Valence Electrons, Ionic Bonds, and Metallic Bonding: A Study Guide, Summaries of Chemistry

This study guide provides an overview of valence electrons, ionic bonds, and metallic bonding. It covers the concept of valence electrons, their role in forming ions, and the octet rule. The guide also explains the formation of ionic compounds and metallic bonds, and includes exercises for practice.

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Study Guide 213
To find the number of valence electrons in an
atom of a representative element, simply look at its
group number.
A positively charged ion, or a cation, is produced
when an atom loses one or more valence electrons.
An anion is produced when an atom gains one or
more valence electrons.
valence electron r(194)
electron dot structure
r(195)
octet rule
r(195)
halide ion
r(199)
r
Although they are composed of ions, ionic
compounds are electrically neutra l.
Most ionic compounds are crystalline sol ids at
room temperature.
Ionic compounds generally have high melting
points.
Ionic compounds can conduct an electric current
when melted or dissolved in water.
ionic compound r(201)
ionic bond
r(201)
chemical formula
r(202)
formula unit
r(202)
coordination number
r(205)
The valence electrons of atoms in a pure metal can
be modeled as a sea of electrons.
Alloys are important bec ause their properties are
often superior to those of their component elements.
metallic bond r(209)
alloy
r(211)
Ions7.1
r
Ionic Bonds and Ionic Compounds7. 2
Bonding in Metals7. 3
BIGIDEA
BONDING AND INTERACTIONS
Atoms form positive ions (cations) by losing
valence electrons and form negative ions (anions)
by gaining valence electrons. The elec trostatic
forces between the oppositely charged ions hold the
cations and anions together in an ionic compound.
Ionic compounds generally have high melting
points and can conduct an electric c urrent in
solution and in the molten state. Metals are made
up of closely packed cations surrounded by a sea of
electrons. The sea-of-electrons model explains why
metals are good conductors of electric current and
why they are ductile and malleable.
7 Study Guide
Study Guide 213
STUDY GUIDE
Evaluate
Review and Assessment Materials
P
R
O
B
L
E
M
S
O
N
L
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N
E
R
O
R
L
E
M
S
O
E
PROBLEM SETS Have students practice
more formula writing problems by using
the Chapter 7 Online Problem Set.
L
A
B
V
I
R
T
U
A
L
VIRTUAL LABS Have students complete
a virtual lab as an in-class or take-home
assignment to help reinforce the concept
of ionic bonding.
Study Tip
Write and answer questions about the content of the
chapter. For Chapter 7, you might ask the following
questions, which require students to summarize the
information contained in the chapter.
What information does the electron dot structure
of an element provide? (the number of valence
electrons)
In most cases, what is the stable electron
configuration of an elemental ion? (In most
cases, a stable configuration is characterized by
an octet of valence electrons; the configuration is
isoelectronic with that of a noble gas.)
Why does NaCl dissolved in water conduct
electricity? (In water, the ionic compound breaks
apart into Na+ and Cl ions that are free to move
in the solution.)
What is the theory of bonding in pure metals?
(metal cations held together by a pool of mobile
valence electrons)
Performance Tasks
MODELING IONIC CRYSTALS Have students choose three ionic compounds and do
research to find out their crystal structures. Then have students use modeling clay
and toothpicks to make three-dimensional models of each crystal structure.
QUENCHING—NOT JUST FOR THIRST Alloys and metals are often quenched in water
after being heated and shaped. Have students research and report on the effects
of quenching on the crystalline structure of metals and alloys. Also, ask them to
compare the resulting crystals to ionic crystals. Reports should include any necessary
graphics and explain any changes in metal properties that occur as a result of the
quenching process.
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Study Guide 213

To find the number of valence electrons in an atom of a representative element, simply look at its group number. A positively charged ion, or a cation, is produced when an atom loses one or more valence electrons. An anion is produced when an atom gains one or more valence electrons.

r valence electron (194) r electron dot structure (195) r octet rule (195) r halide ion (199)

r Although they are composed of ions, ionic compounds are electrically neutral. Most ionic compounds are crystalline solids at room temperature. Ionic compounds generally have high melting points. Ionic compounds can conduct an electric current when melted or dissolved in water.

r ionic compound(201) r ionic bond(201) r chemical formula(202) r formula unit(202) r coordination number(205)

