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Commutator formulas in quantum mechanics. It defines commutators and their use in calculating expectation values. The document also provides different formulas to manipulate commutators. It is a useful resource for students studying quantum mechanics and related topics.
Typology: Lecture notes
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A commutator is defined as
1
where
A and
B are operators and the entire thing is implicitly acting on
some arbitrary function. We’ve seen these here and there since the course
began, most recently in the Heisenberg equation of motion for an expectation
value’s time dependence:
2
d
dt
〈A〉t =
i¯h
H]〉t
It’s worth recalling that any operator
A for which [
H] = 0 is a constant
of the motion – that is, its expectation value 〈A〉 t
= 〈A〉 will be independent
of time altogether.
Commutators can be a little tricky (Problem Set 2 should’ve proved that
to you!), so let’s have a look at the different formulas we can use to make
manipulating them a little easier.
1 Most quantum mechanics books will discuss commutators in some detail. You can
also check out the Wikipedia page, http://en.wikipedia.org/wiki/Commutator, for more
information.
2 The notation I’m using here is shorthand. Wherever the 〈.. .〉t appears, you should
remember that it means we’re calculating
〈Ψ(t)|.. .ˆ|Ψ(t)〉 =
∫ ∞
−∞
Ψ
∗ (x, t)( ˆ.. .)Ψ(x, t) dx
2 Formulas
There aren’t actually that many formulas to point out to you – “just” seven,
not counting one that I’ll have you prove as an exercise – but the amazing
thing is that only the definition given in (1) is fundamental! As a result, you
should be able to prove any claim that you find dubious on your own, and
you’ll only have to do a little pencil pushing. Even if you don’t have trouble
believing any of these formulas, it’s worth working them out at least once.
With that said, here they are (c is a constant):
A, c] = 0
[c
A, c
B] = c[
3 Exercise
Show that [
A, f (
A)] = 0, given that the function f has a power series ex-
pansion in
A. This is a handy thing to know when you want to evaluate the
commutator of ˆx or ˆp with the Hamiltonian operator