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solid state electroni device solution streetman
Typology: Exercises
1 / 9
2 and
4 π^2 2 2 2 o n (^) = n^ rn (^) = n
2
is the th
o o
n
Prob. 2.
(a&b) Sketch a vacuum tube device. Graph photocurrent I versus retarding voltage V for several light intensities. I
Vo V
light in t ensity
Note that Vo remains same for all intensities.
(c) Find retarding potential.
λ=2440Å=0.244μm
V = hν - Φ = 1.24eV μm
=4.09eV
1.24eV μm
Prob. 2.
Show third Bohr postulate equates to integer number of DeBroglie waves fitting within circumference of a Bohr circular orbit.
4 n^2 r = q^2 mv^2 = and p = mvr n mq^2 4 n^2
4 π r^2 r r
r = n o mq^2 mr 2 q^2 mr 2 mv^2 m^2 v^2 r
m^2 v^2 r 2 = n^2 mvrn = n
B n n
p = n ird Bohr postulate
(^2 32) π 2 2 2 2 o n 2
(^2) π 2 =^8
PASCHEN SERIES n n^ 2 n^ 2 - 9 9n^ 2 /(n^ 2 - 9 ) 9119n^ 2 /(n^ 2 - 9) 4 16 7 20. 57 18741 5 25 16 14. 06 12811 6 36 27 12. 00 10932 7 49 40 11. 03 10044 8 64 55 10. 47 9541 9 81 72 10. 13 9224 10 100 91 9. 89 9010 BALMER SERIES n n^ 2 n^ 2 - 4 4n^ 2 /(n^ 2 - 4 ) 9114*n^ 2 /(n^ 2 - 4) 3 9 5 7. 20 6559 4 16 12 5. 33 4859 5 25 21 4. 76 4338 6 36 32 4. 50 4100 7 49 45 4. 36 3968
o 1 2 1 2 1
2 1
Prob. 2.
(a) Find generic equation for Lyman, Balmer, and Paschen series.
h c mq^4 mq^4 ΔE = λ
32 π^2 2 n 2
mq^4 (n 2 - n 2 ) mq^4 (n 2 - n 2 )
λ 32 2 n 2 n 2 2 n 2 n 2 h^2 o 1 2 o 1 2 8 2 n 2 n 2 h^2 h c 8 ε 2 h^3 c n 2 n 2 = o^1 2 = o^1 mq^4 (n 2 - n 2 ) mq^4 n 2 - n 2 2 1 2 1 8(8.8510-12^ F^ )^2 (6.6310^34 Js)^3 2.99810^8 m^ n 2 n 2 = m^ s^1 9.1110-31kg (1.6010-19C)^4 n 2 - n 2
= 9.1110^8 m 1 n^22 n^2 n 2 - n 2
n 2 n 2 = 9.11Å 1 2 n 2 - n 2 2 1 2 1 n 1 =1 for Lyman, 2 for Balmer, and 3 for Paschen
(b) Plot wavelength versus n for Lyman, Balmer, and Paschen series. LYMAN SERIES n n^ 2 n^ 2 - 1 n^ 2 /(n^ 2 - 1 ) 911*n^ 2 /(n^ 2 - 1 ) 2 4 3 1. 33 1215 3 9 8 1. 13 1025 4 16 15 1. 07 972 5 25 24 1. 04 949 LYMAN LIMIT 911 Ǻ
PASCHEN LIMIT 8199 Ǻ
BALMER LIMIT 3644 Ǻ
2
1 1
eV
1 1 1 1
eV
1 1 1 1
Prob. 2. 4 (a) Find Δpx for Δx=1Ǻ.
h Δp =
6.6310 J s = 5.0310-^25 kgm
(b) Find Δt for ΔE=1eV.
ΔE Δt = h Δt = h = 4.14 10 eV s = 3.3010-^16 s
4 4 ΔE 4 π 1eV
Prob. 2. 5 Find wavelength of 100eV and 12keV electrons. Comment on electron microscopes compared to visible light microscopes.
E = 1 mv^2 v =
m
6.6310 J s E
1 = E 4.9110 J m
For 100eV,
For 12keV,
The resolution on a visible microscope is dependent on the wavelength of the light which is around 5000Ǻ; so, the much smaller electron wavelengths provide much better resolution.
Prob. 2. 6 Which of the following could NOT possibly be wave functions and why****? Assume 1-D in each case. (Here i= imaginary number, C is a normalization constant)
A) Ψ (x) = C for all x.
B) Ψ (x) = C for values of x between 2 and 8 cm, and Ψ (x) = 3.5 C for values of x between 5 and 10 cm. Ψ (x) is zero everywhere else.
