Chemistry 110 Solutions: Solubility of Potassium Dichromate and DDT Concentration, Study notes of Chemistry

Solutions to various chemistry problems, including the determination of the solubility of potassium dichromate at different temperatures and the expression of ddt concentration as mass percent. It also covers the preparation of silver nitrate solution and the calculation of the volume of sodium acetate solution required to provide a certain mass. Additionally, it includes the calculation of the molar concentration and molality of solutions, as well as the amount of chloride in aluminum chloride solution and the volume of kbr solution needed to prepare a certain volume of a different molarity solution.

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6/22/2017 B
Solutions
Chemistry 110
1) Solubility
020 40 60 80 100
0
10
20
30
40
50
60
70
Temperature •C
g K2Cr2O7 / 100g H2O
Solubility curve for potassium dichromate
Using the above solubility curve answer the following questions:
a] What is the solubility of K2Cr2O7 at 55 oC? approximately __36_g/100 ml
b] What is the maximum number grams of K2Cr2O7 that will dissolve in 35 grams of water at 30oC? 35g
H2O X 14g K2CrO7
100g H2O = 4.9 g approximately ___4.9 g____
c] If K2Cr2O7 does not supersaturate, tell how many grams will precipitate out per 100 g of solvent when a solution
containing 30 g per 100 g of water at 60oC is cooled to 20oC (30-8)g = __22g__
d] For each of the following, indicate what kind of solution exists.......
(a) saturated, (b) unsaturated
-If the solution contains 2 g K2Cr2O7 in 10 g water at 40oC _____b_____
-If the solution contains 20 grams in 50 g water at 60oC _____a_____
-If the solution contains 90 g in 300 g water at 70 oC _____b_____
2] A 0.200 g sample of tissue from a dead bald eagle is found to contain 2.42 µg of DDT. Express this DDT
concentration as mass percent.
2.42 x 10-6g
0.200g sample (100) = 1.21 x 10-3 %
__________________________
3] How would you prepare 250.0 g of a 1.00% by mass of a silver nitrate solution?
250.0g soln X 1.00g AgNO3
100g soln = 2.50 g AgNO3
Answer: Mix ___2.50___g of silver nitrate with ___247.5__g of water
4] How many milliters of solution are required to provide 4.00 g sodium acetate from a 2.00 M sodium acetate
solution?
4.00g Na2C2H3O2 X 1mol Na2C2H3O2
82.0g Na2C2H3O2 X
1L soln
2.00mol Na2C2H3O2 X 1ml
10-3L = 24.4ml soln
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6/22/2017 B

Solutions

Chemistry 110

  1. Solubility

0 2 0 4 0 6 0 8 0 1 0 0

0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

T e m p e r a t u r e • C

g

K 2 C r 2 O 7

/

1 0 0 g

H 2 O

Solubility curve for potassium dichromate

Using the above solubility curve answer the following questions:

a] What is the solubility of K 2 Cr 2 O7 at 55 o^ C? approximately __ 36 _g/100 ml b] What is the maximum number grams of K 2 Cr 2 O7 that will dissolve in 35 grams of water at 30 o^ C? 35g

H 2 O X

14g K 2 CrO (^7) 100g H 2 O = 4.9 g^ approximately^ ___4.9 g____ c] If K 2 Cr 2 O7 does not supersaturate, tell how many grams will precipitate out per 100 g of solvent when a solution containing 30 g per 100 g of water at 60 o^ C is cooled to 20o^ C (30-8)g = 22g d] For each of the following, indicate what kind of solution exists....... (a) saturated, (b) unsaturated

-If the solution contains 2 g K 2 Cr 2 O7 in 10 g water at 40 o^ C _____b_____

-If the solution contains 20 grams in 50 g water at 60 o^ C _____a_____

-If the solution contains 90 g in 300 g water at 70 o^ C _____b_____

2] A 0.200 g sample of tissue from a dead bald eagle is found to contain 2.42 μg of DDT. Express this DDT

concentration as mass percent.

2.42 x 10-6g 0.200g sample (100)^ = 1.21 x 10

__________________________

3] How would you prepare 250.0 g of a 1.00% by mass of a silver nitrate solution?

250.0g soln X

1.00g AgNO (^3) 100g soln = 2.50 g AgNO^3

Answer: Mix ___2.50___g of silver nitrate with ___247.5__g of water 4] How many milliters of solution are required to provide 4.00 g sodium acetate from a 2.00 M sodium acetate solution?

4.00g Na 2 C 2 H 3 O 2 X

1mol Na 2 C 2 H 3 O (^2)

82.0g Na 2 C 2 H 3 O 2 X^

1L soln 2.00mol Na 2 C 2 H 3 O 2 X^

1ml 10 -3^ L

= 24.4ml soln

6/22/2017 B

__________________________

5] After 25 ml of 0.50 M sulfuric is added to 0.075 liters of water, what is the molar concentration of the resulting solution? [Assume the volumes are additive]

Vf = 25 ml + 75 ml = 100 ml

M 2 =

25ml X 0.50M 100ml = 0.13M

__________________________

6] What is the molality of a solution made by dissolving 20.0 g of sodium chloride in 225 g of water?

20.0g NaCl X

1mol NaCl 58.5g = 0.342 mol

225g H 2 O X

1Kg H 2 O 103 g H 2 O

= 0.225 Kg

m =

0.342mol NaCl 0.225Kg H 2 O = 1.52 m


7] How many grams of chloride are contained in 25 ml of a 2.37 M aluminum chloride solution?

25 ml soln X

2.37moles AlCl (^3) 1000ml X^

3mol Cl 1mol AlCl 3 X^

35.5g Cl 1mol = 6.3 g Cl


8] How many milliters of 3.5 M KBr is needed to prepare 355 ml of 0.50 M solution?

V 1 =

355ml x 0.50M 3.5M = 51 ml


9] 14 grams of methanol, CH3OH, are dissolved in 100.0 g of water a) Find the molality of the solution.

14g CH 3 OH X

1molCH 3 OH 32.0g = 0.44 mol CH^3 OH

100.0g H 2 O X 1Kg 103 g = 0.1000 Kg H 2 O

m =

0.44mol CH 3 OH 0.1000Kg H 2 O = 4.4 m


b) Find the percent alcohol by mass in this solution.

g soln = 14g CH 3 OH + 100g H 2 O = 114 g soln

% mass =

14g CH 3 OH 114g soln (100)^ = 12.3 %