The valence electrons of atoms in a pure metal can be modeled as a sea of electrons. Alloys are important because their properties are often superior to those of their component elements.

r metallic bond(209) r alloy(211)

7.1 Ions

r7.2 Ionic Bonds and Ionic Compounds

7.3 Bonding in Metals

BIG IDEA

BONDING AND INTERACTIONS Atoms form positive ions (cations) by losing valence electrons and form negative ions (anions) by gaining valence electrons. The electrostatic forces between the oppositely charged ions hold the cations and anions together in an ionic compound. Ionic compounds generally have high melting points and can conduct an electric current in solution and in the molten state. Metals are made up of closely packed cations surrounded by a sea of electrons. The sea-of-electrons model explains why metals are good conductors of electric current and why they are ductile and malleable.

7 Study Guide

Study Guide 213

STUDY GUIDE

Evaluate

Review and Assessment Materials

PRO BLEMS

ONLINE R R O L E M M^ S

O^ E PROBLEM SETS^ Have students practice more formula writing problems by using the Chapter 7 Online Problem Set.

LAB

VIRTUAL VIRTUAL LABS^ Have students complete a virtual lab as an in-class or take-home assignment to help reinforce the concept of ionic bonding.

Study Tip Write and answer questions about the content of the chapter. For Chapter 7, you might ask the following questions, which require students to summarize the information contained in the chapter.

  • What information does the electron dot structure of an element provide? (the number of valence electrons)
  • In most cases, what is the stable electron configuration of an elemental ion? (In most cases, a stable configuration is characterized by an octet of valence electrons; the configuration is isoelectronic with that of a noble gas.)
  • Why does NaCl dissolved in water conduct electricity? (In water, the ionic compound breaks apart into Na +^ and Cl −^ ions that are free to move in the solution.)
  • What is the theory of bonding in pure metals? (metal cations held together by a pool of mobile valence electrons)

Performance Tasks

MODELING IONIC CRYSTALS Have students choose three ionic compounds and do research to find out their crystal structures. Then have students use modeling clay and toothpicks to make three-dimensional models of each crystal structure.

QUENCHING—NOT JUST FOR THIRST Alloys and metals are often quenched in water after being heated and shaped. Have students research and report on the effects of quenching on the crystalline structure of metals and alloys. Also, ask them to compare the resulting crystals to ionic crystals. Reports should include any necessary graphics and explain any changes in metal properties that occur as a result of the quenching process.

214 $IBQUFSt"TTFTTNFOU

PRO 7 Assessment * 4PMVUJPOTBQQFBSJO"QQFOEJY&

BLEM

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ONLINE R O B L E M M^ S

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Lesson by Lesson

7.1 Ions

  1. What is a valence electron?
  2. To which group in the periodic table does each of the following elements belong? How many valence electrons do atoms of each element have? a. nitrogen d. barium b. lithium e. bromine c. phosphorus f. carbon 29.Write electron dot structures for each of the fol- lowing elements: a. Cl c. Al b. S d. Li 30.Describe two ways that an ion forms from an atom.
  3. How many electrons must an atom of each element lose to attain a noble-gas electron configuration? a. Ca c. Li b. Al d. Ba 32.Write the symbol for the ion formed when each of the following elements loses its valence electrons. a. aluminum d. potassium b. lithium e. calcium c. barium f. strontium 33.Why do nonmetal atoms tend to form anions when they react to form compounds?
  4. How many electrons must be gained by each of the following atoms to achieve a stable electron configuration? a. N c. Cl b. S d. P
  5. What is the formula of the ions formed when atoms of the following elements gain or lose valence electrons and attain noble-gas configurations? a. sulfur c. fluorine b. sodium d. phosphorus

36.State the number of electrons either lost or gained in forming each ion. a. BrŹ^ e. Ca 2 à b. Naà^ f. Cuà c. As^3 Ź^ g. HŹ d. Ba^2 à^ h. Cu 2 à

