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/ Gh HMapOue pressure of fuse uiquied : abeg™ —+ eva *Kp— Vapout pressuse | . ws “only Temp. dependent * Kp — dependent ypon temp - exepenenionally. aK beavis wd “depe E uae whee oF 4 wv) ae ‘hd ae *dog K esate en Out ae sy a oe ie + ! 6) REA eS Wien “Te hh er 2.505 R Kry R-3030 [te Th 7 Kr Rate cans}. Qa, B- 314 HF [k-mele R= 9+ 0821 atm Jit | K-™9) p= Q.o eal] w-mole- “der Ee Ay fee 2303 R aes ia Se Vapoug pressuzé also depends Upon force OF athacfon t se force OF aibatiton oe ooo Vapout +, Vp + Clecte.s > Ton-dipole? tebend> dipole-dipole Soin of = He EG iS > dipelé induced dipole) jondon toe solvent ei ¥% COR — Polag molecule > Non- Polat yc [p°> Ps | *Vp ee ee eee fee P+ Pressuse OF Pure solvent =H Kault's law * cae ence st soe % Ps = Ky + solvent - Ka P°> Ps > bicoz @ Solute - solvent inicedthfen Peel Pah soluent § ee Mae x le™ Ps = pe. Yeolute | Lroweei ng ar) * (solu -H n a HK Miature oF Volatile ‘cjoute in C %eolute |» Relate Jowesing Volahle Soloent ¥ of. veP on add” of Pr= Pgotoute + Prervent 4F Compasitien of of Napoue prase 3 [Pan FF: Ma] (Ya) i oy PAER KA + Pe Xp & * Talton's lav: Cin} ii oe Pressuwe of gos A Pr Pr (Pay = PrXa Ya. Ye are mole fraction of Aand & jn [Pe Pr in | Vanaue phase « IMs 972° 933° ' 863 oy TEColtigaive Properties A Psop.of solutfon depends upon no-of pares of Solate: * - TErespech ve en the netare oF Solude- « Won volatile solid solu: * diluted salt. 4. Relative youesing of vapous pressure: «If Rive asked | given then | PPPs — RXealoule e o pu Ps = hsoloute p? =_ | Msctouk . nyotal oo Saih given as Hight z diluted s- 2 IF po and Ps given PEPS _ Yeolute — Hsolute Ps Nsolvent Hselvent | I solyent - WAIMA wala we SolMp eA, we ven | Mia HeCswolk's wakes experiment te MA OMB Wa IMR, pies es = obsess in seluens containee pe 3 FAR “etal uot. Joss. 2. Elevation in Belling Point : Ibent 1 $4 Th’ — ctf “Te 7 6 bie : ATE ji Solukvon — Pp, 7! poy Ps + CES Ke roo! on y: is 8 : Fs = QT),% 5. Depression in EEE nuyy, Point + Roel ee AHyqp. loco Wwe BP 4 Fr “TR iscluent) % TE (éeiny P + Cate Kem) BHyap = Het of é ke = MATE? eC ee 44 pisjon* 1000 Faessuve : fro SPM — semepeemfable menboane se osmosis 1 flow of goloent m7, vw dow .cenc SolmD 44 nadusay . Synthetic nigh Cone. Saif. (ox) -fisw of Selvent fiom dese high Conc. soWwent +o So conc, Salven. Ma Min of sdeent Ya= Pax . ce $ Ye= T-Ys, PEAY pe AXAY Py kB t ; on a, AS€ JIT $ Miduse of eo valatile dig: and both ere tmemisibsle + “ te [w= nires | Yee Pe |e eee. 2 71 Sic YR P,e Bi ; =: ‘ % ad Boiling Point Naps Pressuz € =[wa_ Pema \y uo : ty torn Tea ram 8g s Feo MG: tho Tote. « —rcase oF mist bie- aig mi 4ne BP ane BP 6 pet sthase gal? — does not follow Rowlt"! lara Ly aye deviakton C4inngeé integacH'on Re Anmie <0 » 4570 AVmizid § A640 Alagacd) —ol clay CSai aye deviation. F - Repla ec Wee. Aecieton. Comnget imiegaction se Atmnix <9 AN enix 40 Agmintto mates AG toa ee Foe Ideal : Ga af +he mix. ig less than in the placed by usea kee qpiezadton ) Barh- dig: entive Ramge af carpasition . AKee Yategackion 3) — —ve deviation = +ve deviation . HL “The mole fimehfon of is &qual +o+he mol p ; ‘ ve 2 Weng tee oe Mand ain ‘a jab Pare - In vepoue phase oF cantaine 1 Ay = OA ane fee containes Yore *a (2) fon toin ee 4-Ya, Pgs U- FAs) 0) i ees @ & Foe nt Containeg #- 4 Was = Ka tal fay’ 1- Yan 1 eR Po 4+ Case of cvspuratten + Y \ @ Find out ME Vop- Pressure of the so” when 15* dap of vapout formed. Pra itotn + pola de Saree) 5 : @ Find out tne mole Gadfon of #and@ in . | XA ONI%e OF amgionol syskn +he 15+ deoplet of vap. formed . 1S equal -fo-this systero. Yas PAXA we gts 4-Ya PRxA + Pe XG ® findout the composiitan of Jast drop of diquid Remaine 4 niet | Yr=_Pexn —— ==> % Ail sact ehiop femained) =7 Xa and: Xp of OF Proxn + Pp (1-Xa) so)”. 3 Yq and ¥ @ Find ost the total vie alg drop of Jig. Remained a te Py = Pa Xn bs Po Xa = Case of Condensation ++ GKEon GATT Piston Sr enap e1 0) Findout +he Composition of the 45+ deopof Jig phase. Yas Paxa 44 BEST Payat PP Xp Yr of oxigional gaseous midtise = Ya of +nis f Comtainee . 
