VSEPR Worksheet, Lecture notes of Chemistry

ANSWER KEY. A. Molecule. B. Lewis structure (use rules for drawing Lewis structures). C. Build molecule (see pg247), sketch, & give bond angles.

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Gather together the following equipment: 6 small white Styrofoam balls, one large coloured ball, and 6 toothpicks. Complete the chart. Note: when building
molecules use a large coloured Styrofoam ball as the central atom, small white balls as peripheral atoms, and toothpicks to represent bonds. If the molecule
has resonance structures, draw these in the “Lewis structure” box (B), but build only one resonance structure for the “Build molecule” box (C). The bond
angle for a tetrahedral molecule is 109.5°. Other bond angles can be calculated by correctly dividing the 360 degrees of a circle (look at your structure).
A. Molecule B. Lewis structure (use rules
for drawing Lewis structures) C. Build molecule (see pg 247),
sketch, & give bond angles D. Number of
peripheral atoms E. Bond angles
(list all) F. Name
(see pg. 247)
1. CH4
4 109.5° Tetrahedral
2. BeF2
3. PCl5
4. CCl4
5. PF6
6. SO3
H
H
H
H C 109.5
Q1. What does VSEPR stand for? Q2. For molecules that have names associated with their shapes, what is the minimum number of atoms a molecule must have? Explain.
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Gather together the following equipment: 6 small white Styrofoam balls, one large coloured ball, and 6 toothpicks. Complete the chart. Note: when buildingmolecules use a large coloured Styrofoam ball as the central atom, small white balls as peripheral atoms, and toothpicks to represent bonds. If the moleculehas resonance structures, draw these in the “Lewis structure” box (B), but build only one resonance structure for the “Build molecule” box (C). The bondangle for a tetrahedral molecule is 109.

°. Other bond angles can be calculated by correctly dividing the 360 degrees of a circle (look at your structure).

A.

Molecule

B.

Lewis structure (use rules for drawing Lewis structures)

C.

Build molecule (see

pg

sketch, & give bond angles

D.

Number of peripheral atoms

E.

Bond angles

(list all)

F.

Name (see pg. 247)

CH

4

°^

Tetrahedral

BeF

2

PCl

5

CCl

4

PF

  • 6

SO

3

H

H

H

H

C

Q1. What does VSEPR stand for? Q2. For molecules that have names associated with their shapes, what is the minimum number of atoms a molecule must have? Explain.

ANSWER KEY A.

Molecule

B.

Lewis structure (use rules for drawing Lewis structures)

C.

Build molecule (see

pg

sketch, & give bond angles

D.

Number of peripheral atoms

E.

Bond angles

(list all)

F.

Name (see pg. 247)

CH

4

°^

Tetrahedral

BeF

2

2 + 7 x 2 = 16, 16 – 4 – 12 = 0 Note: Be is exception to octet rule

°^

Linear

PCl

5

5 + 7 x 5 = 40, 40 – 10 – 30 = 0

°^

Trigonal

bipyramidal

CCl

4

4 + 7 x 4 = 32, 32 – 8 –24 = 0

°^

Tetrahedral

PF

  • 6

5 + 7 x 6 + 1= 48, 48 – 12 – 36 = 0

°^

Octahedral

SO

3

6 + 6 x 3 = 24, 24 – 6 – 18 = 0. Smust have octet … resonance possible

°^

Planartriangular

H

H

H

H

C

F

F

Be

Cl

P

Cl

Cl

Cl

Cl

C

F

P

F F^

F^

F

F

O

O

O S

O^ S

O^

O^

O^

S^

O

O

Cl^ Cl

Cl

Cl

Q1. What does VSEPR stand for? Valence Shell Electron Pair Repulsion. Q2. For molecules that have names associated with their shapes, what is the minimum number of atoms a molecule must have? Explain

3 (shapes refer to shapes around a central atom. For a “shape” to exist there must be at least 2 peripheral atoms, or 3 total atoms)