  1. Name each ion in Problem 36. Identify each as an anion or a cation. 7.2 Ionic Bonds and Ionic Compounds
  2. Define an ionic bond.
  3. Explain why ionic compounds are electrically neutral.
  4. Which of the following pairs of atoms would you expect to combine chemically to form an ionic compound? a. Li and S d. F and Cl b. O and S e. I and K c. Al and O f. H and N 41.Which of the following pairs of elements will not form ionic compounds? a.sulfur and oxygen b. sodium and calcium c. sodium and sulfur d. oxygen and chlorine
  5. How can you represent the composition of an ionic compound?
  6. Identify the kinds of ions that form each ionic compound. a. calcium fluoride, CaF 2 b. aluminum bromide, AlBr 3 c. lithium oxide, Li 2 O d. aluminum sulfide, Al 2 S 3 e. potassium nitride, K 3 N 44.Write the formulas for the ions in the following compounds: a. KCl c. MgBr 2 b. BaS d. Li 2 O 45.Most ionic substances are brittle. Why?
  7. Explain why molten MgCl 2 does conduct an electric current although crystalline MgCl (^2) does not.

214 Chapter 7 • Assessment

ASSESSMENT

Answers LESSON 7.

  1. an electron in the highest occupied energy level
  2. a. Group 5A; 5 valence electrons b. Group 1A; 1 valence electron c. Group 5A; 5 valence electrons d. Group 2A; 2 valence electrons e. Group 7A; 7 valence electrons f. Group 4A; 4 valence electrons
  3. a. Cl b. S (^) c. Al d. Li
  4. by gaining or losing electrons
  5. a. 2 b. 3 c. 1 d. 2
  6. a. Al3+^ b. Li +^ c. Ba2+^ d. K+ e. Ca2+^ c. Sr2+
  7. Most nonmetals gain 1, 2, or 3 electrons to achieve a noble-gas electron configuration.
  8. a. 3 b. 2 c. 1 d. 3
  9. a. S2–^ b. Na +^ c. F–^ d. P 3–
  10. a. gain of 1 electron b. loss of 1 electron c. gain of 3 electrons d. loss of 2 electrons e. loss of 2 electrons f. loss of 1 electron g. gain of 1 electron h. loss of 2 electrons
  11. a. bromide anion b. sodium cation c. arsenide anion d. barium cation e. calcium cation f. copper(I) cation g. hydride anion h. copper(II) cation LESSON 7.
  12. the electrostatic force that holds ions together in ionic compounds
  13. The positive charges balance the negative charges.
  14. a, c, e
  15. a, b, d
  16. with the formula that reflects the ratio of ions in the compound
  17. a. Ca2+, F–^ b. Al3+, Br –^ c. Li+, O2– d. Al3+, S2–^ e. K+, N 3–
  18. a. K+, Cl–^ b. Ba2+, S2– c. Mg2+, Br –^ d. Li+, O2–
  19. Their network of electrostatic attractions and repulsions forms a rigid structure.
  20. Ions are free to move in molten MgCl 2.

Focus on ELL

5 ASSESS UNDERSTANDING Engage students in discussing the chapter’s key concepts and vocabulary. Encourage them to identify learning strategies they felt were most helpful and those they felt were difficult.

BEGINNING: LOW/HIGH Provide students with a two-column chart which has randomly ordered vocabulary words in one column and definitions in the other. Have students match each word with its definition.

INTERMEDIATE: LOW/HIGH Provide students with a list of one key question from each lesson. Have them write a short answer to each.

ADVANCED: LOW/HIGH Have students write a summary statement for each lesson describing what they have learned.

216 $IBQUFSt"TTFTTNFOU

  1. Write the formulas for each ionic compound that can be made by combining each of pair of ions. a. Ba^2 à^ and BrŹ b. Al^3 à^ and S^2 Ź c. Kà^ and N^3 Ź
  2. The atoms of the noble gas elements are stable. Explain. 70.What is the simplest formula for the com- pounds that can form when each of these ions combine with an oxide (O^2 Ź) ion? a. Fe^3 à^ c. Lià b. Pb^4 à^ d. Mg 2 à
  3. Can you predict the coordination number of an ion from the formula of an ionic compound? Explain.
  4. Metallic cobalt crystallizes in a hexagonal close-packed structure. How many neighbors will a cobalt atom have? 73.Explain how hexagonal close-packed, face- centered cubic, and body-centered cubic unit cells are different from one another.

74.The properties of all samples of brass are not identical. Explain.

