UNIT 3 ATOMIC STRUCTURE Sizing up the Atom, Exams of English

Dalton's Atomic Theory. 1. All elements are composed of tiny indivisible atoms. 2. Atoms of the same element are identical and.

Typology: Exams

2022/2023

Uploaded on 03/01/2023

laksh
laksh 🇺🇸

5

(2)

223 documents

1 / 5

Toggle sidebar

This page cannot be seen from the preview

Don't miss anything!

bg1
9/11/2012
1
UNIT 3
ATOMIC STRUCTURE
Mrs. Medina
1
Early Models of the Atom
All matter is composed of tiny
fundamentals particles
ATOMS: smallest particles of an element
that retain the identity of the element in
a chemical reaction
2
Greek philosopher (~400
BC) suggested existence of
atoms
He claimed atoms were
tiny, indivisible, and
indestructible
His ideas agree with
modern theory but they
were not based on
scientific experiments.
3
Democritus’s Atomic Philosophy
Dalton’s Atomic Theory
John Dalton (1766-1844),
English chemist and
schoolteacher.
He used experimental methods
and transformed Democritus’s
ideas about atoms into
scientific theory.
He studied the ratios in which
elements combine
He formulated an atomic
theory. 4
Dalton’s Atomic Theory
1. All elements are composed of tiny indivisible
atoms
2. Atoms of the same element are identical and
atoms of different elements are different.
3. Atoms of different elements can mix
physically or chemically in whole-number
ratios to form compounds.
4. Chemical reactions occur when atoms are
joined, separated or rearranged.
5. Atom of one element can never became an
atom of another element during a chemical
reaction.
5
Sizing up the Atom
Atoms are around
1 x 10-10 meters in size.
Line up 100,000,000
copper atoms side by side,
they would only produce a
1 cm long line.
A copper penny contains
about 2.4x1022 atoms.
Earth’s population = 6x109
Atoms can be seen with a
scanning tunneling
microscopes
pf3
pf4
pf5

Partial preview of the text

Download UNIT 3 ATOMIC STRUCTURE Sizing up the Atom and more Exams English in PDF only on Docsity!

UNIT 3

ATOMIC STRUCTURE

Mrs. Medina

1

Early Models of the Atom

  • All matter is composed of tiny

fundamentals particles

  • ATOMS : smallest particles of an element that retain the identity of the element in a chemical reaction 2
  • Greek philosopher (~ BC) suggested existence of atoms
  • He claimed atoms were tiny, indivisible, and indestructible
  • His ideas agree with modern theory but they were not based on scientific experiments. (^) 3

Democritus’s Atomic Philosophy Dalton’s Atomic Theory

  • John Dalton (1766-1844),
    • English chemist and schoolteacher.
  • He used experimental methods and transformed Democritus’s ideas about atoms into scientific theory. - He studied the ratios in which elements combine - He formulated an atomic theory. (^) 4

Dalton’s Atomic Theory

  1. All elements are composed of tiny indivisible atoms
  2. Atoms of the same element are identical and atoms of different elements are different.
  3. Atoms of different elements can mix physically or chemically in whole-number ratios to form compounds.
  4. Chemical reactions occur when atoms are joined, separated or rearranged.
  5. Atom of one element can never became an atom of another element during a chemical reaction. 5

Sizing up the Atom

  • Atoms are around 1 x 10-^10 meters in size. - Line up 100,000, copper atoms side by side, they would only produce a 1 cm long line. - A copper penny contains about 2.4x10^22 atoms. - Earth’s population = 6x10^9
  • Atoms can be seen with a scanning tunneling microscopes

Subatomic particles

• There are 3 kinds

of subatomic

particles

– Electrons

– Protons

– Neutrons

7

Electrons

• In 1897, JJ Thomson

(English physicist)

discovered the

electron.

• Electrons are

negatively charged

subatomic particles.

8

How were electrons discovered?

9 ANODE CATHODE The green beam, or cathode ray , travels from cathode to the anode.

  • A low pressure gas was placed in a tube with electrodes on the end
  • Ran an electric current and saw a green beam.

How were electrons discovered?

  • A cathode ray can be deflected by a magnet or electrically charged metal plates.
  • The beam was attracted the positive and repelled from the negative. - Thus, Thomson hypothesized the cathode ray was a stream of tiny negatively charged particles. 10
  • Originally called corpuscles; later renamed electrons.

How were electrons discovered?

• How did Thomson test his hypothesis?

  • He set up an experiment to measure the “charge to mass” ratio of these electrons.
  • He used different gases and different electrode metals
  • => The ratio was constant

• Conclusion : These electrons must be

part of the atoms of all elements!

11

More on Electrons

• In 1916, Robert Millikan

(American physicist)

reported the charge and

mass of an electron.

• 1 unit of negative charge

1 1840

th the mass of a

hydrogen atom

12

The nuclear atom

  • The nucleus is the tiny central core of an atom and is composed of protons and neutrons.
  • In the nuclear atom,
    • The protons and neutrons are located in the nucleus.
    • The electrons are distributed around the nucleus and occupy almost all the volume of the atom. 20

Rutherford’s problem:

In the following pictures, there is a target hidden by a cloud. To figure out the shape of the target, we shot some beams into the cloud and recorded where the beams came out. Can you figure out the shape of the target? Target

Target

  • Elements are different because they contain different numbers of protons - The atomic number = number of protons - The atomic number (# protons) identifies an element.
  • Atoms are electrically neutral
    • Protons = Electrons 7 protons 1 proton 19 protons

ATOMIC NUMBER MASS NUMBER

  • Mass Number = the total number of protons and neutrons
  • Number of neutrons = mass number – atomic number

Neon Isotopes

25

Isotopes

26

  • Are there 3 different kinds of neon

atoms? YES, but they are all Neon

atoms.

  • ISOTOPE : atoms that have the same number of protons but different numbers of neutrons. - They are atoms of the same element. - They are chemically alike because they have the same number of protons and electrons.
  • Elements occur in nature as mixtures of isotopes.

ATOMIC MASS

  • In nature, most elements occur as mixture of two or more isotopes.
  • Each isotope has a fixed mass and abundance
  • The ATOMIC MASS of an element is a weighted average mass of the isotopes
  • A weighted average reflects:
    • The mass of the isotopes
    • The relative abundance of the isotopes 28

How to calculate the Atomic Mass

Name Percent abundance Mass (amu) Average atomic mass Hydrogen- 1 99.985% 1. Hydrogen- 2 0.014% 2.0141 1. Hydrogen- 3 0.001% 3. 29 Arithmetic Mean (1.0078 + 2.0141 + 3.0160) /3 = 2.0126 ??? Weight Average (1.00780.99985 + 2.01410.00014 + 3.0160*0.00001 = 1.00796 Yeah!!!!  To calculate Atomic Mass: Multiply the mass of each isotope by the natural abundance in decimal form Add all the products

The Periodic Table:

A Preview

  • A “periodic table” is an arrangement of

elements in which the elements are

separated into groups based on a set of

repeating properties

  • The periodic table allows you to easily compare the properties of one element to another

The Periodic Table:

A Preview

  • Each horizontal row (there are 7 of

them) is called a period

  • Each vertical column is called a

group, or family

  • Elements in a group have similar chemical and physical properties
  • Identified with a number and either an “A” or “B”