Soap Making Laboratory: Understanding the Saponification Process, Study notes of Chemical Experimentation

Information about a soap making laboratory session held at adm biorenewables education laboratory during the summer academy in 2014. The session covered the learning objectives and outcomes of the soap making process, including the definition of saponification, the role of acids and bases, and the use of essential oils. The document also includes safety instructions and procedures for soap production and curing.

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ADM Biorenewables Education Laboratory Soap Lab
Summer Academy 06/10/2014
Gabriel Domingues & Matt Schul
Soap Lab
Learning Objectives:
Gained an understanding of the saponification process.
Gained an understanding of raw soap and its uses.
Developed and processed different oil based soaps.
Gained “hands-on” experience in the preparation, processing and fabrication of different oil
based soaps.
Learning Outcomes:
Define saponification.
Be able to discuss the process of saponification.
Be able to define what a base and acid are.
Be able to explain what triglycerides are.
Be able to use pH strips to test soap after curing process.
Pre-Lab
Background
Saponification is a process in which a fat molecule is broken down by sodium hydroxide (lye)
into four smaller molecules; three of the new molecules are soap and one is glycerol. In simple
terms saponification is the name for a chemical reaction between an acid and a base to form a salt.
An acid is a molecule or ion that donates protons or hydrogen ions (H+) and/or accepts electrons,
and a base is any substance that donates electrons or hydroxide ions (OH-) and/or that accepts
protons.
When you make soap, you mix an oil or fat (which is your acid) with Sodium Hydroxide or Lye
(which is your base) to form soap (which is a salt). There are many different types of acids that
will react with your base and saponify. Your acid could be olive oil, coconut oil or vegetable oil just
to name a few. Each acid has a unique combination of triglycerides (compounds made of three
fatty acids attached to a single glycerol molecule) which combines with the base (sodium
hydroxide or lye) differently.
Figure 1. General saponification reaction
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Summer Academy 06/10/ Gabriel Domingues & Matt Schul

Soap Lab

Learning Objectives:

  • Gained an understanding of the saponification process.
  • Gained an understanding of raw soap and its uses.
  • Developed and processed different oil based soaps.
  • Gained “hands-on” experience in the preparation, processing and fabrication of different oil based soaps.

Learning Outcomes:

  • Define saponification.
  • Be able to discuss the process of saponification.
  • Be able to define what a base and acid are.
  • Be able to explain what triglycerides are.
  • Be able to use pH strips to test soap after curing process.

Pre-Lab

Background

Saponification is a process in which a fat molecule is broken down by sodium hydroxide (lye) into four smaller molecules; three of the new molecules are soap and one is glycerol. In simple terms saponification is the name for a chemical reaction between an acid and a base to form a salt. An acid is a molecule or ion that donates protons or hydrogen ions (H +) and/or accepts electrons, and a base is any substance that donates electrons or hydroxide ions (OH - ) and/or that accepts protons.

When you make soap, you mix an oil or fat (which is your acid) with Sodium Hydroxide or Lye (which is your base) to form soap (which is a salt). There are many different types of acids that will react with your base and saponify. Your acid could be olive oil, coconut oil or vegetable oil just to name a few. Each acid has a unique combination of triglycerides (compounds made of three fatty acids attached to a single glycerol molecule) which combines with the base (sodium hydroxide or lye) differently.

Figure 1. General saponification reaction

Summer Academy 06/10/ Gabriel Domingues & Matt Schul

Health and safety information for materials used:

  • Sodium hydroxide: Strong base which must be handled with care. Corrosive and caustic. It is important to make sure you are careful when mixing the water and sodium hydroxide.

Safety Checklist:

  • Proper attire is worn (long pants and closed-toe shoes).
  • Food and drinks are stored and consumed outside of the laboratory.
  • Lab coat and safety glass are worn.
  • Latex or nitrile gloves are used when handling samples and chemicals.
  • Insulated gloves are used when handling hot materials.
  • Chemical aprons are worn when handling methanol or sodium hydroxide.

Spill containment and clean up procedures:

  • If a spill occurs it is important that you wash any parts of your body that comes in contact with the spill. Do not wipe your face or body until everything has been washed completely. Regular cleaning spray and paper towels work fine for cleaning small spills.

Soap Production

Problem Statement:

You may be aware about the use of triglycerides to produce biodiesel. This lab uses triglycerides to produce soap. Soap making relies on an ester and a strong base to perform a saponification reaction. We will create a small bar of soap with the lab procedure discussed later.

Lab Checklist

  • 10 g of Sodium Hydroxide
  • 60 g of chosen oil: Soybean, Canola, Coconut, Vegetable oil, etc. (Most oils can be used).
  • 27 mL of distilled water
  • Erlenmeyer flask
  • Beaker
  • Hot plates (2)
  • Magnetic stir bar
  • Thermometers (2)
  • Weigh boat (Soap Container)
  • Transfer pipet
  • 2-3 mL of essential oils (for scent)

Summer Academy 06/10/ Gabriel Domingues & Matt Schul

Emergency Contacts

Jacqulyn Baughman Lab Supervisor Cell: (515) 505-

Marjorie Rover Lab Manager Office: (515) 294-2984 Cell: (319) 230-

Ryan Smith BEI Program Coordinator Office: (515) 294-6244 Cell: (515) 203-1640 Home: (719) 660-

Patrick Johnston Assistant Scientist III Office: (515) 509-0027 Cell: (515) 509-0027 Home: (319) 231-

Approved Trainers: Gabriel Domingues Matt Schul