  1. For each alloy below, list the elements it contains. a. brass c. bronze b. sterling silver d. stainless steel

Think Critically

  1. Make Generalizations What is the relation- ship between the number of electrons in the valence shells in an electron configuration diagram for an atom and the number of dots in the corresponding electron dot structure?
  2. Relate Cause and EffectWhy are many elements more stable as ions than they are as atoms?
    1. Make GeneralizationsIs it accurate to describe sodium chloride (NaCl) as consisting of individual particles, each made up of one Naà^ cation and one ClŹ^ anion? Explain your answer.
    2. Infer For each ionic formula, identify the A-group number to which element X belongs. a. CaX d. Al 2 X (^3) b. MgX 2 e. XF c. X 3 N f. XS
    3. CompareHow do the motions of sodium ions and chloride ions in molten sodium chloride differ from the motions of these ions in sodium chloride crystals?
  3. Relate Cause and EffectTwo physical prop- erties of metals are ductility and malleability. Explain these properties based on what you know about the valence electrons of metal atoms.
    1. Interpret DiagramsHow atoms and ions are arranged in crystals is not just dependent on size. The spheres in each atomic window below are identical in size. The windows have exactly the same area. In which window are the spheres more closely packed? Explain your reasoning. a. b.
    2. Compare and Contrast Describe the similari- ties and differences between ionic compounds and metals in terms of their physical and chemical characteristics.
    3. Relate Cause and EffectHow does the octet rule explain the large increase in energy between the first and second ionization energies of Group 1A metals?
    4. InferAn atom of the element M forms a stable ion in an ionic compound with chlorine having the formula MCl 2. In this compound, the ion of element M has a mass number of 66 and has 28 electrons. a.What is the identity of the element? b. How many neutrons does the ion have?

Hexagonal close-packed

Face-centered cubic

Body-centered cubic

216 Chapter 7 • Assessment

ASSESSMENT

Answers

UNDERSTAND CONCEPTS

  1. a. BaBr 2 b. Al 2 S 3 c. K 3 N
  2. Their outmost occupied energy levels are filled.
  3. a. Fe 2 O 3 b. PbO 2 c. Li 2 O d. MgO
  4. No, the packing of ions in a crystalline structure depends on a number of factors including the relative sizes of the ions. The coordination number of an element can vary from compound to compound.
  5. 12
  6. Hexagonal close-packed unit cells have twelve neighbors for, every atom or ion. Face-centered cubic unit cells also have twelve neighbors for every atom or ion, with an atom or ion in the center of each face. Body-centered cubic unit cells have eight neighbors for every atom or ion, with an atom or ion at the center of each cube.
  7. Brass is a mixture of copper and zinc. The properties of a particular sample of brass will vary with the relative proportions of the two metals.
  8. a. Cu, Zn c. Cu, Sn b. Ag, Cu d. Fe, Cr, Ni, C

THINK CRITICALLY

  1. Each dot in the electron dot structure represents a valence electron in the electron configuration diagram.
  2. By gaining or losing electrons the atoms of elements achieve a noble-gas electron configuration.
  3. No, sodium chloride is composed of equal numbers of sodium ions and chloride ions; the ions are in a 1:1 ratio. Each sodium ion is surrounded by chloride ions, and each chloride is surrounded by sodium ions.
  4. a. 6A d. 6A b. 7A e. 1A c. 1A f. 2A
  5. In sodum chloride crystals the sodium and chloride ions vibrate about fixed points; in the molten state, the ions are free to move.
  6. Metals are ductile (can be drawn into wires) and malleable (can be hammered into shapes). These changes are possible because a metal consists of metal cations in a sea of valence electrons. When subjected to pressure, the cations easily slide past one another.
  7. The spheres are more closely packed in (a); there is less empty space in (a), and a rough count shows 25 spheres in (a) compared with 22 spheres in (b).
    1. Both metals and ionic compounds are composed of ions. Both are held together by electrostatic bonds. Metals always conduct electricity, and ionic compounds conduct only when melted or in water solution. Ionic compounds are composed of cations and anions, but metals are composed of cations and free- floating valence electrons. Metals are ductile, but ionic compounds are brittle.
      1. Removal of the first electron results in a very stable electron configuration. Removing a second electron would disrupt that stability.
      2. a. zinc b. 38 neutrons

