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written homework 5 dr.hodby physics 1
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1) Breaking a bond A diatomic molecule’s potential energy, PE, is measured as a function of the separation, 𝑥, of the two atoms. Note the scale of the axes (nm stands for nanometers, and eV stands for “electron volt” and the unit conversion is 1 eV = 1.6 × 10−19^ J). Note: for very small values of 𝑥, the potential energy becomes effectively infinite (off the graph’s positive scale); while for very large values of 𝑥 the potential energy approaches zero. A) If the separation between the two atoms at some moment is 0.25 nm, approximately how much potential energy does the molecule have at that moment? B) Total energy is kinetic energy plus potential energy. If the separation is 0.25 nm at some moment, which of the following are impossible values of total energy for this two-atom system? [Note: in some cases, the kinetic energy might be enough that the bond will break!] −4 eV, −2 eV, 0 eV, +2 eV Circle the values that are impossible. Explain your reasoning.
C) Only potential energy differences are physically meaningful. We see from the graph that the potential energy approaches zero as 𝑥 becomes large. Imagine a case in which the separation increases from
D) If the bond were broken, the atoms would become widely separated. What is the potential energy of the molecule after the bond is broken? [Hint: this is precisely the reason for choosing the “zero point” to be 𝑥 = ∞!] E) If the molecule is part of a system that is at high temperature, it will have kinetic energy in addition to its potential energy. Suppose the molecule has a total energy of −1.0 eV. What is the kinetic of the molecule when the separation is 0.25 nm? F) Again, suppose the total energy is −1.0 eV. What are the maximum and minimum values of the separation? Explain how you obtained these values.
B) Suppose the system has exactly this minimum thermal energy and the reaction happens completely. How much thermal energy will the system have at the end of the reaction?