− (^) fluoride
− (^) chloride
− (^) chlorite
2 − (^) chlorate
− (^) perchlorate
− (^) bromide
2 − (^) bromate
− (^) iodide
2 − (^) iodate
2 − (^) oxide
− (^) hydroxide
2 − (^) peroxide
2 − (^) sulfide
2 − (^) sulfite
2 − (^) sulfate
2 − (^) selenide
3 − (^) nitride
− (^) nitrite
− (^) nitrate
3 − (^) phosphide
2 − (^) phosphate
3 − (^) arsenide
3 − (^) arsenite
2 − (^) arsenate
4 − (^) carbide
2 − (^) carbonate
4 − (^) silicide
4 − (^) silicate Metals with multiple oxidation states use a Roman numeral in parentheses to specify the oxidation state. METALS WITH MULTIPLE OXIDATION FORMULA WRITE AS READ AS
The names of the non metallic compounds use the name of the first element in the formula followed by the name of the other elements in the compound, modified as above. A prefix indicates the number of each atom in the compound.
Basic form: AX + BY → AY + BX WRITING AND BALANCING CHEMICAL EQUATIONS The Law of Conservation of Mass states that mass is neither created nor destroyed in any chemical reaction. Therefore, balancing of the equations requires the same number of atoms on both sides of a chemical reaction. The mass of all the reactants (the substances going into a reaction) must equal the mass of the products (the substances produced by the reaction). Note that in a chemical equation, by convention, we use the arrow "→" instead of the equal "=" sign. Steps in Balancing Chemical Equation:
Acids and bases, and the salts produced by the reaction between acids and bases, are the principal classifications of chemical substances. These categories were established long before their physical nature or the reasons for their characteristic properties were understood. The word acid is derived from the Latin acetum , "vinegar." Aqueous solutions that contain hydrogen ions are called acids, while those that contain hydroxyl ions are called alkalis. Substances that dissolve in water to form an alkali are called bases. If an acid and a base are mixed, the two substances react to form a chemical salt. Salts are ionic compounds which, when dissolved in water, break up completely into ions. . Characteristics: Acids taste sour, are corrosive to metals, change litmus red, and become less acidic when mixed with bases. Bases feel slippery, change litmus blue, and become less basic when mixed with acids. INORGANIC ACIDS AND BASES Inorganic acids and bases are those made from such elements as sulfur, phosphorus, and nitrogen. The inorganic acid sulfuric acid is by far the largest single product of the chemical industry. This acid is used in the manufacture of fertilizer, the refining of petroleum, and the pickling of metals (removing of impurities). Nitric acid is used in the manufacture of explosives and dyestuffs. Of the bases, the hydroxides of sodium and potassium are used in soap, and ammonia is used in fertilizer. pH The acidity or alkalinity of a solution can be measured using the pH scale, which runs from 1 to 14. Those with a pH lower than 7 are acidic. The lower the pH, the stronger the acid. Solutions with a pH greater than 7 are alkaline. The higher the pH, the stronger the alkali. Pure water with pH of 7 are neutral. Measurement of pH can be done by using indicators. Indicators are substances that change color with a change in pH. The exact amount of base required to neutralize an unknown acid and the pH at the halfway point of the neutralization of an acid are characteristic of that particular acid and may allow its identification or quantification. The pH of a buffer, a solution of a weak acid or base and its salt, changes only slightly when stronger acids or bases are added. Buffers are often used as a standard for pH measurement. The measurement and control of pH is important in the manufacture of foods, paper, and chemicals. In agriculture, testing and maintenance of soil pH are necessary for good yields of crops. Maintenance of water quality and the study of acid rain illustrate the application of pH measurement methods in environmental science.
A. Match the following B. Write the formula Chemical name Chemical formula
q. MgS Aluminium sulfide Iron (III) nitrate Cobalt (II) sulfate Nitrogen monoxide Aluminium oxide Iron (III) hydroxide Barium phosphate Chromium (III) fluoride Ammonium nitrate Manganese (IV) sulfide