Solutions for Exam One - Principles of Chemistry I | CH 301, Exams of Chemistry

Material Type: Exam; Professor: Labrake; Class: PRINCIPLES OF CHEMISTRY I; Subject: Chemistry; University: University of Texas - Austin; Term: Fall 2017;

Typology: Exams

2016/2017

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LaBrake CH301 Exam 1 Fall 2017
50090
R= 0.08206 L atm/mol K
R= 62.36 L torr/mol K
R= 0.08314 L bar/mol K
R= 8.314 J/mol K
NA= 6.022 ×1023 mol1
1 atm = 1.01325 ×105Pa
1 atm = 760 torr
1 atm = 14.7 psi
1 bar = 105Pa
1 in = 2.54 cm
1 lb = 453.6 g
1 gal = 3.785 L
ρwater = 1.00 g/mL
ρmercury = 13.6 g/mL
NOTE: Please keep your Exam copy intact (all pages still stapled). You must turn in your exam
copy plus your bubble sheet, and scratch paper.
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LaBrake CH301 Exam 1 Fall 2017

50090

R = 0.08206 L atm/mol K

R = 62.36 L torr/mol K

R = 0.08314 L bar/mol K

R = 8.314 J/mol K

NA = 6. 022 × 1023 mol−^1

1 atm = 1.01325 × 105 Pa

1 atm = 760 torr

1 atm = 14.7 psi

1 bar = 10^5 Pa

1 in = 2.54 cm

1 lb = 453.6 g

1 gal = 3.785 L

ρwater = 1.00 g/mL

ρmercury = 13.6 g/mL

NOTE: Please keep your Exam copy intact (all pages still stapled). You must turn in your exam

copy plus your bubble sheet, and scratch paper.

This print-out should have 10 questions. Multiple-choice questions may continue on the next column or page – find all choices before answering.

001 10.0 points You fill a balloon with 2.25 L of air at 33◦C and 1.00 atm pressure. You then take this balloon to a higher altitude where the tem- perature is 20◦C and the pressure is 0. atm. What is the new volume of the balloon?

  1. 2.34 L correct
  2. 2.55 L
  3. 2.16 L
  4. 1.98 L

Explanation: Using the combined gas law:

P 1 V 1 T 1 =^

P 2 V 2 T 2

T 1 = 33 + 273 = 306 K

T 2 = 20 + 273 = 293 K

(1.00 atm)(2.25 L) 306 K =^

(0.920 atm)(V 2 ) 293 K

V 2 = 2.34 L

002 10.0 points You have a sample of Ne gas at a certain temperature, pressure, and volume. If you double the volume and decrease the absolute temperature (in Kelvin) by half, how will the pressure change?

  1. The new pressure will be double the orig- inal pressure.
  2. The new pressure will be one fourth the original pressure. correct
  3. The new pressure will be the same as the original pressure.
  4. The new pressure will be half the original pressure.
  5. The new pressure will be four times the original pressure. Explanation: Doubling the volume of a sample of gas will halve the pressure. Halving the absolute tem- perature of a gas will also halve the pressure. Doing both will make the pressure one fourth the original pressure.

003 10.0 points A sample of methane gas (CH 4 ) occupies a volume of 11.5 L at 1 atm and 273 K. What is the mass of the gas?

  1. 7.56 g
  2. 0.513 g
  3. 8.23 g correct
  4. 16.0 g Explanation: The sample of gas is at STP. 1 mole of a gas at STP occupies 22.4 L. x mol 11 .5 L =^

1 mol 22 .4 L x = 0.513 mol CH 4 0 .513 mol CH 4 × (^16) 1 mol CH.04 g CH 44 = 8.23 g CH 4

004 10.0 points Consider the following UNBALANCED reac- tion:

?Al 2 S 3 + ?NH 4 NO 3 → ?Al(NO 3 ) 3 + ?(NH 4 ) 2 S What is the sum of the coefficients in the balanced reaction?

  1. 15
  2. 12 correct
  3. 4
  4. 8
  5. 11 Explanation:

009 10.0 points How many grams of NO can be produced from the following reaction if 60.2 grams of NO 2 is consumed?

3NO 2 (g) + H 2 O(l) → 2HNO 3 (aq) + NO(g)

  1. 0.131 g
  2. 13.1 g correct
  3. 118 g
  4. 277 g

Explanation:

60 .2g NO 2 ×

1 mol NO 2 46 .01g NO 2

×

1 mol NO 3 mol NO 2

×

30 .01g NO 1 mol NO

= 13.1g NO

010 10.0 points Express 642 kg in terms of grams.

  1. 0.642 g
    1. 42 × 108 g
    1. 42 × 105 g correct
  2. 642 g
    1. 42 × 1011 g

Explanation:

642 kg ×

1 g 0 .001 kg

= 6. 42 × 105 g