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A\mines fh INTRO —__|=Amines are. (NITROGEN? ontaining Organic compound: Amines are. present in Steucture of many natural compounds _ like proteins . Vitamins » hormanes_and_manhy plant produces like. nicotine- Clagsification of Amines: ° J+ Amine. are classified 4$ i= Primazy (1°)? Secondary (2) £ Tertiary (3°) Amines. — Their. Geuctures are, obtained in Simple, way be veplacing ones, wo OR three hydyeqen atoms of NH, by Alkyl /ARYL Group ur lh Fa beara aes er ea he eahn aat — 2° Amines are clagsified as, (SIMPLETORSSYMMETRICAL Amines ane 2° Amines are Chssified ag (mixkotoR“UNSYMMETRICAL Ammer. * When all the, alkyl or aay! _gasups on Niteogen are ‘Same (Lis a -eSimpreaAmine.. If these groups are “different” -then it hs CMMED Amine: - Types of Amines Type’ Ftindt nal dgoup Example Name | -formula | formula. | @mmen Name Poimary Amine, (4°) Ainino — Nie GlsNH Ethy] amine, _ | Remem bee his ! |-rhe Reaction of Mitsebenzene with (ear and meounCacericmacieh)? (wil eriE= Inthe breminationsoF nitcobenxenessteci-Acay (aeethexemetasspasitions pf — Q.|Hhat is the acion of atic Anhydeide on eth ylamine_ diethylamine and -eiethylamine : () | GH5-NHy + (Ka- g70-e hs Pyidine GHe- Mt —(Hg Diethyl d u amine AgsHic Anhydride N- acetyl ethylamine CH= ethylethanamidg) fii) | Gls —NH_ + (gre~ O-c~(H,_Pyvidine | GHs-N~ © ~ Cy + Gigs Ome. aHe ui Gus © datic add 2 _ - Diethy| amin. AGH Anydeide. An-dietnyl acetamide (iliy| REAM oF Acct Anhydzide on” tiethylamine is Nob exist? | oe iii- | (axbylamine Renceion Land @ amines do not, give this te - >| R-NH24+(HClg +3KOH A R-NC + 3kCL_+ SH26 | Amine flsacyanicless | Reaction aith Hitzous acid R-NWa Ft HANOo 278- 278K [e-ni-cf) H-oH _R-o + NAT +HEL | "anoine Niue (Nano, + Hcl) ath gig zoniaey Alcohol | Chhavids- | *| What Is _diazotsation? hialie digzotisaHon of Aniline « | Aliphatic OR fromatic paimary Amine reag ‘ith nitzoug acid |+o-form Coxesponding digxonium Salt 2 This Reag® |s Called Feowzorisation> NM, Nec | 3) | Ay NaNox ry + Nact +40 [ AP Aagk” (CO | Aniline Belzertdiazonjury i Chlovde- oid i ty be Sl alabelal da tot bb hk ELL 4) | Reactions of arene, diazonium Salt. | “Trie of Substrate | Reagent | __— Predicts | Reaction } | \-| Sandmayee Rag? Ar nD yo | RTA ay ch te |__ Geod yield) Ar-nSe | SUBCHEY | ayer the | e-Nex | UO ae Et a:| Gaveemon Rea? Ar-n&x | Cu feed, | mca ns ; ‘ood | | Ar-n@xe | suet | Ar-grtta B-|_lodoarene> > | Ar-n@c® | ke | Ay-TtNe —fonmosion | A:| mild Arn2cO | BBR — | Arent nat Hypos HEL Reduaion Ar-NS US | Mycua-O4 | ATH thet Cot HL g-| Phenol aren ScP | RB | Aron tne tice —Formadion | | | 5) | Convert Aniline +o Renzene, Ae nano tHe AR spon ey ale Os Co otc 5° fol [O] nili Benzene Z Benzene Analine diazeniam chtoride- 6) | ReaG" Involving Retention of diazo group CcouPling Peactn's) -N=N- ~— axo group Azo compounds are byighty Coloured and are used ag dyer. ehenol Bareare agen CP- Hydaoxyaz0 benzene) (erangedye) vetavosthie 7 2 a Ne or = Hy +HEL CoyaNEnE +o Sas OF. NS ena g yi diazonien Anijine : chlewda (FFminoaeabenzeng) 
