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"precisely" you can read the length on that ruler's scale—that is, ... However, when looking at a metric ruler in the real world, the smallest marks (i.e. ...
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M. Davis
In chemistry, you will be using measured numbers in lab, in exercises, and on tests and quizzes. The number of digits, i.e. significant figures , reported for a numerical quantity conveys the quality of the measurement or analysis to the reader. When recording data or calculating numerical values, the precision of these values, which is represented by the number of digits, is vital information. In science courses, you will use a meaningful number of digits in reporting your results. Laboratory measuring instruments have their limits, just as your senses have their limits. One of your tasks, in addition to learning how to use various measuring instruments properly , will be to correctly determine the precision of the measuring devices that you use in the lab.
Distances are normally measured with a ruler. The limit of accuracy of a ruler is indicated by how "precisely" you can read the length on that ruler’s scale—that is, how well you can estimate between the marks. On the portion of the ruler shown in Figure1, the distance between the closest marks is 0. cm. The dotted line to the right of the meter stick is at a length of 6.65 cm. The last decimal place, the hundredth’s place, in the measurement is estimated. Here is the key for determining the precision of most measuring devices: You can usually estimate to only one decimal place beyond the closest marks on any measuring device!!
On the ruler in figure 1, the closest marks are 0.1 cm apart, so you can estimate to the hundredths place, 0.01 cm. However, when looking at a metric ruler in the real world, the smallest marks (i.e. millimeter marks, mm) are so close that it is all we can do just to determine that the dotted line is between two of them—about half way. Therefore, your best estimate of the position of the dotted line is 6. centimeters. We can say that the measuring instrument is readable to ±0.05 cm. The ±0.05 cm means that your measurement may be off by as much as 0.05 cm above or below its true value. This value is called the uncertainty or the precision of the instrument.
Figure 1. A portion of a metric ruler (the centimeter scale has been enlarged for ease in reading)
Key Questions
M. Davis
Exercises (Use units and the correct number of “significant figures” for all numerical answers!)
Figure 2 – a portion of a cm ruler
Figure 3 – a portion of a cm ruler
M. Davis
The Buret
In lab you will use a specialized piece of equipment called the buret. It is a skinny glass tube that is designed to deliver specific amounts of a solution as part of the experimental procedure. A buret is shown in figure 7. Burets are different than other measure devices in that they are designed to be read from the top down! When you fill the buret with solution, the initial volume should be at or close to 0.00 mL. As a to deliver device, it is designed to measure how much liquid you drain out of the bottom. For example, if your start volume is 0.00 mL and you drain the liquid out of the buret to a final volume of 15.65 mL, you have added a volume of 15.65 mL to a vessel. This is calculated as: Final Volume – initial volume.
It is IMPERATIVE that you remember that the buret is read from the TOP DOWN. You will always read it from a low number to a high number.
Keep this in mind as you answer the following questions.
Figure 6 – a 10 mL graduated cylinder
Figure 7 – a buret
Figure 8 – initial volume
M. Davis
Figure 9 – final volume