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This study guide provides an overview of valence electrons, ionic bonds, and metallic bonding. It covers the concept of valence electrons, their role in forming ions, and the octet rule. The guide also explains the formation of ionic compounds and metallic bonds, and includes exercises for practice.
Typology: Summaries
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Study Guide 213
To find the number of valence electrons in an atom of a representative element, simply look at its group number. A positively charged ion, or a cation, is produced when an atom loses one or more valence electrons. An anion is produced when an atom gains one or more valence electrons.
r valence electron (194) r electron dot structure (195) r octet rule (195) r halide ion (199)
r Although they are composed of ions, ionic compounds are electrically neutral. Most ionic compounds are crystalline solids at room temperature. Ionic compounds generally have high melting points. Ionic compounds can conduct an electric current when melted or dissolved in water.
r ionic compound(201) r ionic bond(201) r chemical formula(202) r formula unit(202) r coordination number(205)
The valence electrons of atoms in a pure metal can be modeled as a sea of electrons. Alloys are important because their properties are often superior to those of their component elements.
r metallic bond(209) r alloy(211)
7.1 Ions
r7.2 Ionic Bonds and Ionic Compounds
7.3 Bonding in Metals
BONDING AND INTERACTIONS Atoms form positive ions (cations) by losing valence electrons and form negative ions (anions) by gaining valence electrons. The electrostatic forces between the oppositely charged ions hold the cations and anions together in an ionic compound. Ionic compounds generally have high melting points and can conduct an electric current in solution and in the molten state. Metals are made up of closely packed cations surrounded by a sea of electrons. The sea-of-electrons model explains why metals are good conductors of electric current and why they are ductile and malleable.
7 Study Guide
Study Guide 213
Review and Assessment Materials
PRO BLEMS
ONLINE R R O L E M M^ S
O^ E PROBLEM SETS^ Have students practice more formula writing problems by using the Chapter 7 Online Problem Set.
LAB
VIRTUAL VIRTUAL LABS^ Have students complete a virtual lab as an in-class or take-home assignment to help reinforce the concept of ionic bonding.
Study Tip Write and answer questions about the content of the chapter. For Chapter 7, you might ask the following questions, which require students to summarize the information contained in the chapter.
Performance Tasks
MODELING IONIC CRYSTALS Have students choose three ionic compounds and do research to find out their crystal structures. Then have students use modeling clay and toothpicks to make three-dimensional models of each crystal structure.
QUENCHING—NOT JUST FOR THIRST Alloys and metals are often quenched in water after being heated and shaped. Have students research and report on the effects of quenching on the crystalline structure of metals and alloys. Also, ask them to compare the resulting crystals to ionic crystals. Reports should include any necessary graphics and explain any changes in metal properties that occur as a result of the quenching process.
214 $IBQUFSt"TTFTTNFOU
BLEM
S
ONLINE R O B L E M M^ S
O^ E
Lesson by Lesson
7.1 Ions
36.State the number of electrons either lost or gained in forming each ion. a. BrŹ^ e. Ca 2 à b. Naà^ f. Cuà c. As^3 Ź^ g. HŹ d. Ba^2 à^ h. Cu 2 à
214 Chapter 7 • Assessment
Answers LESSON 7.
Focus on ELL
5 ASSESS UNDERSTANDING Engage students in discussing the chapter’s key concepts and vocabulary. Encourage them to identify learning strategies they felt were most helpful and those they felt were difficult.
BEGINNING: LOW/HIGH Provide students with a two-column chart which has randomly ordered vocabulary words in one column and definitions in the other. Have students match each word with its definition.
INTERMEDIATE: LOW/HIGH Provide students with a list of one key question from each lesson. Have them write a short answer to each.
ADVANCED: LOW/HIGH Have students write a summary statement for each lesson describing what they have learned.
216 $IBQUFSt"TTFTTNFOU
74.The properties of all samples of brass are not identical. Explain.
Think Critically
Hexagonal close-packed
Face-centered cubic
Body-centered cubic
216 Chapter 7 • Assessment
Answers
UNDERSTAND CONCEPTS
THINK CRITICALLY
Ionic and Metallic Bonding 217
Enrichment
Write About Science
Sodium chloride (NaCl)
Clź Naá
Clź Csá
Cesium chloride (CsCl)
The statue of Ludwig van Beethoven in Central Park is made of bronze. Bronze is an alloy containing cop- per and tin. When bronze is exposed to the elements, it reacts with water (H 2 O), carbon dioxide (CO 2 ), and oxygen (O 2 ) in the air to produce a film of copper(II) carbonate (CuCO 3 ). Copper(II) carbonate is an ionic compound that is blue-green in color. A film of copper(II) car- bonate on the Beethoven statue gives the statue its green color. The film also protects the metal against further corrosion.
Ionic and Metallic Bonding 217
CHEMYSTERY
APPLY CONCEPTS After students have read through the CHEMystery, discuss the principles of ionic and metallic bonding that make the development of the green patina possible. Ask What type of bonding occurs? (The product is an ionic compound composed of copper from the statue and water and carbon dioxide from the air.) Ask How is the film able to protect the metal against further corrosion? (Because the film has a different composition, it doesn’t react with air in the same way that the metal does.)
CHEMYSTERY ANSWERS
92. The configuration is [Ar]3 d^9. 93. Sample answer: Bronze is an attractive metal alloy before and after it forms a patina. 94. The metallically-bonded alloy is able to react with elements in its environment to form an ionic compound, which is less reactive.
Answers
WRITE ABOUT SCIENCE
However, if a silver atom loses its 5 s^1 electron, the result is an outer electron configuration of eighteen electrons, written as 4 s^2 4 p^64 d^10. This configuration is favored and stable. It is known as a pseudo-noble-gas configuration.