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Diamond Crystal Structure
Diamond is a metastable allotrope of carbon where the each carbon atom is bonded covalently with other surrounding four carbon atoms and are arranged in a variation of the face centered cubic crystal structure called a diamond lattice
Diamond Unit Cell
Figure shows four atoms (dark) bonded to four others within the volume of the cell. Six atoms fall on the middle of each of the six cube faces, showing two bonds. Out of eight cube corners, four atoms bond to an atom within the cube. The other four bond to adjacent cubes of the crystal
Lattice Vector and Basis Atoms
So the structure consists of two basis atoms and may be thought of as two inter-penetrating face centered cubic lattices, with a basis of two identical carbon atoms associated with each lattice point one displaced from the other by a translation of ao(1/4,1/4,1/4) along a body diagonal so we can say the diamond cubic structure is a combination of two interpenetrating FCC sub lattices displaced along the body diagonal of the cubic cell by 1/4th length of that diagonal. Thus the origins of two FCC sub lattices lie at (0, 0, 0) and (1/4, 1/4,1/4)
(a) (b)
(aa) Crystallographic unit cell (unit cube) of the diamond structure (bb)) The primitive basis vectors of the face centered cubic lattice and the two atoms forming the basis are highlighted.
From triangle WXY
XY^2=(a/4)^2+(a/4)^ =(a^2)/ From triangle XYZ XZ^2=(a^2)/8 + (a/4)^ =(3a^2)/ But XZ=2r So (2r)^2 = (3a^2)/
AAtomic radius r =( a(3)^1/2)/
Atomic packing factor is = v/V =[(84PI*r^3)/3]/[(a)^3] By putting value of r we get----- APF=0.34 =34%
Thus it is a loosely packed sstructure
