Titrimetric Analysis: Terms and Types of Acids, Summaries of Chemical Principles

The terms and concepts related to titrimetric analysis, a method used in quantitative chemical analysis. It covers definitions of analyte, titrant, indicator, end point, stoichiometric point, equivalent weight, titer, standard solution, standardization, and neutralization reaction. Additionally, it provides information about hydrochloric and sulfuric acids.

Typology: Summaries

2020/2021

Uploaded on 02/04/2022

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ACTIVITY 2
1. Define the following terms:
a. Titrimetric analysis
Titrimetric analysis is a method of analysis in which a solution of the substance being
determined is treated with a solution of a suitable reagent of exactly known concentration. The reagent
is added to the substance until the amount added is equivalent to the amount of substance to be
determined.
b. Analyte
An analyte, component, or chemical species is a substance or chemical constituent that is of
interest in an analytical procedure. The purest substances are referred to as analytes. Example: 24 karat
gold, NaCl, water, etc.
c. Titrant
Titration is a common laboratory method of quantitative chemical analysis to determine the
concentration of an identified analyte. A reagent, termed the titrant or titrator, is prepared as a
standard solution of known concentration and volume.
d. Indicator
chemical indicator, any substance that gives a visible sign, usually by a color change, of the
presence or absence of a threshold concentration of a chemical species, such as an acid or an alkali in a
solution. An example is the substance called methyl yellow, which imparts a yellow color to an alkaline
solution.
e. End point
The experimental point at which the completion of the reaction is marked by some signal is
called the end point. This signal can be the color change of an indicator or a change in some electrical
property that is measured during the titration.
f. Stoichiometric point
The equivalence point, or stoichiometric point, of a chemical reaction is the point at which
chemically equivalent quantities of reactants have been mixed. For an acid-base reaction the
equivalence point is where the moles of acid and the moles of base would neutralize each other
according to the chemical reaction.
g. Equivalent weight
equivalent weight, in chemistry, the quantity of a substance that exactly reacts with, or is equal
to the combining value of, an arbitrarily fixed quantity of another substance in a particular reaction. The
equivalent weight of an element is its gram atomic weight divided by its valence (combining power).
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ACTIVITY 2

  1. Define the following terms: a. Titrimetric analysis Titrimetric analysis is a method of analysis in which a solution of the substance being determined is treated with a solution of a suitable reagent of exactly known concentration. The reagent is added to the substance until the amount added is equivalent to the amount of substance to be determined. b. Analyte An analyte, component, or chemical species is a substance or chemical constituent that is of interest in an analytical procedure. The purest substances are referred to as analytes. Example: 24 karat gold, NaCl, water, etc. c. Titrant Titration is a common laboratory method of quantitative chemical analysis to determine the concentration of an identified analyte. A reagent, termed the titrant or titrator, is prepared as a standard solution of known concentration and volume. d. Indicator chemical indicator, any substance that gives a visible sign, usually by a color change, of the presence or absence of a threshold concentration of a chemical species, such as an acid or an alkali in a solution. An example is the substance called methyl yellow, which imparts a yellow color to an alkaline solution. e. End point The experimental point at which the completion of the reaction is marked by some signal is called the end point. This signal can be the color change of an indicator or a change in some electrical property that is measured during the titration. f. Stoichiometric point The equivalence point, or stoichiometric point, of a chemical reaction is the point at which chemically equivalent quantities of reactants have been mixed. For an acid-base reaction the equivalence point is where the moles of acid and the moles of base would neutralize each other according to the chemical reaction. g. Equivalent weight equivalent weight, in chemistry, the quantity of a substance that exactly reacts with, or is equal to the combining value of, an arbitrarily fixed quantity of another substance in a particular reaction. The equivalent weight of an element is its gram atomic weight divided by its valence (combining power).

h. Titer The titer is defined as the quotient of the nominal concentration of a volumetric solution and the actual concentration. The calculated factor is then used as the correction factor to the titrant. The measured value of the titer is multiplied with the nominal concentration. i. Standard solution In analytical chemistry, a standard solution is a solution containing a precisely known concentration of an element or a substance. A known mass of solute is dissolved to make a specific volume. Standard solutions are used to determine the concentrations of other substances, such as solutions in titration. j. Standardization Standardization is the process of determining the exact concentration (molarity) of a solution. Titration is one type of analytical procedure often used in standardization. In a titration, an exact volume of one substance is reacted with a known amount of another substance. k. Neutralization reaction Neutralization is a reaction where an acid reacts with an alkali to form a neutral solution of a salt and water.

  1. What kind of acid is hydrochloric acid? Hydrochloric acid is the water-based, or aqueous, solution of hydrogen chloride gas. It is also the main component of gastric acid, an acid produced naturally in the human stomach to help digest food. ACTIVITY 3 What kind of acid is Sulfuric acid? Sulfuric acid is a very strong acid; in aqueous solutions it ionizes completely to form hydronium ions (H3O+) and hydrogen sulfate ions (HSO4−). In dilute solutions the hydrogen sulfate ions also dissociate, forming more hydronium ions and sulfate ions (SO42−).