C) Ψ (x) = i C for x= 5 cm, and linearly goes down to zero at x= 2 and x = 10 cm from this peak value, and is zero for all other x.
If any of these are valid wavefunctions, calculate C for those case(s). What potential energy for x ≤ 2 and x ≥ 10 is consistent with this?
A) For a wavefunction (x) , we know
Ρ = *^ (x)(x)dx = 1
Ρ = *^ (x)(x)dx = c^2 dx Ρ=
0 c = 0 (x) cannot be a wave function
Ρ = *^ (x) (x)dx = 0 (xc) annot be a wave function.
C) (x)=
iC x-2 3
2 x 5
iC x-10 5
5 x 10
(^5 2 10 ) c 2 c (^2) Ρ = (x)(x)dx = x-2 dx + x-10 dx
c^2 5 c^2
10
= (x-2)^3 3× 2 +^ (x-10)^3 3×25 5
27 125 ^ 8c^2 = c^2 + = 27 3×25 3
8c^2 Ρ = 1 =1 c=0. 3
(x) can be a wave function
regions.
2
Prob. 2. A particle is described in 1D by a wavefunction: Ψ = Be-2x^ for x ≥0 and Ce+4x^ for x<0, and B and C are real constants. Calculate B and C to make Ψ a valid wavefunction. Where is the particle most likely to be?
A valid wavefunction must be continuous, and normalized. For (0) = C = B
To normalize ,
dx = 1
0 1 e8x^ + C^2 e-4x^1 8 C^2 C^2
Prob. 2. The electron wavefunction is Ceikx^ between x=2 and 22 cm, and zero everywhere else. What is the value of C? What is the probability of finding the electron between x=0 and 4 cm? = Ceikx 22 *dx = C (^2) (20) = 1 2 4
cm
20 2
2 dx =
Prob. 2. 9
Find the probability of finding an electron at x<0. Is the probability of finding an electron at x>0 zero or non-zero? Is the classical probability of finding an electron at x>6 zero or non?
The energy barrier at x=0 is infinite; so, there is zero proba bility of finding an electron at
x<0 (|ψ|^2 =0). However, it is possible for electrons to tunnel through the barrier at 5<x<6;
so, the probability of finding an electron at x>6 would be quantum mechanically greater
2 ^ A 2
2 ^ A
A e
(^2 28) ( 9. 11 10 - (^31) kg)
x z
p 2 p 2 2
x z
than zero (|ψ|^2 >0) and classical mechanically zero.
Prob. 2. 10
Find 4 p^2 2 p^2 7 mE for^ ( x ,^ y ,^ z ,^ t )^ A e j^ (10 x^3 y -4 t^ )^.
A*^ e-^ j(10x+3y-4t)
ej(10x+3y-4t)dx
(^2) - j^ x x (^) A e-^ j(10x+3y-4t)ej(10x+3y-4t)dx
A*^ e-^ j(10x+3y-4t)
ej(10x+3y-4t)dz
(^2) - j^ z z A e-^ j(10x+3y-4t)ej(10x+3y-4t)dz
A*^ e-^ j(10x+3y-4t)^
j(10x+3y-4t)dt
j t
A e-^ j(10x+3y-4t)ej(10x+3y-4t)dt
4 p 2 +2 p 2 +7 mE = 400
L L
1
Prob. 2.
Find the uncertainty in position (Δx) and momentum (Δρ).
Ψ(x,t) =
sin πx e-2πjEt/ h^ and
L
L L (^0)
x = *^ x dx =
x sin^2
x dx = 0.5L (from problem note)
L L
x^2 = *^ x dx =
x^2 sin^2
x dx = 0.28L^2 (from problem note)
Δx = x^2 - x
2 = 0.28L^2 - (0.5L)^2 = 0.17L
p ^
h = 0. h
4 π Δx L
Prob. 2.
Calculate the first three energy levels for a 10Ǻ quantum well with infinite walls.
En = n^2 π^2 2 m L^2
n^2 = 6.0310-20^ n^2
E = 6.0310-^20 J = 0.377eV E 2 = 4 0.377eV = 1.508eV E 3 = 9 0.377eV = 3.393eV
P r o b. 2. 1 3
Show schematic of atom with 1s^2 2s^2 2p^4 and atomic weight 21. Comment on its reactivity.
nucleus with 8 protons and 13 neutrons
2 electrons in 1s
2 electrons in 2s
This atom is chemically reactive because the outer 2p shell is not full. It will tend to try to add two electrons to that outer shell.
4 electrons in 2p
= proton = neturon = electron