Structure - Civil Engineering - Lecture Slides, Slides of Civil Engineering

The main points in these lecture slides are:Structure, Aggregate Particles, Hydrated Cement Paste, Transition Zone, Aggregates, Shape, Distribution, Structure, Macrostructure, Structure

Typology: Slides

2012/2013

Uploaded on 05/07/2013

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The Structure of Concrete
Three phases present in concrete:
(1) Aggregate particles
(2) Hydrated cement paste (hcp)
(3) Transition zone, which is the interfacial region between the
aggregates and the hcp.
The amount, size, shape and distribution of these three
phases constitute the structure of concrete.
Macrostructure - the structure visible to the human
eyes.
Microstructure - the microscopically magnified portion
of a macrostructure.
The structure of concrete is highly heterogeneous and
dynamic (i.e. changes with time).
Structure of the Aggregate Phase
Aggregates in concrete are usually chemically stable.
Thus, the properties of concrete are influenced
primarily by the physical rather than the chemical
properties of the aggregate.
The aggregate phase is predominantly responsible for
the unit weight, elastic modulus and thermal properties
of the concrete.
Effects of the shape and texture of the coarse
aggregate:
More angular and rougher texture gives better bonding with
the cement paste, but lower consistency in the fresh concrete.
The aggregate phase is usually stronger than the other
two phases of concrete, and does not affect the strength
of the concrete, except in the case of weak aggregates.
Effects of flat and elongated aggregate -
tendency to trap bleed water.
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The Structure of Concrete

  • Three phases present in concrete:

(1) Aggregate particles (2) Hydrated cement paste (hcp) (3) Transition zone, which is the interfacial region between the aggregates and the hcp.

  • The amount, size, shape and distribution of these three

phases constitute the structure of concrete.

  • Macrostructure - the structure visible to the human

eyes.

  • Microstructure - the microscopically magnified portion

of a macrostructure.

  • The structure of concrete is highly heterogeneous and

dynamic (i.e. changes with time).

Structure of the Aggregate Phase

  • Aggregates in concrete are usually chemically stable.

Thus, the properties of concrete are influenced

primarily by the physical rather than the chemical

properties of the aggregate.

  • The aggregate phase is predominantly responsible for

the unit weight, elastic modulus and thermal properties

of the concrete.

  • Effects of the shape and texture of the coarse

aggregate:

  • More angular and rougher texture gives better bonding with the cement paste, but lower consistency in the fresh concrete.
  • The aggregate phase is usually stronger than the other

two phases of concrete, and does not affect the strength

of the concrete, except in the case of weak aggregates.

Effects of flat and elongated aggregate -

tendency to trap bleed water.

Structure of Hydrated Cement Paste

  • Anhydrous Portland cement - angular particles in the

size range 1 to 50 μm.

  • Calcium silicate hydrate (C 3 S 2 H 3 or C-S-H)
    • Recall the chemical reactions:

2C 3 S + 6H ⇒ C 3 S 2 H 3 + 3CH

2C 2 S + 4H ⇒ C 3 S 2 H 3 + CH

  • C-S-H makes up 50 to 60% of the solids in a completely hydrated cement paste.
  • C-S-H appear as very small fibrous crystals which fill the space formerly occupied by water and the dissolved cement particles.
  • Calcium hydroxide
  • Constitutes 20 to 25% of the volume of solids in the hydrated paste.
  • Large prismatic crystals.
  • Little contribution to strength of concrete.
  • Chemically unstable. High solubility in acidic solution.
  • Ettringite
  • Recall : C 3 A + 3C Ŝ H 2 + 26H ⇒ C 3 A·3C Ŝ ·H 32 (Ettringite) (Formed at the beginning of hydration process) C 3 A·C Ŝ ·H (^) 12-18 + 2CH + 2 Ŝ + (10-16)H ⇒ C 3 A·3C Ŝ ·H (^32) (Formed as a result of sulfate attack on monosulfate hydrate)
  • Needle-shaped prismatic crystals.
  • Monosulfate hydrate
  • Recall:

C 3 A + C Ŝ H 2 + (10-16)H ⇒ C 3 A·C Ŝ ·H12-18 (Monosulfate) (From hydration of C 3 A)

C 3 A·3C Ŝ ·H 32 + 2C 3 A + (4-22)H ⇒ 3 ( C 3 A·C Ŝ ·H12-18 )

(From ettringite at the early stage of hydration.)

  • Hexagonal plate crystals.
  • Susceptible to sulfate attack.
  • Unhydrated clinker grain
  • Some unhydrated clinker grains may be found in the microstructure of hydrated cement pastes.
  • Interlayer space in C-S-H
  • This void size is small and does not have any adverse effect on the strength and permeability of the hydrated cement paste.

Calculations in Case A

Assume volume of cement = 100 cm^3 w/c = 0.

⇒ mass of cement = 100 x 3.15 =315 g

mass of water = 315 X 0.63 g = 200 g (round off)

volume of water = 200 cm^3

total volume of paste = 100 + 200 = 300 cm^3

At 0% hydration

Volume of solid = volume of cement = 100 cm^3

Solid-to-space ratio = 100/300 = .33 or 33%

At 50% hydration

50% of the cement (with a volume of 50 cm^3 ) hydrates to form a hydration product with a volume of 100 cm^3.

Total volume of solid = vol. of hydration product

  • vol. of unhydrated cement

= 100 + 50 = 150 cm^3

Solid-to-space ratio = 150/300 = .50 or 50%

At 75% Hydration

75% of the cement (with a volume of 75 cm^3 ) hydrates to form a hydration product with a volume of 150 cm^3.

Total volume of solid = 150 + 25 cm^3 = 175 cm^3

Solid-to-space ratio = 175/300 = .58 or 58%

At 100% Hydration

Total volume of solid = vol. Of hydration product

= 200 cm^3

Solid-to-space ratio = 200/300 = .67 or 67%

Calculations in Case B

Assume volume of Cement = 100 cm^3 mass of cement = 315 g

At w/c of 0.

mass of water = 315 X 0.4 = 126 g

volume of water = 126 cm^3

Total volume of paste = 100 + 126 = 226 cm^3

Volume of hydration production at 100% hydration = 200 cm^3

Solid-to-space ratio = 200/226 = .885 or 88.5%

  • Influence of the Transition Zone on Properties

of Concrete

  • The transition zone is the weakest phase, and thus is

the strength-limiting phase in concrete.

  • The transition zone explains why concrete fails at a

considerably lower stress level than the strength of

either the aggregate or the hardened cement paste.

  • It takes considerably more energy to propagate

cracks under compression than in tension. This

explains why concrete fails in a brittle manner in

tension, but is relatively tougher in compression.

This also explains why the tensile strength is much

lower than the compressive strength.

  • The microcracks present in the transition zone explains

why the aggregate and hcp remain elastic until fracture in

a uniaxial compression test, whereas concrete shows

inelastic behavior.

  • Influence of the Transition Zone on Properties of

Concrete (Continued)

  • The structure of the transition zone (with its high volume of voids and microcracks) explains why the stiffness of the concrete is less than either that of the aggregate or the hcp.
  • The existence of microcracks in the transition zone explains why the permeability of the concrete is higher than the permeability of the hcp, or the aggregate.
  • The w/c ratio in the transition zone affects the strength of the concrete. In general, the larger the aggregate, the higher will be the local w/c ratio in the transition zone and, consequently, the weaker and more permeable will be the concrete.