Ionic and Metallic Bonding 217

Enrichment

  1. Apply Concepts Classify each element in the following list. Will an atom of each element form a cation or an anion, or is the element chemically nonreactive? For the atoms that do form ions during a chemical reaction, write the number of electrons the atom will gain or lose. a.lithium b. sodium c. neon d. chlorine e. magnesium
  2. InferThe chemically similar alkali metal chlorides NaCl and CsCl have different crystal structures, whereas the chemically different NaCl and MnS have the same crystal structures. Why?
  3. CalculateSilver crystallizes in a face-centered cubic arrangement. A silver atom is at the edge of each lattice point (the corner of the unit cell). The length of the edge of the unit cell is 0.4086 nm. What is the atomic radius of silver?
  4. Analyze Data Consider two ionic compounds, NaCl and CaO. a.In which compound would you expect the electrostatic forces that hold the compound together to be the strongest? Explain your choice. b.The melting point of NaCl is 801°C. The melting point of CaO is 2614°C. Does this data support your prediction? Why or why not?

Write About Science

  1. CompareDescribe the formation of a cation that is an exception to the octet rule. In your description, compare the electron configuration of the cation to the electron configurations of the nearest noble gases.
  2. ResearchGo online and research X-ray dif- fraction crystallography. How are the samples prepared? How are the X-rays generated and detected? How is this technique used to study the structure of crystalline substances?

Sodium chloride (NaCl)

Clź Naá

Clź Csá

Cesium chloride (CsCl)

It’s Not Easy

Being Green

The statue of Ludwig van Beethoven in Central Park is made of bronze. Bronze is an alloy containing cop- per and tin. When bronze is exposed to the elements, it reacts with water (H 2 O), carbon dioxide (CO 2 ), and oxygen (O 2 ) in the air to produce a film of copper(II) carbonate (CuCO 3 ). Copper(II) carbonate is an ionic compound that is blue-green in color. A film of copper(II) car- bonate on the Beethoven statue gives the statue its green color. The film also protects the metal against further corrosion.

  1. Apply Concepts A copper atom can lose one or two electrons to form a Cuà^ ion or a Cu 2 à^ ion, respectively. The charge of the copper ion in CuCO 3 is 2à. Write the electron configuration of this cation.
  2. Form an OpinionWhy do you think bronze is often used to create statues?
  3. Connect to the BIG IDEA How are the properties of the copper(II) carbonate film on the statue different from the properties of the bronze beneath the film? Explain how these properties are a result of the type of bonding present.

CHEMYSTERY

Ionic and Metallic Bonding 217

ASSESSMENT

CHEMYSTERY

APPLY CONCEPTS After students have read through the CHEMystery, discuss the principles of ionic and metallic bonding that make the development of the green patina possible. Ask What type of bonding occurs? (The product is an ionic compound composed of copper from the statue and water and carbon dioxide from the air.) Ask How is the film able to protect the metal against further corrosion? (Because the film has a different composition, it doesn’t react with air in the same way that the metal does.)

CHEMYSTERY ANSWERS

92. The configuration is [Ar]3 d^9. 93. Sample answer: Bronze is an attractive metal alloy before and after it forms a patina. 94. The metallically-bonded alloy is able to react with elements in its environment to form an ionic compound, which is less reactive.

Answers

  1. a. cation: lose 1e–^ b. cation: lose 1e – c. unreactive d. anion: gain 1e– e. cation: lose 2e–
  2. Na+^ and Cs+^ differ greatly in size. Na+^ and Cl–^ are similar in size to Mn2+^ and s2–^.
  3. 0.1445 nm
  4. a. CaO; the electrostatic forces of attraction between Ca2+^ and O2−^ are much stronger than the forces between Na+^ and Cl−. b. Yes; more energy is needed to overcome the electrostatic attractions in CaO and melt the compound.

WRITE ABOUT SCIENCE

  1. An atom of silver has the electron configuration l s^2 2 s^22 p^6 3 s^2 3 p^6 3 d l0 4 s^24 p^6 4 d l0^5 s^1. To achieve the configuration of the preceding noble gas, krypton, a silver atom would have to lose eleven electrons and form Ag 11+. To achieve the configuration of the following noble gas xenon, a silver atom must gain seven electrons and form Ag7–^. Because ions with such high charges are unlikely, silver does not achieve a noble-gas configuration.

However, if a silver atom loses its 5 s^1 electron, the result is an outer electron configuration of eighteen electrons, written as 4 s^2 4 p^64 d^10. This configuration is favored and stable. It is known as a pseudo-noble-gas configuration.

  1. Remind students to use reliable sources and to document their sources. For such an extensive project, it might make sense for students to work in groups and divide up the tasks.