Stoichiometry Word Problems 2 SOLUTIONS, Summaries of Stoichiometry

Stoichiometry Word Problems 2 SOLUTIONS. 1. Cellular respiration occurs in animal cells, a reaction that is essentially the combustion of a sugar.

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Student Name: _______________________________________________ Pd. ____ Date: __________
Stoichiometry Word Problems 2 SOLUTIONS
1. Cellular respiration occurs in animal cells, a reaction that is essentially the combustion of a sugar
called glucose, C
6
H
12
O
6
. If the average human uses 550 liters of oxygen when breathing, how many
grams of glucose are used by this process?
Balanced Equation: C
6
H
12
O
6
+ 6 O
2
6 CO
2
+ 6 H
2
O
6126
2
6126
6126
2
6126
2
22
61.736
1
180
6
1
4.22
1
1
550 OHCg
OHCmol
OHCg
Omol
OHCmol
OL
OmolOL =
2. Nitroglycerin, C
3
H
5
(ONO
2
)
3
, was invented in 1846 by an Italian chemist named Ascanio Sobrero.
Nitroglycerine contains both an oxidant and a fuel. When it detonates, it decomposes to form carbon
dioxide, water, nitrogen, and oxygen, all in a gaseous state. Every mole of the explosive that
decomposes in this way generates a tremendous amount of energy – approximately 1.5 MJ (1 MJ = 1
megajoule = 1 x 10
6
J = 1 MJ).
a. If 1.135 kilograms of nitroglycerin detonates, how many total liters of gas (assuming
STP) are produced?
Balanced Equations: 4 C
3
H
5
(ONO
2
)
3
10 H
2
O + 12 CO
2
+ 6 N
2
+ O
2
3253
)(ONOHC812
1
4.22
4
29
227
1
1
1000
1
135.1 L
gasmol
gasL
nitromol
gasmol
nitrog
nitromol
nitrokg
nitrognitrokg =
b. How much energy is produced by the explosion?
MJ
nitromol
energyMJ
nitrog
nitromol
nitrokg
nitrognitrokg 5.7
1
1
227
1
1
1000
1
135.1 =
3. Sodium hydroxide is a strong, inexpensive base used commonly in many industrial chemical
processes. It is manufactured by creating a strong aqueous brine (NaCl) solution and applying an
intense electrical current. The sodium ions react with the water to generate sodium hydroxide,
hydrogen gas, and chlorine gas. If 2345 g of salt is mixed with 4562 g of water:
a. Which reactant is limiting?
Balanced Equation: 2 NaCl + 2 H
2
O 2 NaOH + H
2
+ Cl
2
OHg
OHmol
OHg
NaClmol
OHmol
NaClg
NaClmolNaClg
2
2
22
54.721
1
18
2
2
5.58
1
1
2345 =
Since the amount of H
2
O required is less than the amount provided (4562 g), it is in
excess, so NaCl is the limiting reagent.
pf3

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Student Name: _______________________________________________ Pd. ____ Date: __________

Stoichiometry Word Problems 2 SOLUTIONS

  1. Cellular respiration occurs in animal cells, a reaction that is essentially the combustion of a sugar called glucose, C 6 H 12 O 6. If the average human uses 550 liters of oxygen when breathing, how many grams of glucose are used by this process?

Balanced Equation: C 6 H 12 O 6 + 6 O 2  6 CO 2 + 6 H 2 O

6 12 6 (^61262)

6 12 6 2

6 12 6 2

gCH O molCH O

gCH O molO

molCH O LO

L O molO = 

  1. Nitroglycerin, C 3 H 5 (ONO 2 ) 3 , was invented in 1846 by an Italian chemist named Ascanio Sobrero. Nitroglycerine contains both an oxidant and a fuel. When it detonates, it decomposes to form carbon dioxide, water, nitrogen, and oxygen, all in a gaseous state. Every mole of the explosive that decomposes in this way generates a tremendous amount of energy – approximately 1.5 MJ (1 MJ = 1 megajoule = 1 x 10^6 J = 1 MJ). a. If 1.135 kilograms of nitroglycerin detonates, how many total liters of gas (assuming STP) are produced?

Balanced Equations: 4 C 3 H 5 (ONO 2 ) 3  10 H 2 O + 12 CO 2 + 6 N 2 + O 2

1 812 C^3 H^5 (ONO^2 )^3

L

molgas

Lgas molnitro

molgas gnitro

molnitro kgnitro

kg nitro gnitro = 

b. How much energy is produced by the explosion?

MJ

molnitro

MJenergy gnitro

molnitro kgnitro

kg nitro gnitro

  1. 5 1
  1. Sodium hydroxide is a strong, inexpensive base used commonly in many industrial chemical processes. It is manufactured by creating a strong aqueous brine (NaCl) solution and applying an intense electrical current. The sodium ions react with the water to generate sodium hydroxide, hydrogen gas, and chlorine gas. If 2345 g of salt is mixed with 4562 g of water: a. Which reactant is limiting?

Balanced Equation: 2 NaCl + 2 H 2 O  2 NaOH + H 2 + Cl 2

gH O molHO

gHO molNaCl

molHO gNaCl

g NaCl molNaCl 2 2

Since the amount of H 2 O required is less than the amount provided (4562 g), it is in excess, so NaCl is the limiting reagent.

b. How much base is produced?

Use the limiting reactant (NaCl):

g NaOH molNaOH

gNaOH molNaCl

molNaOH gNaCl

g NaCl molNaCl

  1. 42 1

c. How much of the excess reactant is left over?

From part (a), 721.54 g of water were consumed. Subtract this from the given (4562 – 721.54 = 3840 g H 2 O are left over.

  1. Prior to World War II, ammonia was produced by a process called dry distillation, by which ammonium chloride and quicklime (calcium oxide) react to form calcium chloride, calcium hydroxide, and ammonia. The reaction looks like this:

2 NH 4 Cl + 2 CaO  CaCl 2 + Ca(OH) 2 + 2 NH 3

If 75.6 g of ammonium chloride is allowed to react with 52.8 g of quicklime: a. How many grams of the excess reactant are left over?

g CaO molCaO

gCaO molNHCl

molCaO gNHCl

g NHCl molNHCl

  1. 50 1

4 4

Since more quicklime is needed than is provided, quicklime is the limiting reactant. Therefore:

gNH Cl molNHCl

gNHCl molCaO

molNHCl gCaO

g CaO molCaO 4 4

75.6 – 40.4 = 35.2 grams of NH 4 Cl are left over.

b. How many grams of ammonia are formed?

Use the limiting reactant:

3 3

gNH molNH

gNHCl molCaO

molNH gCaO

g CaO molCaO = 